The invention relates to a method for normal
temperature and pressure whole-wet leaching of toxic elements in mining and metallurgical
solid waste, wherein the
solid waste at least contains one of toxic elements comprising Hg, Cd, Ge, Te, Cr, Ga, Li, In, Sn, Pb, Ni, Tl, As, Sb, Be, F, Co, Bi, Cu and Ag. The method comprises the steps: crushing the
solid waste, then adding water, and blending into a mine
slurry; adding
sulfuric acid and a leaching aid
polyol sulfone halogen into the mine
slurry, and carrying out first-stage leaching; filtering the last-step leached liquid, carrying out itemized extraction of the toxic elements contained in the filtrate, carrying out second-stage leaching on a filter residue with
sodium chloride added with the leaching aid, and carrying out
hydrolysis or
ion exchange of the leached liquid to obtain corresponding
metal enriched products. With adopting of the novel leaching aid
polyol sulfone halogen, the acid leaching process of the toxic elements in the solid waste is fundamentally changed, not only is the efficiency improved but also all the toxic elements can be leached, then itemized separation and extraction is carried out, the post liquid after the toxic elements are extracted can be purified into pure water for reuse, and elements in the leached residue have no
toxicity, so that the mining and metallurgical solid waste
raw material can be treated with low cost and high efficiency, the waste is turned into treasure, and solid waste resource and innocuous utilization are achieved.