The invention belongs to the field of waste
lithium iron phosphate battery recycling, and particularly discloses a method for recycling
phosphorus, iron and
lithium in
lithium iron phosphate black
powder, which comprises the following steps: S1, leaching the
lithium iron phosphate black
powder by
dilute acid, and carrying out filter pressing to obtain an acid leaching solution; s2, alkali liquor is added into the pickle liquor to adjust the pH value,
ferric phosphate is precipitated, and
ferric phosphate dihydrate and
ferric phosphate precipitated liquor are obtained through filtering; s3, adding caustic soda liquid into the
iron phosphate precipitation post-liquid to adjust the pH value, filtering to obtain
lithium phosphate and a
lithium phosphate precipitation post-liquid, returning the filtered
lithium phosphate to S1 for acid leaching, and supplementing
phosphorus and enriching lithium; and S4, carrying out MVR concentration on the lithium phosphate
precipitation solution to enable the lithium to reach a certain concentration, adding the lithium phosphate precipitation solution into a
sodium carbonate solution, and carrying out lithium precipitation and washing to finally obtain a
lithium carbonate product. According to the method disclosed by the invention, the lithium phosphate is returned to the acid leaching section to be leached without additionally adding a
phosphorus supplementing agent, so that phosphorus can be supplemented for precipitated iron phosphate, the lithium can be enriched, and iron, phosphorus and lithium resources in the
lithium iron phosphate black
powder can be effectively recovered.