The invention discloses a preparative gas-phase chromatograph device for separating and purifying a high-boiling-point volatile monomer component, comprising a column temperature tank, a shunting three-way valve, a sample collection device, a post-column heating device, a sample inlet, a vaporizing chamber, a separation system and a detection device, wherein the sample inlet, the vaporizing chamber, the separation system and the detection device are sequentially communicated, the shunting three-way valve, the vaporizing chamber and the separation system are arranged in the column temperature tank, the sample collection device and the post-column heating device are arranged outsides the column temperature tank, the inlet of the shunting three-way valve is communicated with the outlet of the separation system, one outlet of the shunting three-way valve is communicated with the sample collection device through a pipeline, and the post-column heating device comprises an insulation sleeve sleeved on a pipeline and a temperature control device used for detecting and regulating the temperature in the insulation sleeve. The temperature of the pipeline controlled by the post-column heating device is higher than that in the column temperature tank, thereby the high-boiling-point volatile monomer component is difficult to condense when transported to the sample collection device in the pipeline, mixing of components which sequentially flow out is efficiently avoided, and the purity of a preparative target object is enhanced.