652 results about "Aviation kerosene" patented technology

The present invention relates to a novel synthetic route of a liquid chain hydrocarbon fuel totally independent of fossil energy based on a lignocellulose raw material to obtain a platform compound. The method includes three parts: 1) preparing oxygen-containing organic compounds with carbon chain length of 8-16 through the acid-catalyzed alkylation reaction by taking lignocelluloses-based carbonyl-containing platform compounds and furan platform compounds as raw materials on a novel solid catalyst; 2) effectively removing carbon-carbon double bonds and carbon-oxygen double bonds to prepare saturated oxygen-containing organic compounds by hydrogenation of the alkylated product; and 3) conducting hydrodeoxygenation for the hydrogenated alkylation product by using a metal-solid acid bifunctional catalyst to obtain the biomass aviation kerosene or high grade diesel fuel with the carbon chain length of 8-16 and having a high energy density and stability.

The invention relates to a new liquid chain hydrocarbon fuel synthetic route that acquires a platform chemical compound based on a lignocellulose raw material and is completely independent of fossil energy. The liquid fuel obtained by the method can be used as a substitute of aviation kerosene and diesel oil or as an additive for improving the cetane number and cold hardiness of fuels, thereby reducing the national dependence on imported petroleum in terms of liquid fuels. The method provided in the invention consists of two parts: 1) on a novel solid acid catalyst, an aldehyde group-containing compound (such as formaldehyde, acetaldehyde, propionaldehyde, and butyraldehyde, etc.) and a furan platform compound (such as furan, methyl furan, and hydroxylmethyl furan, etc.) undergo an acid catalyzed alkylation reaction to prepare an oxygen-containing organic compound with a carbon chain length of 8-16; and 2) hydrogenation and hydrodeoxygenation are conducted on an alkylation product to hydrogenate unsaturated bonds and remove the oxygen therein, thus preparing aviation kerosene or high grade diesel oil with a carbon chain length ranging from 8 to 16.

The invention discloses a hydrogenation catalyst and a preparation method thereof. The catalyst comprises hydrogenation active metal components and a carrier consisting of the small crystal grain Y-shaped molecular sieve, amorphous silica-alumina and aluminum oxide, wherein the small crystal grain Y-shaped molecular sieve is a small crystal grain Y-shaped molecular sieve subjected to hydro-thermal treatment. The hydrocracking catalyst provided by the invention has the characteristics of high catalyst activity, excellent target product selectivity, great preparation flexibility, and the like, thus the catalyst can be used for preparing products such as heavy naphtha, aviation kerosene, diesel oil and the like with high yield and good product quality.

The invention relates to a new synthesis route of a liquid branched paraffin fuel, the method adopts a lignocellulose based platform compound as a raw material and is completely independent of fossil energy. The liquid fuel obtained by the method can be used as an aviation kerosene (or diesel) substitute or as an additive to increase the cetane number and cold resistance of fuel. The method provided by the invention includes two steps of: 1) under the promotion of a base catalyst, subjecting a lignocellulose based furfural compound (including furfural, methylfurfural or 5 hydroxymethylfurfural) and branched chain keto (including methyl isobutyl ketone, and mesityl oxide, etc.) to aldol condensation reaction so as to synthesize an oxygen-containing organic compound with a carbon chain length of 9-16; and 2) conducting hydrodeoxygenation on the aldol condensation product generated in step1 to obtain biomass aviation kerosene branched hydrocarbon with a carbon chain length of 9-16, higher energy density, stability and low freezing point.

