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58results about How to "Achieve efficient recycling" patented technology

Recycling method for copper indium gallium selenide (CIGS) waste

The invention relates to a recycling method for copper indium gallium selenide (CIGS) waste. The recycling method comprises the steps that selenium in the CIGS waste is subjected to acidifying, roasting and volatilizing at first, SeO2 gas is reduced through a sodium sulfite solution, and crude selenium is obtained to achieve advance separation of the selenium, so that the problem that the selenium is always difficult to separate in the industry is solved; and then, the rest of three kinds of metal are separated, particularly, gallium-containing alkali liquor produced in the indium separation process and a gallium-containing solution obtained in the gallium separation process are combined, and electrodepositing residual liquor can be returned to the to-be-electrodeposited gallium-containing solution to be subjected to circulatory electrodepositing, so that efficient and circulatory recycling of gallium is achieved. According to the recycling scheme of the recycling method for the CIGS waste, the comprehensive recycling rate of the various materials is much higher than the existing level in the same industry; in addition, production wastewater zero discharge can be achieved in the whole recycling process, and the environment-friendly degree is high; and moreover, the whole recycling process is easy to operate, high in safety and reliability, low in cost and capable of achieving large-scale production easily and has broad application prospects.
Owner:HANERGY MOBILE ENERGY HLDG GRP CO LTD

Method for extracting and recycling scandium and titanium from acid leaching solution containing scandium and titanium

Disclosed is a method for extracting and recycling scandium and titanium from an acid leaching solution containing scandium and titanium. When the acid solution containing both scandium and titanium is processed, scandium is preferentially extracted by making full use of the features that the concentration of the acid leaching solution is relatively high, and the high acidity can restrain iron and titanium and improve the selectivity of organic phosphonic acid extracting agents to scandium, a residue rich in scandium is obtained by the use of a NaOH solution through back extraction, titanium is extracted by the use of amine extracting agents which are high in selectivity to titanium after scandium is extracted, titanium is processed by a NH4Cl-H2O2 mixed solution through back extraction, a back extraction solution concentrates and crystallizes, NH4Cl crystals are separated out, and a solution rich in titanium is obtained. By the adoption of the method, effective recycling of scandium and titanium is achieved, the problem that when scandium and titanium are extracted by the use of the organic phosphonic acid extracting agents and the amine extracting agents respectively under the usual conditions, due to the fact that iron, scandium and titanium are not separated thoroughly, the follow-up separation process is tedious is solved, the process is short, the cost is low, comprehensive recovery of low-concentration scandium and titanium in the acid leaching solution and titanium dioxide production waste acid is achieved, and the method has the advantages of being simple in technological process, high in scandium and titanium concentration ratio, thorough in separation and low in production cost, and free of pollution.
Owner:贵州鑫亚矿业有限公司 +1

Method for recycling iron, indium and tine in zinc volatilizing kiln slag

The invention provides a method for recycling iron, indium and tine in zinc volatilizing kiln slag. The method comprises the following steps: uniformly mixing zinc volatilizing kiln slag and a reducing agent, subsequently feeding the mixture into a rotary furnace to carry out reduction roasting, and at the same time capturing fume generated in the process; furthermore feeding oxidation gas into the rotary furnace, carrying out magnetic roasting and capturing the fume generated in the process at the same time; carrying out air-cooling on remaining materials inside the rotary furnace, grinding ore, and subsequently carrying out low intensity magnetic separation so as to obtain magnetite concentrate. The effective recycling of iron in the kiln slag is realized through the steps, and tail slag contains copper. The recycling rates of the iron, the indium and the zinc can be respectively 75-85%, 85-93% and 86-95%; through low intensity magnetic separation, the iron grade of the iron concentrate is improved while ensuring the recycling rate of the iron, the effective recycling of an iron resource is achieved, and the iron grade of the iron concentrate is improved to be 70-75% finally; the process is short, the operation is simple and feasible, economic cost is low and metal comprehensive recycling rate is high, a conventional process order of separation-first and smelting-later is broken, and the comprehensive utilization rate of a secondary resource is improved.
Owner:ZHAOQING FEINAN METAL

