207 results about "Potassium alum" patented technology

The invention discloses a method for recovering and preparing alum from activated clay production waste liquid, comprising the following steps of using sulfuric acid, aluminum sulfate in the activatedclay production waste liquid to react with aluminum hydroxide and stronger ammonia water or potassium hydroxide, filtering, evaporating to obtain ammonium alum or potassium alum, purifying, removingimpurities to obtain ammonium alum or potassium alum products with more than 99% of purity. The invention solves the problem existing in the management and recycling method of the activated clay production waste liquid, lowers cost for preparing alum in industry and has the advantages of environment protection, energy conservation and the like.

The invention relates to a method for comprehensively recycling copper, selenium and uranium from a stone coal extraction vanadic acid immersion liquid, which mainly comprises the following steps: crystallizing potassium alum or ammonia alum from stone coal sulfuric acid leach solution to remove aluminum, adding a copper-containing material and a phosphorus-rich material into the solution to regulate the copper concentration and the uranium/phosphorus ratio of the solution, adding an alkali to regulate the pH value, and adding a reducer to reduce and precipitate copper, selenium and uranium in the solution, thereby implementing efficient separation and enrichment of the copper, selenium and uranium in the stone coal vanadium extraction process. The invention has the advantages of simple technique, high copper/selenium/uranium recycling rate, low reagent consumption, low recycling cost, environment friendliness and the like.

The invention relates to multifunctional waterproof anti-leakage liquid for cement mortar, which is prepared from 60 to 70 weight parts of stearate solution, 20 to 30 weight parts of modified water-glass solution, 5 to 1 weight part of beta-naphthalene sulfonic acid formaldehyde condensation sodium salt and 900 weight parts of water, wherein the stearate solution is prepared from stearic acid, soda ash, ammonia water, potassium hydratem sodium chloride and water, the modified water-glass solution is prepared from polyvinyl alcohol, sodium silicate solution, potassium alum, dibutyl phthalate and water. The invention overcomes the defect of the reduced cement mortar strength of other rigid waterproof agents, has good waterproof effect, avoids the fault caused by the adding amount which can not be easily mastered, and has low price, simple production and low cost. The plastering mortar mixed with the product has excellent spreading performance and work degree of satisfaction.

The invention relates to a method for preparing high-purity vanadium pentoxide by use of a stone coal one-step method. The technical solution is as follows: a fluidized bed furnace for one-step roasting of stone coal is adopted to perform one-step fluidized bed roasting on the stone coal; roasted materials are leached in three segments, final pickling slurry is subjected to primary separation so as to obtain final pickle liquor, secondary overflow is returned to be subjected to primary size mixing, and tertiary overflow is returned to be subjected to secondary size mixing; the pH value of the final pickle liquor is regulated, and slags obtained after regulation are returned to a segment III so as to be leached; the regulated pickle liquor is crystallized to obtain a potassium alum byproduct; after crystallization, the liquid is subjected to reduction and precipitation-based impurity removal, and filter residues are dried to obtained a ferrous oxalate byproduct; after impurity removal, pH value regulation is performed on the liquid by use of weak acid salt, then counter-current extraction is performed on the liquid, and extraction raffinate is returned to be subjected to tertiary size mixing; after being washed, the loaded organic phase is subjected to countercurrent reverse extraction; a lean organic phase is regenerated and then is returned to be extracted; after a vanadium-rich solution is oxidized, urea is added, stirring is performed, the obtained molybdenum precipitation mother solution is returned to be subjected to primary size mixing, and ammonium polyorthovanadate is calcinated to prepare vanadium pentoxide. The method has the characteristics of short process flow, less pollution, low energy consumption, less chemical usage, high vanadium recovery rate and high product purity.

