160results about How to "No post-processing required" patented technology

The invention provides a preparation method and application of nanosheet self-assembled microflower-shaped VS2. The preparation method comprises the steps that firstly, the pH of a vanadium source solution and the pH of a sulfur source solution are regulated to be 11-14 under the magnetic stirring state through a sodium hydroxide solution; secondly, the solutions are poured into a reaction inner lining, the inner lining is contained in an outer kettle and fixed, and then the outer kettle is placed in a homogeneous reaction instrument; finally, a product obtained after a reaction is cooled, washed, collected and dried, and then the nanosheet self-assembled microflower-shaped VS2 can be obtained. The technology of the method is simple and easy to control, and the prepared nanosheet self-assembled microflower-shaped VS2 is uniform in chemical constitution and high in purity, has a specific self-assembled structure and shows the excellent electrochemical property when the nanosheet self-assembled microflower-shaped VS2 serves as a lithium-sodium ion battery electrode material. In addition, the method has the advantages that the defect that a traditional calcination method is high in temperature is overcome, large equipment and harsh reaction conditions are not needed, the raw materials are cheap and easy to obtain, the cost is low, the yield is high, aftertreatment is not needed, and the method is friendly to the environment and can be suitable for large-scale production.

The invention discloses a formation method of two-color or multi-color jacquard warp knitting cloth. The warp knitting cloth is knitted on a jacquard warp knitting machine. The formation method comprises the following steps that (1) jacquard patterns are designed by the adoption of a computer; (2) knitting is prepared; (3) parameters are input to the jacquard warp knitting machine, knitting is achieved through the machine, and the warp knitting cloth with preset patterns is obtained. The knitted warp knitting cloth can be of two colors or multiple colors, yarns in each color independently form jacquard and other patterns, the appearance is attractive, and the problems of cost and loss increasing, environmental protection, the physical property, quality and the like caused by the fact that the two colors or the multiple colors of the warp knitting cloth is obtained by the adoption of post processing are resolved. Meanwhile, more than seven yarn guide bars are adopted to knit, the formed warp knitting cloth not only has the function of irregular pattern jacquard but also displays different colors of different patterns, patterns of a cloth cover of the warp knitting cloth are complex and changeable, the different colors are mutually combined to form the cloth cover with distinct levels and distinguished in flexibility.

The invention discloses a synthetic method of Ni3S2 microrod array. The synthetic method comprises following steps: 1, nickel foam to be treated is subjected to full ultrasonic cleaning and drying; 2, a vanadium source and a sulfur are dissolved in an appropriate amount of a solvent at a molar ratio of 1: (1-11), and full stirring is carried out so as to obtain a solution A, wherein the concentration of the vanadium source in the solution A is controlled to be 10 to 40mM; 3, the solution A is delivered into a hydrothermal reactor with a polytetrafluoroethylene lining, the nickel foam obtained via pretreatment in step 1 is immersed in the solution A, the hydrothermal reactor is sealed, and solvothermal reaction is carried out at 70 to 200 DEG C for 6 to 30h; and 4, after reaction, the hydrothermal reactor is cooled at room temperature, and an obtained product is washed fully and dried so as to obtain the Ni3S2 microrod array. Operation of the synthetic method is simple; reaction conditions are mild; reaction period is short; the purity of prepared Ni3S2 is high; the morphology is uniform; and excellent electrocatalytic hydrogen evolution performance is achieved.

The invention discloses metal three-dimensional additive manufacturing apparatus and method. The apparatus includes: a jet flow nozzle internally provided with an electric conductor, a film forming nozzle communicated with a high molecular polymer supply source, a gas ejection nozzle communicated with a hot gas source, a cleaning nozzle communicated with a deionized water source, a cathode substrate, an electro-deposition power supply, and an electrolyte cycle filter apparatus. In the apparatus, with scanning movement of the nozzles, the film forming nozzle stacks two rows of film layers on the cathode substrate, the gas ejection nozzle and the cleaning nozzle can rapidly clean and dry the surface of the films, and the jet flow nozzle ejects electrolyte to the zone between the two rows offilm layers on the cathode substrate, thus electro-depositing the metal layer in the localization manner; by increasing the height of the nozzles, the stack film layers and metal layers are added continuously, thus achieving the additive manufacturing of a three-dimensional metal member. The apparatus has simple structure and high efficiency, and can shape the three-dimensional metal member havinghigh compactness and precision.

The invention discloses a preparation method of a cake-piece-shaped N/BiVO4 photocatalyst growing along a high-activity (040) crystal orientation. The method comprises the following steps: mixing a bismuth salt solution with a vanadium salt solution according to a molar ratio Bi:V=1:1, and uniformly stirring to form a mixture A; adding NaN3 into the mixture A according to the molar ratio NaN3:Bi=(0.8-1.1):1, and stirring to form a mixture B; adding NH4Cl and N2H4.H2O into the mixture B according to the molar ratio NaN3: NH4Cl: N2H4.H2O=3:1:1 to form a precursor; and adopting a microwave hydrothermal method to obtain N/BiVO4 powder. The preparation method has the advantages of simplicity in operation and short reaction time, the synthesized N/BiVO4 powder grows along the high-activity (040) crystal orientation, and the particle morphology takes the shape of a cake piece, so that the photocatalytic activity of the N/BiVO4 powder under ultraviolet light and visible light irradiation is higher.