Cooking range generating steam by using waste heat

The invention relates to a cooking range generating steam by using waste heat. The cooking range a furnace body, a furnace head and a water tank, wherein the furnace body is combined by an inner furnace wall and an outer furnace wall; a hollow region surrounded by the inner furnace wall is a hearth; a plurality of tubular fire bars are uniformly arranged below the hearth at intervals in the furnace body; the furnace head comprises an outer furnace ring, an inner furnace ring and a pot body supporting ring; the lower end of the inner furnace ring is connected to the inner furnace wall; the lower end of the pot body supporting ring is connected to the outer furnace wall; a cavity among the inner wall furnace, the outer wall furnace and the furnace head is a heating cavity; a coil surrounding the hearth is arranged in the heating cavity; a steam pipe communicating with the top of the heating cavity is arranged in the upper part of the water tank; a water outlet pipe communicating with the bottom of the heating cavity is arranged in the lower part of the water tank; a gas outlet pipe is arranged on the top of the water tank; a water inlet is formed between the steam pipe and the water outlet pipe on the water tank; and a float ball water inlet valve is arranged on the water inlet. The cooking range provided by the invention realizes efficient recovery of smoke heat and automatic control of water inflow in a stove using process.
Owner:JIANGSU SHENGONG STOVE CO LTD

Method for extracting valuable metals from mixed manganese-rich waste leachate of lithium ion battery

The invention discloses a method for efficiently separating valuable metals from mixed manganese-rich waste leachate of a lithium ion battery. The method comprises the following steps: firstly, nickel-cobalt components are selectively precipitated and separated from a manganese-rich solution with a precipitation method; then, by aid of difference of complexing bonding of ammonia with cobalt and nickel and of a precipitant with cobalt and nickel, an ammonia and ammonium salt mixed solution is adopted for selectively dissolving nickel component in nickel-cobalt precipitated sludge, and efficientseparation of nickel and cobalt is realized; finally, manganese component in the solution with nickel and cobalt precipitated is extracted selectively with a solvent extraction method, and efficientseparation of manganese and lithium is realized. According to the provided process of selective nickel-cobalt precipitation-raffinate manganese and lithium extraction and separation-precipitated sludge selective nickel dissolution and nickel-cobalt separation, operation is simple, flow is short, cost is low, and efficient separation and recovery of valuable component elements in the manganese-richleachate of the waste lithium ion battery can be realized.
Owner:广西埃索凯循环科技有限公司

Humidification device and method for textiles

The invention discloses a humidification device and method for textiles, and belongs to the technical field of textiles. The device comprises a humidifying box, the bottom of the humidifying box is provided with a base, and the four corners of the bottom of the base are each provided with a traveling wheel; the upper part and the lower part of an inner cavity of the humidifying box are provided with a humidifying chamber and a water tank respectively, the two outer sides of the humidifying box are provided with a feeding roller frame and a discharging roller frame respectively, and the two outer walls of the humidifying chamber are connected with a feeding port and a discharging port respectively; the top and the bottom of the inner cavity of the humidifying chamber are both provided witha humidifying spraying pipe, the top of the water tank is provided with a water collecting cavity, and the other side wall of a water injection pipeline is connected with a first water pump through acirculating water pipe; a waterproof installation groove is formed in the inner wall of a conveying roller, and a second water pump is arranged in an inner cavity of the waterproof installation groove. The humidification uniformity of textile fabric is improved, the humidifying efficiency is high, and wastewater is filtered, so that effective recycling of the wastewater and reasonable utilizationof resources are achieved.
Owner:尹义娜

Method for preparing mercury-containing catalyst by combining microwave with ultrasonic regenerated coal