The invention relates to a method for producing alum by utilizing alunite, comprising the steps that alunite mineral powder is selected and used, the mineral powder is dehydrated by microwave roasting, sulfuric acid solution is leached and dissolved out, the filtering separation is carried out, the leaching agent is evaporated and concentrated, and the leaching agent is cooled and alum is crystallized. Potassium sulphate is added to the leaching agent, and potassium alum is completely produced; potassium sulphate is not added to the leaching agent, potassium alum is produced, and aluminum sulfate is co-produced; and crystallization mother liquor is recycled. Compared with the existing alum refining technology adopting 'water immersion method' and a vertical coal kiln, the method for producing alum by utilizing alunite has the beneficial effects that the utilization rate of resources is improved, the yield of alum is increased, the production cycle of the alum is shortened, energy sources are saved, the production cost is reduced, waste residues and waste gases are reduced, and the environment is protected.

The invention relates to an impurity removing method for a vanadium contained leaching agent. According to the technical scheme, potassium sulphate is added into the vanadium contained leaching agent according to the mass ratio of the potassium sulphate to aluminum in the vanadium contained leaching agent being (2.5-4.0):1, crystallization is carried out, primary solid-liquid separation is carried out, and liquid obtained after crystallization and potassium alum are obtained. A reducing agent is added into the liquid obtained after crystallization according to the ratio of the amount of total matter in the reducing agent to the amount of the Fe(III) matter in the liquid obtained after crystallization being (1.5-3.5):1, stirring is carried out, and liquid obtained after reducing is obtained. A precipitator is added into the liquid obtained after reducing according to the ratio of C2O4<2-> matter in the precipitator to the amount of iron matter in the liquid obtained after reducing being (2-15):1, stirring is carried out, secondary solid-liquid separation is carried out, and the vanadium contained leaching agent obtained after impurity removing and filter residues are obtained; the vanadium contained leaching agent obtained after impurity removing is used for the follow-up vanadium enrichment process; and the filter residues are dried, and therefore the oxalates compound by-products of iron are obtained. The impurity removing method has the beneficial effects of being good in vanadium and impurity ion separating effect, simple in process, small in reagent consumption, low in vanadium loss rate and capable of achieving resource utilization.

The method for preparing lithium carbonate from lepidolite comprises the following steps: take lepidolite (100-500 mesh), add 98% concentrated sulfuric acid in a mass ratio of 1: [0.8-3], stir, and dry step by step to obtain clinker , and crush the clinker into 100-500 mesh, add water to soak, stir, and boil to obtain a mixed solution; centrifuge the mixed solution while it is hot to obtain mother liquor A, cool the mother liquor A in a reaction vessel to 20-80°C, and crystallize Rubidium cesium alum is extracted, and then centrifuged to obtain mother liquor B; the mother liquor B is cooled to -30~20°C in the reaction vessel, potassium alum is crystallized, and then centrifuged to obtain mother liquor C; mother liquor C is neutralized with lye to the pH value After centrifugation, the mother liquor D is obtained, and then the mother liquor D is evaporated and concentrated, and then filtered to obtain the mother liquor E; the mother liquor E is mixed with potassium carbonate or sodium carbonate solution, heated to 80-100°C, and completed under stirring. That is, the crude product of lithium carbonate is prepared, and the crude product is centrifuged, washed and dried to obtain the finished battery grade lithium carbonate. The invention improves the leaching rate of lithium, saves raw materials, generates less slag, and lowers requirements on equipment.

The invention discloses a comprehensive utilization method for a waste aluminum-plastic paper composite packing material. The method comprises the following steps: crushing, cleaning and drying the waste aluminum-plastic paper composite packing material; heating, pyrolyzing and gasifying the dried material in a vacuum high-pressure high-temperature kettle, and performing low temperature curing recovery; putting the pyrolyzed and gasified aluminum-plastic paper mixed material into a reaction kettle, adding a caustic potash solution for reaction, and recovering the generated hydrogen serving as a special fuel; neutralizing the rest material by using dilute sulfuric acid, and performing filter pressing and washing to obtain a filter cake, namely the available water pulp; and filtering off the water pulp, evaporating and crystallizing the obtained filtrate, and centrifuging to remove residue so as to recover potassium alum with wide application.