The invention relates to a new method for preparing hydrocarbons in the scope of aviation kerosene from C8-C16 furyl oxygen-containing organic compounds as raw materials by hydrogenation deoxidation reaction, wherein the C8-C16 furyl oxygen-containing organic compounds are obtained by C-C coupling of lignocellulose based platform chemical compounds; low temperature direct hydrogenation deoxidation under the condition of no solvent of the furyl oxygen-containing organic compounds can be realized by use of a metal-solid acid dual-functional catalyst to obtain a series of low freezing point branched alkanes having the chain in the length range of the aviation kerosene in high yield. The catalyst is composed of two parts of an active metal A and an acid vector X. The catalyst related in the method ahs the characteristics of being in no need of a solvent, simple in operation process, mild in reaction conditions, good in aviation kerosene (or diesel) selectivity, and the like, and is an ideal hydrogenation deoxidation catalyst for preparing liquid fuels from the furyl oxygen-containing organic compounds by the hydrogenation deoxidation.

The invention discloses a hydrocracking method for selective increasing of an aviation kerosene yield. The hydrocracking method comprises that raw oil and hydrogen are mixed and then orderly undergo a hydrofinishing reaction and a hydrocracking reaction; a reaction effluent is cooled and is subjected to separation so that a heavy diesel fraction is obtained; and the heavy diesel fraction having the content of 10 to 100% and a temperature of 320 to 370 DEG C is fed back to a raw material tank and then undergoes a reaction sequentially, wherein the heavy diesel fraction has low aromatic hydrocarbon content and naphthenic hydrocarbon content and is an appropriate fraction for selective increasing of aviation kerosene yield. The hydrocracking method realizes high selectivity of an aviation kerosene fraction. The recycle heavy diesel fraction is fed into the raw material tank and undergoes a hydrofinishing reaction in a hydrofinishing reactor and a hydrocracking reaction in a hydrocracking reactor so that an aromatic hydrocarbon further undergoes a hydrogenation saturation reaction. Therefore, the hydrocracking method is conducive to improvement of a smoke point of aviation kerosene and reduction of aromatic hydrocarbon content of aviation kerosene.

The invention relates to an ultra-deep absorption desulfurizer for light oil and an application thereof. The desulfurizer comprises 10.0-80.0% of zinc oxide, 5.0-75.0% of VIII metal oxide, 1.0-50.0% of adsorption assistant, 1.0-10.0% of pore-expanding agent and 10.0-35.0% of adhesive. The method for making the desulfurizer comprises the following steps: uniformly mixing, pressing to obtain sheets or squeezing to obtain strips, drying and roasting. The absorption desulfurizer does not use noble metals, thereby having the advantage of low price; the invention adopts mixed roasting technique, thereby having the advantages of simple preparation method and easy operation; the desulfurizer has the advantages of high desulfurization activity and favorable regeneration effect, and can be used for processing low-sulfur light oil; the content of sulfides in the processed light oil can be reduced to below 0.5 ppm; and the desulfurizer is suitable to be used in the low-temperature fine desulfurization process of naphtha, gasoline, diesel, aviation kerosene and the like.

The invention relates to a method for preparing biodiesel by mixing waste edible oil with mineral diesel oil and hydrogenization. The method comprises the steps as follows: pretreatment of waste edible oil, a first stage of hydrogenization process, a second stage of hydrogenization process, and a product fractionation process. The method adopts the waste edible oil and the mineral diesel oil as raw materials for preparing high-quality biodiesel and biological aviation kerosene components which have low polycyclic aromatic hydrocarbon contents, high cetane values, low sulfur contents and low nitrogen contents, effectively solves the problems of blockage of a catalyst bed caused by the settlement of metal and gelatine in the animal and vegetable hydrogenization process, influence on the activity of catalyst from H2O, CO2 and CO produced in reaction, sulfur supplement of a hydrogenization system, and influence on the service life of the catalyst caused by centralized release of reaction heat, can realize the continuous hydrogenization and industrial production of materials containing animal and vegetable oils, and has practical significance.

