The invention relates to a preparation technology of an electrochemical oxidation electrode material, and aims at providing a method for preparing a Ti/SnO2-Sb (titanium/tin dioxide-antimony) electrode by a tricarboxylic organic acid-Sn(II)/Sb(III) complex. The method comprises the following steps of using the pretreated Ti sheet as a working electrode, arranging counter electrodes at both sides in parallel, and respectively soaking the working electrode and the counter electrodes into an electrodeposition solution, wherein the electrodeposition solution is a mixed water solution of stannous dichloride, antimony trichloride, tricarboxylic organic acid and gelatin; connecting a positive pole of a direct current power source and the counter electrodes, and connecting a negative pole and theworking electrode; after the electrodeposition is completed, drying the working electrode at room temperature without cleaning; after drying, warming for 1 to 3h at the temperature of 450 to 650 DEG C, and cooling to room temperature, so as to obtain the electrode product. The preparation technology has the advantages that the operation is simple, the environment-friendly effect is realized, and the cost is low; the electrode surface is uniform and complete, and the covering degree is good; the antimony-doped tin dioxide is uniformly and densely distributed at the electrode surface, the specific surface area is high, and more active sites are provided in the electrochemical oxidation process; the service life of accelerated test of the electrode product is long, and the stability is good.