The invention discloses a phase state analysis method of Pt, Pd and Au in black rock-type platinum group minerals, combining the mineral composition of black rock, the enrichment form of precious metal elements in such minerals and the properties of precious metal elements, and referring to The analysis method of the active state of platinum, palladium and gold divides the occurrence phases of Pt, Pd, and Au in black rocks into four phases: exchangeable phase, organic binding phase, sulfide binding phase, and residue phase. By developing a new desorbent ─Potassium thiocyanate-sodium cyanide, which inhibits the adsorption of organic matter and carbon to Pt, Pd, and Au in each phase. Use 5% triammonium citrate, sodium pyrophosphate buffer solution, glacial acetic acid-hydrogen peroxide to leach Pt, Pd, and Au in the exchangeable phase, organic binding phase, and sulfide binding phase, and accurately determine the state of each phase by ICP-MS The content of Pt, Pd and Au in the black rock provides a theoretical basis for geological prospecting and comprehensive utilization of precious metal elements in black rock.