The invention discloses a super-hydrophobic/super-oleophilicity copper wire mesh for oil and water separation and a preparation method and application thereof. The preparation method comprises the steps that firstly, the copper wire mesh is ultrasonically cleaned through diluted hydrochloric acid, absolute ethyl alcohol and deionized water respectively and dried through nitrogen; chemical deposition liquid of copper sulfate and a sodium thiosulfate solution is prepared; the cleaned copper wire mesh is placed into the chemical deposition liquid for a deposition reaction; the copper wire mesh is taken out and cleaned through the deionized water and dried in the air; the dried copper wire mesh is placed in a solution of a curing agent and polydimethylsiloxane with hydroxyl sealed end, and the copper wire mesh is taken out and heated. No expensive fluorine-containing substance is needed, the copper wire mesh has the advantages that the preparation technology is simple, reaction conditions are mild, no strong acidity or strong basicity or corrosivity reagents are needed, and no harm is caused to the environment, separation of oily wastewater can be achieved rapidly and efficiently, the good separation effect on chloroform, normal hexane, petroleum ether, plant oil, diesel oil, aviation kerosene and the like is achieved, and separation of strong acidity, strong basicity and high salinity oily wastewater can be achieved.

The invention discloses a preparation method of a hydrogenation catalyst. According to the catalyst, a cracking molecular sieve, amorphous silica-alumina and alumina are used as carriers, and VIII and VIB metals are used as hydrogenation active components. The preparation process comprises the following steps of: mixing the cracking molecular sieve, amorphous silica-alumina and alumina for molding, drying, loading the active metals by an immersion method, drying and roasting to obtain the catalyst. In comparison with the routine immersion method, the method provided by the invention can be used to prepare the molded carriers without roasting, simplify time and energy, minimize strong interaction, help uniform distribution of the metals as well as performance of the metal activity, and avoid specific surface area loss caused by multi-step roasting. The catalyst prepared by the method is especially applicable to be used as a hydrogenation catalyst for high-yield high-quality heavy naphtha, aviation kerosene and diesel oil. By the adoption of the preparation method, activity and selectivity of the catalyst are raised.

A water-solubility printing ink washing agent comprises A component, B component and solvent according to weight ratio of 1: (1.5-2.5): (0.04-0.08), wherein raw materials of the A component are as follows according to weight parts: 12-15 parts of fatty alcohol-polyoxyethylene ether, 0.5-1 part of alkylphenol polyoxyethylene, 8-10 parts of aviation kerosene, 2-4 parts of dibutyl phthalate, 1-3 parts of butyl cellosolve, 1-2 parts of benzyl alcohol and 1-3 parts of butyl acetate; raw materials of the B component are as follows according to weight parts: 5-8 parts of sodium dodecyl benzene sulfonate, 1-2 parts of ethanolamine, 1-3 parts of diethanolamide, 0.5-1 part of urea, 0.5-1 part of sodium carbonate, 0.3-0.5 part of sodium silicate, and 45-55 parts of water. The preparation of the invention is simple, has simple and convenient manufacture, stable performance, safe usage, does not easily burn, does not corrode device and does not pollute the environment. The washing agent has good washing effect, is safe and non-toxic, has easily obtained and stored raw materials, has high stability, can be repeatedly used, and has wide market prospect.

This invention discloses a hydrocracking method.It includes that the heavy distillate oil and poor quality catalytic cracking diesel refining separately by hydrogenation, and the mixture enters into hydrocracking reactivator, then its cracking products is conducted gas liquid separation. Light naphtha, heavy naphtha, aviation kerosene, diesel oil and end oil will be obtained by distillating the liquid phase. The density of the poor quality catalytic cracking diesel oil is above 0.9g/ml, and the aromatic hydrocarbon is over 60wt% and the value of hexadecane is under 30. It is a adequate utilization of catalytic cracking craft to produce High aromatic hydrocarbon heavy naphtha and high quality end oil with heavy distillate oil and poor quality catalytic cracking diesel, which can be separately used as catalytic reforming material and making ethylene material by steam cracking method. High aromatic hydrocarbon heavy naphtha in this invention will produce a large amount of reforming hydrogen after catalytic reforming treatment, which can be used in the process of hydrocracking to make this preparation more ecnomical and reasonable.

