The invention discloses a ternary positive
electrode material@
titanium nitride core-shell-structured
composite material, belonging to the technical field of positive
electrode materials of
lithium ion batteries. The
composite material is of a compact double-layer structure, wherein the inner layer is a
nickel-
cobalt-aluminum or
nickel-
cobalt-aluminum ternary positive
electrode material, and the outer layer is a high-
crystallinity titanium oxide TiN; on the basis that the total weight of the
composite material is 100%, the
mass fraction of the inner layer is 30-95%, and the
mass fraction of the outer layer is 5-70%; and the outer layer is
TiN with high
crystallinity, the
crystallinity of the outer layer is not lower than 90%, and the purity of the outer layer is not lower than 99.5%. In addition, the invention also discloses a preparation method of the composite material. Compared with an original ternary positive
electrode material which is not subjected to
coating treatment, the composite material of the invention has the characteristics of remarkably improved
conductivity, relatively high specific capacity, good
cycling stability, improved rate capability and reduced
internal resistance. The preparation method is simple in process, free of
pollution, low in cost, short in flow and easy for industrial amplification.