The invention belongs to the technical fields of functional
polymer materials and
electrochemistry and in particular relates to a preparation method of a pore-filing type
proton exchange membrane taking double
ether crosslinked porous polybenzimidazole
imide as a base. The preparation method of the pore-filing type
proton exchange membrane taking the double
ether crosslinked porous polybenzimidazole
imide as the base comprises the following steps: firstly synthesizing polybenzimidazole
imide provided with a cross-linkable
imidazole group on a main chain, preparing the synthesized polybenzimidazole imide into a membrane solution, adding a double
ether crosslinking agent, reacting with the
imidazole group, a crosslinking sulfonated
polyimide polymer in a membrane forming process, adding a pore-forming agent at the same time to form a crosslinked porous polybenzimidazole imide membrane, and finally compounding the crosslinked porous polybenzimidazole imide membrane with perfluorosulfonate resin, so that the pore-filling type
proton exchange membrane is obtained. A
basement membrane gives good mechanical properties to the pore-filling type membrane, and the pore-filling type membrane has
high dimensional stability; meanwhile, the proton
conductivity of a perfluorosulfonate membrane is not greatly reduced. The preparation method of the pore-filing type proton exchange membrane taking the double ether crosslinked porous polybenzimidazole imide as the base has the advantages that the preparation technology
controllability is good; and compared with the traditional perfluorosulfonate membrane, the obtained pore-filling type proton exchange membrane has high
mechanical strength and good dimensional stability and has broad application prospect in a
polymer electrolyte membrane fuel
cell.