The invention discloses an
arsenic sulfide waste residue recycling treatment method, which comprises the following steps: performing alkaline leaching to obtain sulfo-
arsenite or sulfo-
arsenate solution, filtering to remove waste residues through a filter, to obtain alkaline
leachate, then performing oxidation desulfurization, so as to oxidize sulfo-
arsenite or sulfo-
arsenate into sulfo-
arsenite or
arsenate ions, then filtering and separating elemental
sulfur through another filter to obtain arsenite or arsenate solution, recovering acid-base from the arsenite or arsenate solution by utilizing a bipolar membrane device, returning base solution for alkaline leaching and acid solution for crystalization and preparation of As2O3 or As2O5, performing
electrodialysis or
reverse osmosis concentration on residual liquor in a bipolar membrane salt chamber, returning concentrated liquor as inflowing water of the salt chamber of the bipolar membrane device, and draining or recovering
fresh water. According to the
arsenic sulfide waste residue recycling treatment method, the problems that for the traditional
arsenic sulfide waste residue treatment method, consumption is large, the content of arsenic in
effluent water does not reach the standard, the recycling rate is low, the technological process is complicated, secondary
pollution exists and the like can be solved, the content of arsenic in
effluent water reaches the standard, the recycling rate of As and S is high, the advantages of low consumption, low running cost, simple technological process and the like can be achieved.