The invention discloses a preparation method of almond shell-based
biomass hard carbon, which comprises the following steps: cleaning an almond shell material,
drying, and crushing; pre-carbonizing the almond shell
powder, so that the almond shell
powder is preliminarily carbonized into carbon
powder; further crushing, screening,
pickling and
drying the pre-carbonized carbon powder; and performing high-temperature
carbonization on the pre-carbonized carbon powder, and dividing a heating curve into two sections during high-temperature
carbonization to finally obtain the hard carbon material. Crushing and screening are carried out before pre-
carbonization, the shape and size of a
biomass precursor are controlled, the
biomass cracking process of the material is more thorough, the defects of terminal hard carbon are reduced, a gap structure is increased, the capacity of the hard carbon material is increased, and the coulombic efficiency of the first round is improved. In the high-temperature carbonization stage, two different heating rates are adopted, the quick heating mode is adopted in the relative low-temperature stage, the preparation efficiency is guaranteed, the
slow heating mode is adopted in the relative high-temperature stage, the performance of the material is improved, and especially the first-round coulombic efficiency index of the material is improved.