The invention discloses high-hydrophilic and exothermal
spinning solution for
polyacrylonitrile-based
carbon fibers and a preparation method thereof. The
spinning solution consists of N,N-
dimethyl formamide solution of
monomer and co-
monomer random
copolymer. The preparation method for the
spinning solution comprises the following steps of: adding azodiisobutyronitrile initiator,
acrylonitrile main
monomer, allylimidazolidone co-monomer and N,N-
dimethyl formamide solvent into a reaction kettle with a condensation and mechanical stirring device, stirring and mixing the components at the
room temperature, bubbling the mixture for 10 to 40 minutes by using
nitrogen, then reacting the mixture for 6 to 36 hours at the constant temperature of between 50 and 70 DEG C under the protection of the
nitrogen, and then removing residual monomers and bubbles to obtain the spinning solution with high hydrophilic property and good exothermal property, wherein the main monomer accounts for 94 to 98 percent of the total
mass of the monomers, the co-monomer accounts for 2 to 6 percent of the total
mass of the monomers, the azodiisobutyronitrile accounts for 0.2 to 1.0 percent of the total
mass of the monomers, and the mass total concentration of the monomers is 15 to 35 percent. The weight-average molecular weight of the
copolymer can be controlled to be between 0.1 and 0.35 million, the
contact angle of the
copolymer and the water is about 32.3 degrees, and the spinning solution has good hydrophilic property and low exothermal rate.