The invention provides an application of AK sugar crystal mother liquor produced by a sulfamic acid-sulfur trioxide method, which is a sylvite preparation by using crystal mother liquor, and a method for preparing sylvite by using AK sugar crystal mother liquor. The method comprises the following steps: mixing crystal mother liquor and organic acid or inorganic acid, keeping a mixture in an acidic property, cooling, filtering, and recrystallizing to obtain sylvite. The sylvite is prepared by the AK sugar crystal mother liquor which is originally taken as waste water for discharging by using the sulfamic acid-sulfur trioxide method. The sylvite comprises inorganic salts, such as potassium sulfate; organic salts, such as potassium oxalate; even double salts, such as potassium alum. The obtained sylvite can be a product for sale, so that the production cost of AK sugar can be reduced. Simultaneously, the potassium content in waste water can be reduced and the environmental pollution caused by waste water is minimized. The invention aims at reducing the cost of AK sugar, minimizing the environmental pollution caused by waste water from the process, raising the economic, social and environmental benefits of AK sugar production process by using the sulfamic acid-sulfur trioxide method.

The invention relates to a method for processing chestnut in syrup, belonging to the technical field of methods for processing food. The invention aims at providing a method for preserving a high sugar degree can under the condition of high temperature sterilization so that the high sugar degree can is kept in a certain water holding state for a long time. The technical scheme of the invention is as follows: chestnut is cleaned, shucked and sliced into a jewel shape, and the original color is maintained; precooking and rinsing: 0.15 percent of potassium alum and 0.15 percent of disodium ethylene diamine tetraacetate need to be added to precooking solution, and the mixture is rinsed in circulating water; liquid syrup preparation: liquid syrup of which the syrup content is 50 percent is prepared; and air exhaust and can seal: a can is led into an exhaust box and then is processed by the steps of heating and air exhaust for 40 minutes, so as to lead the central temperature in the can to be no less than 85 DEG C, and finally the can is sealed. The preparation method of the invention has the advantages of easy operation and simple process, and contributes to the fresh keeping.

The invention relates to a method for producing potassium sulphate and aluminium chloride by utilizing potassium alum. According to the method, the selected materials are the potassium alum, potassium chloride and water as a solvent, and the weight ratio of the potassium alum and the potassium chloride is 1.5-2.5:1. The produduction method comprises a stage for preparing the potassium sulphate through a potassium alum/ potassium chloride complex decomposition reactive crystallization method, and a stage for preparing the aluminium chloride through evaporation and concentration crystallization, wherein the potassium sulphate preparation stage can be carried out for one time or several times circularly; during the stage, the replacement reaction temperature is larger than or equal to 60 DEG C, the reaction time is larger than or equal to 20min, the solid-liquid separation and insulation temperature is larger than or equal to 50 DEG C, and the evaporation and concentration crystallization temperature is larger than or equal to 90 DEG C. Compared with the existing method for producing the potassium sulphate and the aluminium chloride by utilizing the potassium alum, the method has the beneficial effects of short technological process (one-step conversion), easiness in solid-liquid separation, low energy consumption, no environment pollution, low production cost, easiness in industrialization implementation, high material utilization ratio and the like.

The invention discloses a method of extracting aluminium hydroxide from potassium- and aluminium-containing ores. The method comprises the following process steps: reacting the potassium- and aluminium-containing ores in a reaction system containing sulphur acid, obtaining a leaching solution containing aluminium sulphate and potassium sulphate through solution leaching and liquid-solid separation, separating out the crystal of potassium alum by lowering the temperature, carrying out a slurry mixing reaction with lime and water to obtain gypsum residue containing aluminium hydroxide, carrying out a leaching reaction with the aluminium hydroxide solution, cooling and diluting the slurry to obtain a sodium aluminate solution, adding a seed crystal, and cooling and crystallizing to obtain an aluminium hydroxide crystal. The method disclosed by the invention realizes the purpose of comprehensively extracting aluminium, potassium and by-product semi-hydrated gypsum from the potassium- and aluminium-containing ores, realizes the comprehensive utilization of the ores, and has a high aluminium yield and good comprehensive benefits.