The invention relates to a method for preparing a mercury-containing catalyst by combining microwave with ultrasonic regenerated coal, and belongs to the technical field of recycling of coal preparedwaste mercury catalysts. The method comprises the following steps: uniformly mixing a coal prepared waste mercury catalyst with ammonia water to obtain a mixture A; under ultrasonic conditions, carrying out leaching reaction on the mixture A for 20 to 240 minutes, filtering and drying; carrying out microwave drying on the obtained product under the conditions of 50 to 150 DEG C for 5 to 30 minutes; carrying out microwave heating under the conditions of 150 to 400 DEG C for 5 to 120 minutes to obtain a mercury demercurated waste catalyst and Hg vapor; condensing and recycling the obtained Hg vapor to obtain liquid pure mercury; introducing activated gas and carrying out microwave activation on the obtained mercury demercurated waste catalyst under the conditions of 500 to 800 DEG C for 10 to 100 minutes to obtain activated carbon for a regenerated mercury waste catalyst. The method disclosed by the invention has the advantages of simple overall process flow, low cost of raw materials, capability of achieving the regeneration of the activated carbon and efficient recovery of mercury, economic value and actual production significance.
Owner:KUNMING UNIV OF SCI & TECH

Resourceful treatment method of high-sulfur copper tailings, and product and application thereof

The invention provides a resourceful treatment method of high-sulfur copper tailings, and a product and application thereof, and relates to the technical field of resourceful treatment of tailings. The resourceful treatment method of the high-sulfur copper tailings includes the steps of desulfurizing the high-sulfur copper tailings to obtain sulfur concentrate and tailing pulp A; treating the tailing pulp A to obtain building sand and tailing pulp B; and treating the tailing pulp B to obtain a cement active admixture. According to the resourceful treatment method of the high-sulfur copper tailings, and the product and application thereof, all-component efficient recycling of the high-sulfur copper tailings is achieved while the adverse effect of sulfur-containing components in the high-sulfur, fine-fraction and high-moisture copper tailings which are difficult to utilize on downstream resource utilization products is avoided, and the raw material supply pressure of the building sandstone and cement industry is effectively relieved while the tailings treatment problem is solved; and meanwhile, the resourceful treatment method of the high-sulfur copper tailings does not generate secondary waste, and is suitable for industrial production.
Owner:铜陵有色金属集团股份有限公司 +1

Intelligent bait casting device capable of identifying fish schools and recycling remnant bait and using method

The invention discloses an intelligent bait casting device capable of identifying fish schools and recycling remnant bait and a using method. The device comprises a material carrying cover, a bait binis arranged at the bottom of the material carrying cover, a water storage tank is arranged below the bait bin, the water storage tank is connected with a water pumping and draining device, a fish finder is arranged at one side of the material carrying cover, and a net door is arranged in the middle of the material carrying cover. An upper inner net is arranged at the top of the material carryingcover, a lower inner net is arranged at the bottom of the material carrying cover, and a plurality of light bait suction pumps and heavy bait suction pumps are arranged in the bait bin. By means of the device, quantitative bait casting can be conducted according to the fish schools, effective recycling of the remnant bait is achieved, the utilization rate of resources is increased, pollution of the bait to water and bottom mud of a culture pond can be reduced, and the culture environment is improved; and secondly, the device is convenient to operate, high in flexibility, wide in feeding area and high in use efficiency, and reference can be provided for mechanical and intelligent application of aquaculture in China.
Owner:HOHAI UNIV

Method for preparing highly pure zinc sulfate heptahydrate from zinc-containing blast furnace gas sludge

