The invention discloses an electrolyte mixture, a composition for conductive polymer synthesis and conductive polymer solid electrolytic capacitor formed by using the same. The electrolyte mixture includes a conductive polymer and a nitrogen-containing polymer. The nitrogen-containing polymer includes a cyclic nitrogen-containing polymer, a polymer with primary amine group, a polymer with secondary amine group, a polymer with tertiary amine group, a polymer with quaternary ammonium group, or a combination thereof. The interface impedance between the conductive polymer and the oxide film can be facilitated by additionally providing the cyclic nitrogen-containing polymer, and the filming performance of the conductive polymer can be improved, the conductivity of the conductive polymer can be improved, and by applying the cyclic nitrogen-containing polymer to the solid electrolytic capacitor, the capacitance, the reliability, the voltage resistance performance, and the thermal resistance performance of the solid electrolytic capacitor can be improved, the dissipation factor value, the 120kHz equivalent series resistor, and the service lifetime can be reduced.