The invention provides a catalyst for reaction of preparing aviation kerosene by castor oil through hydrogenation and a preparation condition of the catalyst. Modified MCM-41, SBA-15 and the like are used as the carrier of a hydro-de-oxygenation catalyst, and one selected from Ni, Ni2P, Co, CoP and Pt is used as an active component; modified SAPO-11, SAPO-34 and the like are used as the carrier of a hydrogenation isomerism catalyst, and one or two selected from Ni, Ag, Pd and Ru is/are used as the active component; the catalyst for the action of preparing the aviation kerosene by the castor oil through a one-step method is characterized in that with one or more selected from modified USY, a beta-type molecular sieve, an X-type molecular sieve and ZSM-5 as the carrier and Ni and Cu as active components or Ni2P and Cu3P as the active components, under a proper reaction condition, the aviation kerosene which meets the need of the operation conditions is prepared.

The invention related to a method for preparing tribonema biological oil, the tribonema biological oil prepared through the method and biodiesel, aviation kerosene, food or feed prepared from the tribonema biological oil. Particularly, one or two of isomorphous tribonema, common tribonema, small-size tribonema, pseudo-silk tribonema and cystic tribonema or a mixture of more algae is subjected to scale culture on an open culture device or a closed culture device or a culture device on which the tribonema grows in a biofilm form and an attaching manner to obtain oil-containing tribonema biomass. The tribonema biomass is extracted with an organic solvent, or squeezed or prepared by adopting an extracting and squeezing combined method to obtain biological oil containing 40-80wt% of triglyceride, 65-85wt% of hexadecenoic fatty acid in the fatty acid and 6-15wt% of eicosatetraenoic polyunsaturated fatty acid.

The invention discloses a middle-pressure hydrocracking method for producing aviation kerosene and low-freezing point diesel. The method comprises the steps that a single-section serial one-time passing flow is adopted under a middle pressure condition; the heated material and hydrogen enter a hydrotreatment reactor; reaction effluent enters a hydrocracking reactor without separation, and reacts under the existence of a hydrocracking catalyst; the generated reaction effluent is subjected to oil-gas separation and then cyclically used after being compressed by the obtained hydrogen-rich gas; the obtained liquid is distilled to obtain a little of pyrolytic naphtha; and a large part of product is middle distilled oil fraction. By adopting the method provided by the invention, 3# aviation kerosene and low-freezing point diesel meeting the GC6537-2006 standard are prepared from light wax oil or a mixed material of the light wax oil and FCC light cycle oil under the middle pressure condition. The method disclosed by the invention is simple in flow, low in operating cost, and low in device investment.

The invention discloses a hydrocracking method of a productive high-quality jet fuel. Raw material oil and hydrogen successively pass through a hydrofining zone and a first cracking reaction zone to obtain tail oil to get into a second cracking reaction zone for cracking; two cracking catalysts exist in the first cracking reaction zone, the upstream of the first cracking reaction zone is loaded with a catalyst I, and the downstream of the first cracking reaction zone is loaded with a catalyst II; the catalyst I contains 15%-50% of a modified Y molecular sieve, the catalyst II contains 3%-30% of the modified Y molecular sieve, and the content of the Y molecular sieve in the catalyst I is 10%-25% higher than the content of the Y molecular sieve in the catalyst II. The catalyst I has strong aromatic conversion ability, can convert aromatic hydrocarbons in heavy components into smaller molecules to distribute into the heavy naphtha fractions and aviation kerosene fractions, the catalyst II has strong alkane cracking ability, by synergy of the catalyst II and the catalyst I, the quality of the jet fuel is obviously improved. The hydrocracking method can maximumly produce the high quality jet fuel.

