The invention discloses a production process of vacuum aluminum-plated composite films. The production process comprises the steps of selecting base materials, carrying out vacuum aluminum plating, coating an adhesive, compositing, rolling up, and carrying out aging treatment, so that a finished product vacuum aluminum-plated composite film is obtained. Compared with the prior art, a composite film prepared according to the invention has the following advantages and effects that experiments prove that a sub-gloss film produced according to the invention has a good aluminum-layer adhesion force, a strong tensile strength (210-301 MPa), good glossiness, and excellent oxygen and moisture permeable barrier properties, the solvent residue is less than or equal to 0.13, the sub-gloss film is environmentally friendly, smooth in surface, bright and clean, safe, sanitary, and easy to recover, the phenomena that the aluminum-layer adhesion force of a composite film prepared in the prior art is poor, aluminum powder is easily removed, and the glossiness of printed patterns is weak are overcome, products are widely used in the packaging industries for foods, cigarettes, gifts, cosmetics, medicines and the like, and the film is a basic raw material used in the printing composite industry.