The invention discloses a water-based
formaldehyde-free
adhesive for a
flame-retardant composite board and a preparation method thereof. The
adhesive is mainly prepared from a
fumaric acid-
aluminum complex, a 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-
oxide compound, a microencapsulated
isocyanate and defatted bean flour. During high-temperature
combustion,
isocyanate generated by
decomposition of defatted bean flour and
isocyanate generated by
decomposition of
polyurethane react with
fumaric acid to form an
imine structure, the 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-
oxide and the
imine structure are subjected to an
addition reaction to generate a
nitrogen-containing compound, the
nitrogen-containing compound is thermally decomposed during
combustion to generate
ammonia inert gas, the
combustible gas concentration and the
combustion rate are reduced; the
nitrogen-containing compound is subjected to a nitrogen-containing reaction to form a nitrogen-containing
flame retardant, and the concentration and combustion rate of
combustible gas are reduced. The nitrogen-containing compound is combusted to form a
carbon layer, molten drops are reduced, and the
flame retardant property is improved. The
adhesive prepared by the method improves the
water resistance on the basis of a water-based adhesive, does not contain
aldehyde groups, does not release
formaldehyde to pollute the environment, has good flame retardant property, can effectively slow down the combustion rate of the composite board, and has very high practicability and production value.