The invention relates to an aluminothermic welding method of a seamless steel rail. A welding flux comprises C, Si, Mn, Cr, Ni, Mo, V, aluminum powder and oxide and iron powder, the process comprisesthe following steps of polishing, derusting and dehumidifying a steel rail; preheating the steel rail until the rail head turns red; igniting and preheating the aluminothermic welding flux, and reacting and pouring; after pouring, heating the steel rail at 250-300 DEG C within the position, 500 mm away from the outside of a sand mold frame, of the two sides of the sand mold frame; knob removing,meanwhile, keeping the temperature of the steel rail at 250-300 DEG C within the position, 500 m away from the outside of the sand mold frame, of the two sides of the sand mold; cooling the welded junction to 500 DEG C, performing hot grinding, cooling weld metal part after the hot grinding, keeping the temperature of the steel rail at 250-300 DEG C within the position, 500 m away from the outsideof the sand mold frame, on the two sides of the sand mold frame in the process till the weld metal part reaches 250-300 DEG C, and performing cover heat preservation on the welded junction for 20 min; and removing the cover, and naturally cooling to room temperature. The method ensures the welding quality.