The invention discloses a hydrogenation transformation method of poor quality diesel distillate. The poor quality diesel distillate and hydrogen pass the reaction area which contains hydrorefining catalyst; the obtained material is separated to obtain hydrogen-rich gas and diesel distillate; the hydrogen-rich gas and the diesel distillate is fed into the hydrogenation cracking reaction area; the separated aviation kerosene distillate is fed into the aviation kerosene hydrorefining reaction area; the gas obtained in the hydrogenation cracking area through the separation of the material stream is for recycle use; naphtha and diesel product are obtained; the obtained aviation kerosene distillate is fed into the aviation kerosene hydrorefining reaction area; the gas obtained through the separation of aviation kerosene hydrorefining material steam is for recycle use and the aviation kerosene product is obtained. The hydrogenation transformation method of poor quality diesel distillate adopts the combination process of hydrorefining and hydrogenation cracking to transform the diesel distillate into high quality naphtha, aviation kerosene and diesel products directly.

The present invention relates to one kind of low fluorescence lubricant for well drilling fluid and its production process. The low fluorescence lubricant is produced through adding aviation kerosene in 50-90 weigh portions and industrial white oil in 15-75 weigh portions into reaction kettle, heating in water jacket furnace to 70-90 deg.c and stirring for 30-60 min, adding sulfur powder in 0.5-2.5 weigh portions, stirring and further heating to 90-100 deg.c, adding oleic acid in 3.5-8.5 weigh portions, stirring for 30-60 min, cooling to 70-80 deg.c, adding polyoxyethylene ether in 3.5-8.5 weigh portions and Span-80 in 0.5-2.5 weigh portions, and further stirring for 30- 60 min. It is used in drilling well and can inhibit the hydrating expansion of clay shale, consolidate well wall and avoid bit freezing. Compared with available technology, the present invention has the advantages of low fluorescence level and no influence on geological logging.

This invention relates to synthetic diesel oil, which is produced by: (1) mixing isooctyl nitrate 30 wt.%, cyclohexylamine 30 wt.%, ferrocene 30 wt.%, and zinc peroxide 10 wt.% to obtain composite additive; (2) mixing fossil-grade diesel oil 10-40 parts and the composite additive 0.3-2 parts to obtain mother diesel oil; (3) mixing 200# solvent oil 10-30 parts and lightweight aviation kerosene 5-20 parts to obtain modified 200# solvent oil; (4) mixing fatty acid methyl ester or C9 10-60 parts, the mother diesel oil and the modified 200# solvent oil to obtain the synthetic diesel oil. The synthetic diesel oil has such advantages as low cost, simple process and abundant raw materials, and can be used for replacing standard fossil-grade diesel oil.

The invention discloses an optical measuring method and device for the spatial distribution of liquid droplets of a fuel nozzle. By using a characteristic that aromatic compounds in aviation kerosene can emit red-shift fluorescence signals under the excitation of ultraviolet light with a wavelength of 266 nm, a correction scheme for solving the problem that the measurement errors of spatial distribution of fuel are caused due to the attenuation of laser energy in a droplet cone is designed. The method and device disclosed by the invention are characterized in that the spatial distribution of the liquid droplets in the fuel droplet cone can be quickly and accurately measured, and have an advantage of flow field noninterference, transient and time average results can be obtained, and a deficiency that only an average result can be obtained by a fuel accumulation method is solved. The optical measuring method for the spatial distribution of liquid droplets of a fuel nozzle disclosed by the invention can be used for measuring the spatial distribution characteristics of the liquid droplets in the droplet cone of the fuel nozzle of an aero-engine or an internal combustion engine, and for fuel which does not contain fluorescent components, a tracer agent is required to be added.

This invention discloses a hydrocracking method, and this invention is used for producing high aromatic hydrocarbon heavy naphtha and high quality end oil.It includes that heavy distillate oil and poor quality catalytic cracking diesel hydrocracks separately, and the mixture of the cracking products is conducted gas liquid separation. Light naphtha, heavy naphtha, aviation kerosene, diesel oil and end oil will be obtained by distillating the liquid phase. The density of the poor quality catalytic cracking diesel oil is above 0.9g/ml, and the aromatic hydrocarbon is over 60wt% and the value of hexadecane is under 30. It is a adequate utilization of catalytic cracking craft to produce high aromatic hydrocarbon heavy naphtha and high quality end oil with heavy distillate oil and poor quality catalytic cracking diesel, which can be separately used as catalytic reforming material and making ethylene material by steam cracking method. High aromatic hydrocarbon heavy naphtha in this invention will produce a large amount of reforming hydrogen after catalytic reforming treatment, which can be used in the process of hydrocracking to make this preparation more ecnomical and reasonable.