A health-care and nutritive sheet jelly is proportionally prepared from lotus root starch, lotus seed powder, cassava starch, water and potassium alum.

The invention relates to a method for preparing high-purity potassium alum and aluminum sulfate from alunite ore. The method comprises the following steps: firstly, roasting the alunite ore to remove crystal water; secondly, performing sulfuric acid leaching on dehydrated alunite to obtain aluminum and potassium, and crystallizing the potassium alum in leaching liquid; thirdly, adding a certain quantity of acid into crystallization mother liquid, returning to a circulating leaching process, and crystallizing the potassium alum in circulating leaching liquid; and finally, crystallizing the aluminum sulfate in potassium alum crystallization mother liquid circulated for a certain number of times. The purpose of the invention is to provide the method for preparing the high-purity potassium alum and the aluminum sulfate from the alunite ore, which is simple in process, low in production cost and easy to industrialize in allusion to the comprehensive utilization problem of the alunite ore.

It is undoubtedly a good way to kill two birds with one stone by using waste aluminum cans to produce new energy hydrogen and environmental protection products potassium alum. Hydrogen has many uses. Hydrogen burns in oxygen and releases a lot of heat. The temperature of its flame-oxygen flame reaches 3000°C, which can be used for welding or cutting metals. As a fuel, hydrogen has the characteristics of abundant resources, high combustion calorific value and less pollution. Potassium alum plays an important role in water purification, paper sizing, paint printing and dyeing, lake pigment pharmaceuticals, paint making, tanning, fiberboard processing, as well as rubber and metallurgy, colored glass, food industry, agriculture, etc. . The invention uses waste aluminum cans as raw materials, produces hydrogen through potassium hydroxide solution, further neutralizes potassium aluminate solution with sulfuric acid, and obtains high-quality potassium alum through crystallization, filtration, washing and centrifugal dehydration. The invention not only eliminates pollution, but also can achieve the purpose of turning waste into wealth and utilizing waste, and is a good method that kills two birds with one stone.

The present invention relates to a composition for improving the health status of various joints in the human body. The composition includes at least one plant extract as fatty base with active role, at least one extract from plants with anti-microbial properties, at least one extract from plants with analgesic and/or anti-inflammatory properties, and at least one extract from plants with anti-rheumatic and regenerative properties, to which dimethylsulfoxide, allantoin and/or potassium alum may be added. The composition may be used to treat osteoarthritis, rheumatic joint disease, joint swelling, pain, hallux valgus, traumatic conditions of the joints including sprains, strains, post-surgical recovery, bone edema, and speed up the recovery of athletes post-injury.

The invention provides a method of separating and recovering aluminum, potassium, and ammonium from a mixed solution containing aluminum sulfate, potassium sulfate, and ammonium sulfate. The method comprises following steps: evaporating and condensing the mixed solution, cooling the condensate to carry out crystallization to obtain mixed crystals of potassium alum and ammonium alum, burning the mixed crystals at a high temperature to prepare alumina, and recovering potassium sulfate and ammonium sulfate at the same time. The provided method can efficiently recover aluminum, potassium, and ammonium, and obtains high purity alumina, potassium sulfate, and ammonium sulfate, furthermore, the energy consumption is low, the investment is little, the production is carried out in an enclosed environment, no waste solid, waste gas or wastewater is discharged, the devices are easy to enlarge, and the industrial application prospect is good.