The invention relates to a method for preparing highly pure zinc sulfate heptahydrate from zinc-containing blast furnace gas sludge, and belongs to the technical field of comprehensive utilization of metallurgical resources. The method comprises the following steps: breaking, drying and grinding block zinc-containing blast furnace gas sludge, adding the ground zinc-containing blast furnace gas sludge to a sulfuric acid solution to carry out acid dipping, carrying out solid-liquid separation to obtain filter residues and a filtrate, adding a hydrogen peroxide solution and limestone to the filtrate in order to carry out oxidation, neutralization and iron precipitation, filtering the obtained filtrate to obtain iron-containing residues used for iron recovery and an iron removed solution; adding ZnF2 powder to the iron removed solution, stirring, reacting and precipitating the iron removed solution and the ZnF2 powder for 1-2 h, and filtering the obtained solution to obtain calcium and magnesium residues and a zinc sulfate solution; and sequentially carrying out evaporative concentration, cooling crystallization, dehydration and air drying on the zinc sulfate solution to obtain the highly pure zinc sulfate heptahydrate, and returning a mother liquor obtained in the dehydration process to the evaporative concentration process. The method effectively recovers the valuable element zinc from the blast furnace gas sludge, and allows the highly pure zinc sulfate heptahydrate to be prepared.
Owner:KUNMING UNIV OF SCI & TECH

Neutralizing and concentrating device used for monoammonium phosphate production and using method thereof

The invention discloses a neutralizing and concentrating device used for monoammonium phosphate production and a using method thereof. Specifically, the bottom of a reactor is connected with a steam heat exchanger through a circulating pump; the steam heat exchanger is connected with a tubular reactor; the tubular reactor is connected with the top of the reactor through a reaction slurry circulating tube; the upper part of the reactor is equipped with an extracted residual acid conveying tube; the middle part of the reactor is connected with a high-pressure pump through a high-pressure pump conveying tube, and the slurry is fed to a powder spraying tower. Extracted residual acid or concentrated phosphoric acid performs neutral reaction with gas ammonium, so that monoammonium phosphate which meets powder-spraying indexes is conveyed to the powder spraying tower through the high-pressure pump to obtain a monoammonium phosphate finished product. When a slurry method is used for producingmonoammonium phosphate from extracted residual acid, concentration of acid needs to be reduced for follow-up production as concentration of the extracted residual acid is too high, so that steam consumption amount of slurry concentration can be reduced while the monoammonium phosphate product is produced through the slurry method; and 43200 tons of steam is saved per year according to the extracted residual acid consumption amount, so that the annular saved steam amount reaches economic benefits of 7.78 millions of yuan.
Owner:YIDU XINGFA CHEM COMPANY

A clean production method for reusing residual activated sludge in a sewage treatment plant

Disclosed is a sanitary production method for recycling residual activated sludge in a sewage treatment plant. The method comprises the steps that residual activated sludge in a secondary sedimentation tank of the urban sewage treatment plant is naturally sedimented to reach the sludge sedimentation ratio of 50-60% and then directly added into an aeration stirring tank through no pretreatment, aeration stirring treatment is performed for 110-120 h, and then natural sedimentation is performed; 2, a supernate obtained through natural sedimentation is drained into an MAP sedimentation reactor, the P / Mg / N molar ratio is adjusted to be 1 / 1.2 / 1 by adding a magnesium salt solution and a phosphor salt solution, the pH value of a reaction solution is adjusted to be 8.9+ / -0.1 through 5M NaOH, a supernate obtained after sedimentation is drained into an anaerobic adjusting tank, and generated sediments are discharged into a separation recycling device; 3, sedimentation bottom mud obtained after natural sedimentation in the step 1 is discharged into the anaerobic adjusting tank, a supernate obtained after MAP sedimentation in the step 2 is drained into the anaerobic adjusting tank, and then further fermentation is performed to produce methane and recycle energy. Operation is convenient and easy to implement, no new chemical substances are introduced, follow-up slurry anaerobic digestion treatment is facilitated, and the recycling cost of phosphorus resources and energy is low.
Owner:GUANGDONG UNIV OF PETROCHEMICAL TECH

Method for selectively extracting cobalt and nickel from nickel sulfide concentrate