The invention relates to a method for preparing C5/C9 copolymerized petroleum resin. The method comprises the following steps of: mixing crude m-pentadiene, crude cyclopentadiene and selectively hydrogenated and pretreated C9 material D uniformly, performing pre-polymerization at the temperature of between 180 and 230 DEG C to obtain a dimmer mixture F of C10 and C15, blending hydro-cracking aviation kerosene serving as a solvent, performing catalytic polymerization for 2 to 5 hours at the temperature of between 30 and 65 DEG C by using gaseous boron trifluoride as a catalyst to obtain deep yellow to brown polymerization solution, rectifying under reduced pressure to remove the solvent and oligomers, and thus obtaining the C5/C9 copolymerized petroleum resin. The prepared C5/C9 resin is good in compatibility and light in color; the preparation method is reasonable and strong in pertinence; the hue, the compatibility and the thermal stability of the resin are remarkably improved; and the resin can be widely applied in the fields of ink, coating, papermaking, plastics and the like.

The invention relates to a catalyst for preparing aviation kerosene components through one-step hydrodeoxygenation cracking isomerization of grease and a preparation method of the catalyst. The catalyst is mainly used for the process of preparing new-generation ultra-clean aviation fuel oil substitution components through one-step catalytic hydrogenation of grease model compounds, grease and derivatives of the grease. The catalyst provided by the invention is loading noble metal/composite solid acid carrier catalyst which is composed of 0.2-5.0% of Pd, 5-85% of a bata molecular sieve, 10-94.8% of Al2O3. With the adoption of the catalyst, the grease and the grease model compounds can be converted into the biological aviation kerosene components (C8-C16) through hydrogenation, deoxygenation, cracking and isomerization. The catalyst obtained by the preparation method has the advantages of high activity, high selectivity, low hydrogen consumption and the like, and has great significance in promoting development of biological aviation kerosene and reduction of carbon emission; in evaluation for the catalytic activity of the catalyst, the hydrodeoxygenation conversion rate of grease is 100%, and the yield of the aviation kerosene components is 72.3%.

The invention relates to powder metallurgy aviation brake material used for a large scale aircraft. The brake material comprises the following components calculated according to the mass percent: 8 to 18 percent of ferrum, 8 to 16 percent of graphite, 4 to 10 percent of dune sand, 1 to 5 percent of tin, 1 to 3 percent of nickel, 1 to 10 percent of SiC+Al2O3, 1 to 5 percent of molybdenum disulphide, and 50 to 75 percent of copper. The components are mixed evenly and then aviation kerosene is added, the compression sintering process is as follows: the temperature is elevated for two to four hours and held for two to three hours, the holding temperature is 950 to 1020 DEG C, the thermal insulated pressure is 1.5 to 3.0 MPa, and the sintering is protected under the hydrogen atmosphere. The average friction coefficient mu is equal to 0.20 to 0.30, the attrition performance, the system compatibility and the service life, etc. reach or exceed in the performance indexes of an import brake pair.

The invention relates to a method for preparing biological aviation kerosene by using swell-cooked dirty oil. The method comprises the following steps: filtering out slag, desalting, dewatering and decoloring, then conducting fractional distillation, circulating three to five times together with ammonium formate in circulating type microwave reaction equipment under the action of a Pd/Al2O3 catalyst, extracting together with ethyl acetate, then desalting and dewatering, adding into a fractionating tower for fractionating to obtain biological aviation kerosene. The biological aviation kerosene prepared by adopting the method reaches the existing biological aviation kerosene standard, the shortage of biological aviation kerosene can be effectively overcome, the recovered swell-cooked dirty oil can avoid polluting the environment, and the resources can be saved.