The invention belongs to the field of
functional polymers, and particularly relates to a high-
toughness, repairable, recoverable and
flame-retardant
epoxy vitrimer and a
composite material thereof. The
epoxy vitrimer is obtained by reacting dithio-diphenyl
diglycidyl ether,
bisphenol A
diglycidyl ether,
isocyanuric acid tri [2-(3-mercaptopropionyloxy)
ethyl ester] and dithio-diphenyl diphosphate diphenyl at the temperature
ranging from
room temperature to 90 DEG C or above, after being completely cured, the
epoxy vitrimer shows the characteristic of high
toughness, the elongation at break reaches 200% or above, and the epoxy vitrimer shows that damage can be repaired and the service life of the epoxy vitrimer is prolonged. And hot-pressing recycling and reshaping and
flame-retardant characteristics can be realized. The high-
toughness, repairable, recoverable and
flame-retardant epoxy vitrimer
composite material is obtained by reacting the epoxy vitrimer resin and
silicon dioxide modified by dithio
diphenyl phosphate diphenyl
glycidyl ether at the temperature
ranging from the
room temperature to 90 DEG C or above; the epoxy vitrimer
composite material shows the characteristic of high toughness after being completely cured, the elongation at break reaches 150% or above, and the epoxy vitrimer composite material shows the characteristics of being repairable in damage, capable of being recycled and reformed through
hot pressing and flame-retardant.