The invention discloses a method for producing potassium alum by utilizing industrial leftovers, namely waste aluminum residues. The method comprises the following steps: (1) preparing aluminum residue slurry by using the waste aluminum residues; (2) enabling the aluminum residue slurry to react with concentrated sulfuric acid so as to generate aluminum sulfate crude liquor; (3) performing settling separation on the aluminum sulfate crude liquor; (5) cooling and crystallizing the aluminum sulfate crude liquor; and (6) washing, airing and packaging, thereby obtaining the finished potassium alum product. According to the method disclosed by the invention, the waste aluminum residues are taken as raw material, the production cost is saved, the amount of waste residues is small, the additional benefits can be brought, and wastewater can be recycled; and moreover, the method is simple in process, convenient to operate, high in safety, low in energy consumption and low in production cost and is suitable for large-scale production.

The invention relates to a preparation method of aluminum borate whisker, and particularly relates to a preparation method of the aluminum borate whisker. The preparation method of the aluminum borate whisker comprises the following steps of (1) pretreating alumen: calcining the alumen for 2-6 hours at a temperature of 250-350 DEG C, grinding or ball-milling and screening with a 120-mesh sieve; (2) mixing auxiliary materials: mixing pretreated alumen with boric acid and a fluxing agent by fully grinding or ball-milling, wherein a molar ratio of the pretreated alumen to boric acid is (1-4.5):1 and a molar ratio of the pretreated alumen and boric acid to the fluxing agent is 1:(0.5-2); and (3) tabletting the auxiliary materials: putting the mixed auxiliary materials in a mold with a diameter of 10-30 mm, regulating a pressure to 20-80 kN, tabletting the auxiliary materials to obtain a cylindrical auxiliary material; and sintering, leaching and drying the cylindrical auxiliary material to obtain the aluminum borate whisker. The preparation method is simple in process; the produced aluminum borate whisker has excellent qualities; an alum mineral product of alumen and boron resource in Qarhan salt lake are fully utilized; production cost is reduced; and the preparation method has wide industrialization prospects.

The invention discloses a method for preparing potassium alum by utilization of activated clay production waste water, and belongs to the activated clay waste water processing and inorganic salt preparation technology fields. Sulfuric acid and aluminum sulfate in activated clay production waste water are reacted with aluminum hydroxide and potassium sulfate, and a potassium alum product with a purity of more than 99.5% is prepared after steps of impurity removal, crystallization, press filtration, dewatering and the like. Activated clay waste water can be processed effectively, sulfuric acid and aluminum sulfate in activated clay production waste water can be utilized fully, and purposes of energy saving, emission reduction and changing waste into valuables are achieved. When the method is compared with the prior art, potassium sulfate with a lower price is employed to replace potassium hydroxide, and the production cost is low. centrifuge dewatering is employed to replace heating dewatering, the production efficiency is high, and the cycle is short. Through technology optimization, the purity of potassium alum is high.

The invention discloses a method for CO2 mineralization with blast furnace slag and co-production of aluminum ammonium sulfate. The method comprises the following steps: 1, ammonium sulfate decomposition of blast furnace slag: mixing blast furnace slag and ammonium sulfate at a certain temperature and roasting to convert valuable metal oxide in the blast furnace slag into corresponding ammonium sulfate complex salt; 2, preparation of aluminum ammonium sulfate crude liquor: leaching the roasted product obtained in the step 1 by the use of water so as to obtain aluminum ammonium sulfate crude liquor and leaching residue; 3, cooling for crystallization: cooling the aluminum ammonium sulfate crude liquor to obtain crystallization mother liquor and aluminum ammonium sulfate crystals, washing and airing to obtain aluminum ammonium sulfate; 4, magnesium-rich solution mineralization: adding ammonia water into the crystallization mother liquor obtained in the step 3 and introducing CO2 to generate magnesium carbonate so as to realize CO2 mineralization and obtain first mineralization mother liquor; 5, leaching residue mineralization: adding ammonia water into the leaching residue obtained in the step 2 and introducing CO2 to generate calcium carbonate so as to realize CO2 mineralization and obtain second mineralization mother liquor; and 6, ammonium sulfate circulation: mixing the mineralization mother liquors, carrying out evaporative concentration and cooling for crystallization so as to obtain ammonium sulfate solids and recycling.