The invention relates to the technical field of organic
chemical synthesis, in particular to a method and a
system for efficiently synthesizing
diphenyl carbonate. The method comprises the following steps: taking
phenol and carbonic ester as raw materials, taking a multi-
metal vanadium oxide compound as a catalyst, and reacting in a high-temperature reaction kettle with a mechanical stirring and condensation
reflux device and a kettle bottom gas
distributor; carbonic ester is continuously injected from the bottom of the high-temperature reaction kettle along with
inert carrier gas, unreacted carbonic ester is refluxed through fractional condensation, and a byproduct
alcohol is discharged along with the
inert carrier gas; the carbonic ester is
dimethyl carbonate or
diethyl carbonate; the dosage of the catalyst is 0.5-5wt% of the
mass of the
phenol raw material According to the invention, through
continuous feeding and specific
condensation temperature control, selective condensation
reflux of raw materials (carbonic ester) and selective removal of by-products (alcohols) are realized, reversible balance of ester exchange reaction is effectively broken, forward proceeding of the reaction is greatly promoted, and
phenol conversion rate and reaction efficiency are significantly improved.