This application relates to a method for preparing
carbamate compounds from dioxazolone derivatives, comprising the following steps: reacting a dioxazolone derivative with a hydroxyl-containing compound in the presence of a catalyst to prepare the
carbamate compound. The catalyst includes one or more of dichlorobis(4-methylisopropylphenyl)
ruthenium(II), tri(acetylacetonate)
ruthenium(III),
cyclooctadiene ruthenium(II)
chloride, and dichloro(pentamethylcyclopentadienyl)
iridium(III) dimers. This synthetic method is universally applicable to the synthesis of
carbamate compounds with different group types (such as
alkyl,
aryl, heteroaryl, etc.), and exhibits high yields and mild
reaction conditions.