PendingCN113430370ALow leaching temperatureReduce leaching energy consumptionCobalt sulfatesNickel sulfatesPhosphateSlag
The invention provides a method for selectively extracting cobalt and nickel from nickel sulfide concentrate. The method comprises the following steps: metal elements in the nickel sulfide concentrate are selectively leached through a superfine grinding-oxygen pressure leaching process to obtain nickel sulfide concentrate leachate, wherein the metal elements at least comprise copper, iron, cobalt, nickel, magnesium and calcium elements; phosphate is added into the nickel sulfide concentrate leachate to generate iron phosphate slag and phosphate slag precipitates so as to remove iron ions and copper ions in the leachate; sodium fluoride is added as a precipitant to carry out precipitation reaction so as to remove calcium ions and magnesium ions in the leachate; and cobalt ions and nickel ions are extracted and separated through an extraction process correspondingly to prepare a cobalt sulfate product and a nickel sulfate product. According to the method, efficient recycling of the nickel element in the nickel sulfide concentrate is achieved, other metal elements are further utilized to reduce environmental pollution, and the resource utilization rate and the utilization value of raw materials are improved.
Owner:NAT ELECTRIC POWER INVESTMENT GRP YELLOW RIVER UPSTREAM HYDROPOWER DEV CO LTD +3

A neutralization and concentration device and method for use in the production of monoammonium phosphate

The invention discloses a device for neutralization and concentration in the production of monoammonium phosphate and a method for using it. Specifically, the bottom of the reactor is connected with a steam heat exchanger through a circulation pump, the steam heat exchanger is connected with a tubular reactor, and the tubular reactor undergoes reaction The slurry circulation pipe is connected to the top of the reactor; the upper part of the reactor is provided with a feeding pipe for raffinate; the middle part of the reactor is connected to the high-pressure pump through the slurry-to-high-pressure pump delivery pipe and then sent to the powder spraying tower. Neutralize raffinate or concentrated phosphoric acid with ammonia gas to obtain monoammonium phosphate slurry that meets the powder spraying index, and then use a high-pressure pump to transport it to the powder spraying tower to obtain monoammonium phosphate products. Solve the technical problem that when using raffinate acid to produce monoammonium phosphate products by slurry method, because the acid concentration of raffinate acid is too high, the acid concentration needs to be reduced before subsequent production can be carried out, which can save the time for producing monoammonium phosphate products by slurry method According to the current raffinate consumption, the steam consumption for slurry concentration can save 43,200 tons of steam per year, and the direct economic benefit of saving steam consumption is 7.78 million yuan.
Owner:YIDU XINGFA CHEM COMPANY

Coal gangue grading and quality-grading pyrolysis decarburization and waste heat gradient utilization system and operation method

The invention discloses a coal gangue grading and quality-grading pyrolysis decarburization and waste heat gradient utilization system and an operation method, and the coal gangue grading and quality-grading pyrolysis decarburization and waste heat gradient utilization system comprises a pyrolysis furnace used for inputting coal gangue and carrying out pyrolysis; an air preheater; the decarburization furnace is used for inputting preheated air; the combustion device is used for inputting pyrolyzed solid materials for combustion decarburization; the pyrolysis gas input device is used for inputting pyrolysis gas and combusting in the oil-gas combustor; the decarburization furnace is used for outputting decarburized ash and flue gas; a slag cooler; a waste heat boiler; heat-exchanged flue gas output by the waste heat boiler is used as a heat source for pyrolysis of the pyrolyzing furnace, and flue gas used after pyrolysis is used as a heat source for preheating of the air preheater. According to the invention, superior combustion conditions are ensured through graded and quality-divided utilization of pyrolysis oil gas and solid materials and gradient utilization of waste heat, and the technical problems of stable ignition and sufficient decarburization of large-scale direct combustion of full-grade coal gangue in the prior art can be solved.
Owner:XI AN JIAOTONG UNIV
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