The application discloses a transparent
conductive oxide film for a
heterojunction cell and a preparation method thereof. The transparent
conductive oxide film substrate is sequentially provided with an intrinsic
amorphous silicon film and a doped
amorphous silicon film and is stably formed into a uniform
pyramid structure with a size of 1-2 microns on the surface of a
silicon wafer. A buffer layer is grown on the surface of the doped
amorphous silicon, and the buffer layer is located between an
indium titanium oxide (ITIO) film and the doped amorphous
silicon. The application grows a buffer layer with a thickness less than 10 nanometers on the surface of the doped amorphous
silicon. The growth process cannot physically damage the effective
doping sites of the amorphous silicon. The buffer layer can block the direct bombardment of high-energy particles, protect the doped amorphous silicon film from damage, ensure the smooth progress of the
deposition process, make the transparent
conductive oxide film still have good conductive performance, make the transparent conductive
oxide film have high light
transmittance, and thus be favorable to the improvement of the efficiency of the
heterojunction solar cell.