The invention discloses a method for on-scale continuous production of a three-dimensional graphene membrane and application, belonging to the field of functional materials. The method comprises the following steps: 1, preparing a graphene oxide solution; 2, stirring and concentrating; 3, soaking a polytetrafluoroethylene bath into methanol; 4, filling the concentrated graphene oxide solution into the polytetrafluoroethylene bath, thereby obtaining graphene oxide strips; 5, leading out the graphene oxide strips from the methanol solution, firstly drying, and further performing reduction expansion, thereby obtaining the three-dimensional graphene membrane; and 6, collecting the three-dimensional graphene membrane, and coiling. The graphene oxide solution and functional nanoparticles are mixed, and the functional three-dimensional graphene membrane can be prepared by performing the above preparation steps. The method is simple in preparation process, environment-friendly, low in cost and applicable to on-scale production, and the three-dimensional graphene membrane prepared by using the method is three-dimensional and porous and has the characteristics of light mass, large specific surface area and good flexibility.

The invention provides a method for preparing platy lanthanum hydroxide nanocrystalline through a microwave-ultrasonic method. Analytically pure lanthanum nitrate hexahydrate and polyethylene glycol are added in deionized water to obtain a solution B; a potassium hydroxide or sodium hydroxide solution is added in the solution B to form a precursor solution C; the precursor solution C is poured into a four-neck round-bottom flask, the flask is put in a microwave-ultraviolet-ultrasonic trinity synthesis reaction apparatus, microwave heating and ultrasonic combination under a temperature-time mode is selected, the precursor solution C is cooled to the room temperature naturally after reaction is finished, a product is collected through centrifugation and then washed several times by deionized water and absolute ethyl alcohol, and the product is dried to obtain the final product platy lanthanum hydroxide nanocrystalline. The method adopts a simple microwave-ultrasonic preparation process, is short in reaction time period and low in energy consumption, reaction can be finished in liquid phase in one time, and no after-treatment is needed. La(OH)3 particles made by the method are of platy structures and are large in specific surface area, good in dispersibility and excellent in performance.

The invention provides a construction method and support mould for tunnel primary support. The movable support mould is adopted in tunnel primary support construction; a mould cavity is formed betweenthe support mould and the tunnel excavation face; the support mould moves with the outline of the tunnel excavation face as the moving track; the mould cavity used for forming a tunnel primary support concrete layer is formed through joint cooperation of the movable support mould and the tunnel excavation face; the mould cavity is filled with concrete added with an accelerator, and after the concrete at the bottom of the mould cavity is initially solidified, the support mould moves towards a next station step by step; when the support mould moves, a mould cavity which is newly formed by the support mould in the moving process and the tunnel excavation face is continuously filled with concrete added with an accelerator; and finally, the whole tunnel primary support concrete layer is formed. The construction method and support mould have the beneficial effects that the working time is short, efficiency is high, the using quantity of the accelerators is small, springback is avoided, flatness is high, smoothness is achieved, unevenness is avoided, attractiveness is achieved, and after-treatment is not needed.

A rod-shaped zinc oxdie particle (tens nm-several microns) is prepared through preparing the aqueous solution of zinc salt, preparing the aqueous solution of ammonium alcoholate, proportionally mixing them in the preheated secondary water solvent, reaction, ageing, and centrifugal separation. It can be used for preparing photoelectric device, chemical sensor, atomic microscope, or scan tunnel microscope.

The invention discloses a method for preparing a three-dimensional carbon material. The method comprising: S1) soaking a sponge in a soluble catalyst precursor aqueous solution, after drying, obtaining a soaked sponge; the soluble catalyst being a salt compound of iron series element; S2) heating the soaked sponge in a protective atmosphere and keeping the temperature, and obtaining the three-dimensional carbon material. Compared with the prior art, according to the invention, the sponge is used as a solid carbon source, the sponge adsorbs catalyst precursor in an early stage, and then in theprotective atmosphere, the sponge is pyrolyzed and carbonized, the catalyst is generated in situ, and the carbon nanotube grows at the same time; the three-dimensional carbon material with the carbonnanotube winding a carbonized sponge framework is prepared, the method is simple without requiring post processing; moreover, the three-dimensional carbon material maintains the elasticity and the three-dimensional framework structure of the sponge, has certain conductivity, also has a larger specific surface area and rich void structures, and after depositing metal lithium, and the three-dimensional carbon material maintains the elasticity and the three-dimensional framework structure of the sponge can achieve high current density and high surface capacity without dendrite formation.

The invention discloses a VOOH/VS4 micrometer composite powder as well as a preparation method and application of the VOOH/VS4 micrometer composite powder. The preparation method comprises the steps:simultaneously adding sodium metavanadate and thioacetamide into deionized water to obtain a solution A; then, dropwise adding an aqueous ammonia solution into the solution A to obtain a solution B; pouring the solution B into a reaction liner, and then, carrying out sealing for a hydrothermal reaction; next, taking out a product cooled after being reacted, alternately cleaning the product by using water and alcohol, and then, collecting the product; and freezing the cleaned product, and then, drying the product to obtain the VOOH/VS4 micrometer composite powder. The VOOH/VS4 micrometer composite powder prepared according to the preparation method is composed of uniform spheroidal structures of which the diameters are about 10mu m, parts of spheroidal structures are gathered, the insides of microspheres are formed by self-stacking micrometer VS4 short rods of which the diameters are 0.5-1.0mu m and the length is 1.0-2.0mu m, and the outsides of the microspheres are randomly formed fromVOOH long rods having the diameters of 50-200nm and single-crystal structures. The VOOH/VS4 micrometer composite powder is applied to the fields of lithium/sodium ion batteries and photo/electric catalysis. The VOOH/VS4 micrometer composite powder shows excellent electrochemical properties and catalytic property when being applied as an anode material of a sodium/lithium ion battery and a photo/electric catalyst.

The invention relates to a method for extracting microalgal oil by supercritical CO2 isothermal transformation technology. The method comprises the steps of: removing impurities in dried microalgae, and then crushing and grinding; putting the ground microalgae dry powder into an extraction kettle, filling supercritical CO2 into the extraction kettle, and extracting under the conditions that the pressure is 12-25MPa, the temperature is 34-42 DEG C and the time is 150-180min; carrying out isothermal decompression separation on the supercritical CO2 containing solute successively by two stages of separators; and collecting fatty acid oil extract separated out from the bottoms of the two stages of separators to obtain the product. According to the method, organic solvent is not needed in the whole process, so that no residual solvent exits in the extract, and oxidation and thermal cracking are not caused in the extraction process; the oil is high in yield and purity; the product is excellent in quality; the whole set of technology is simple in operation and does not have corresponding post-processing requirement. Meanwhile, the method prevents the microalgal oil from poisoning the human body and polluting the environment in the extracting process.

The invention discloses a high-hardness wear-resistant piston pin and a preparation method thereof. The preparation method comprises the following steps of firstly, respectively mixing matrix material powder and Co-Cr-W alloy powder with a binder, and performing granulation to obtain a matrix material feed and a high-hardness wear-resistant coating material feed; then, sequentially injecting the matrix material feed and the Co-Cr-W alloy coating material feed into a mold cavity by using an injection molding technology to obtain a product green body; removing the binder in the green body through catalytic debinding and thermal debinding processes; and finally, performing co-sintering densification to obtain the Co-Cr-W series high-hardness wear-resistant piston pin. The process is simple, the bonding performance of a coating layer and a matrix is good, and the piston pin has the characteristics of high hardness and wear resistance.

The invention discloses a W18O49 coated carbon fiber composite material and a preparation method thereof. The W18O49 coated carbon fiber composite material takes carbon fibers as a reaction source and the W18O49 coated carbon fiber composite material is produced by adopting a solvothermal method; a monoclinic W18O49 nano-material grows on the carbon fibers through the solvothermal method in a coating manner; in a solvothermal preparation process, any template and any catalyst are not needed; the technology is simple, the yield is high and the cost is low, so that the W18O49 coated carbon fiber composite material is suitable for batch production; the W18O49 nano-material directly grows on carbon cloth and the prepared nano composite material has a uniform shape and coating tightness and can be used as photocatalysis, electrocatalysis, solar cell, flexible sensor, field emission and lithium-ion battery negative electrode materials.

The invention discloses a high-precision 3D printing device based on an SLA technology. The high-precision 3D printing device comprises a device table, a photocuring working barrel groove formed in the device table, a laser scanning head mechanism and a PLC. At least one photosensitive resin injection opening is formed in the portions, of the same horizontal height, of the inner side wall of the photocuring working barrel groove. The photosensitive resin injection openings are connected with a photosensitive resin storing container through pipelines and a photosensitive resin topping-up pump. At least one bearing medium injection opening is formed in the position, lower than the photosensitive resin injection openings, of the inner side wall of the barrel groove. The bearing medium injection openings are connected with a bearing medium storing container through pipelines and a bearing medium topping-up pump. The photosensitive resin topping-up pump and the bearing medium topping-up pump are electrically connected with the PLC. Photosensitive resin floats on the surface of a bearing medium, while high polymer formed after the photosensitive resin is cured is sunken into the bearing medium. The printing device is high in printing precision, transition of printing cambered surface trails is smooth, the photosensitive resin is cured completely, and curing bonding force among layers is large.