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45results about How to "Smooth material surface" patented technology

Organic Li-based bentonite-WPU (waterborne polyurethane) leather finishing agent and preparation method thereof

The invention discloses an organic Li-based bentonite-WPU (waterborne polyurethane) leather finishing agent and a preparation method thereof. The method comprises the following steps: firstly, carrying out organic modification on Li-based bentonite so as to prepare organic Li-based bentonite; and then, dispersing the organic Li-based bentonite into a WPU matrix in nano scale by using a latex commixing or in-situ polymerization method so as to obtain the organic Li-based bentonite-WPU leather finishing agent. In the invention, because quaternary ammonium salts, organic amines, a coupling agentand polyisocyanates are selected to carry out organic modification on Li-based bentonite, the surface microenvironment of a chain-connected silicate layer of the Li-based bentonite and the wetting action (on polymers) of the Li-based bentonite are improved, thereby enhancing the dispersibility of the Li-based bentonite in organic polymers and the compatibility of the Li-based bentonite and the organic polymers, and better facilitating the expression of nano effects; and because the Li-based bentonite with a two-dimensional nanostructure is introduced into the WPU matrix by using a latex commixing or in-situ polymerization method, therefore, due to the unique structure and properties of a nano-clay, while the transparency of a finishing material is not affected, the thermal stability, friction-resistant strength and water vapor permeability of the finishing material can be improved markedly, and the mechanical properties of the finishing material are also enhanced and toughened.
Owner:SICHUAN UNIV

Cu-Ni functionally gradient material and preparation method thereof

The invention discloses a Cu-Ni functionally gradient material and a preparation method thereof. The functionally gradient material comprises an intermediate copper layer and two side nickel layers, wherein a gradient distribution layer is arranged between the copper layer and each nickel layer; and the copper content of the gradient distribution layer is decreased gradually and the nickel content is increased gradually to the directions of the nickel layers. The material is high in bending resistance, electric conductivity, heat conductivity and mechanical performance; various parts of the material are linked closely; the surface structure of the material is dense and flat; a stable NiO protective film can be formed on the surface of the material in the air at the temperature of 700 to 900 DEG C, so that substrate copper is effectively prevented from being oxidized; and therefore, the material has the characteristic of high surface oxidation resistance. According to the preparation method, aiming at the characteristics of the conventional Cu-Ni functionally gradient material, according to a diffusion basic theory, the method of electrodepositing Ni and interfusing Ni and Cu at the same time under the action of an electric field is adopted to accelerate the thickening of a gradient layer. The preparation method has the advantages that the formation speed of the gradient layer is high; the time required for preparing a thick gradient layer is short; and the method is easy to control and simple in process and the like.
Owner:NORTH CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY

Anion-cation doped P2 type sodium ion battery positive electrode material

The invention relates to an anion-cation doped P2 type sodium ion battery positive electrode material and a preparation method thereof. The chemical formula of the cathode material is Na0.67CuxMn1-xO2-yFy, x is more than 0 and less than or equal to 0.35, y is more than 0 and less than or equal to 0.3, a manganese salt, a copper salt and sodium fluoride are weighed according to the molar ratio of Mn, Cu and F elements and dissolved in deionized water, then a sodium salt is added and stirred to be dissolved, a mixed metal salt solution is prepared, and a citric acid solution is used as a complexing agent; the mixed metal salt solution is added into the complexing agent, ammonia water is added to adjust the PH value of the solution to be 8-11, the heating temperature is 60-90 DEG C, and gel is obtained after drying by distillation under the stirring condition; and the obtained gel is dried and crushed, presintered in an air atmosphere, sintered, and cooledto room temperature to obtain the positive electrode material. Through the synergistic effect of Cu ions and F ions, excellent electrochemical performance is shown, for example, the specific capacity of the material is improved, and the rate capability and the cycling stability are good.
Owner:TIANJIN UNIVERSITY OF TECHNOLOGY

W-Ni-Cu gradient material and preparation method thereof

The invention discloses a W-Ni-Cu gradient material and a preparation method thereof. The method comprises the following steps: taking a molten salt system of NaCl-KCl-NaF-NiO as an Ni leakage source and taking a copper-plating aqueous solution as a Cu leakage source; electrically depositing and leaking nickel on a pure W plate through molten salt, electrically depositing and leaking Cu through an aqueous solution; and finally diffusing and annealing to obtain the W-Ni-Cu gradient material. The material is high in thermal shock resistance and thermal fatigue resistance; all the components of the material are combined closely; the material surface structure is compact and smooth; the material has high electrical conductivity, high thermal conductivity and high mechanical performance. The method is capable of simultaneously carrying out mutual diffusion between W and Ni and carrying out mutual diffusion between Ni and Cu under the action of an electric field and a temperature field by using an electric deposition method according to the basic diffusion theory (the electric field can accelerate the diffusion of solid metals, and the diffusion speed of the opposite party can also be mutually improved when carrying out multi-element diffusion in the solid diffusion); the thickening of gradient layers can be accelerated; the W-Ni-Cu gradient material has the characteristics of rapid forming speed of the gradient layers, short preparation time, randomly controllable thickness of the gradient layers, compact surface structure of the material, high thermal conductivity and simple process.
Owner:NORTH CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY

Layered composite oxide coated positive electrode material and preparation method and application thereof

The invention relates to a layered composite oxide coated positive electrode material as well as a preparation method and application thereof. The preparation method comprises the following steps: uniformly mixing cobalt salt and M salt or oxide according to a ratio, conducting sintering to obtain a bulk phase material precursor, mixing the bulk phase material precursor with lithium salt and an additive according to a ratio, conducting sintering at a high temperature, and conducting crushing to obtain gradient-doped modified lithium cobalt oxide; ultrasonically dispersing layered protonated titanate nanosheets in a uniformly dispersed dispersion liquid containing a metal oxide, transferring the dispersion liquid to a high-pressure reaction kettle for reaction, and conducting washing after separation to obtain intercalated layered titanate; carrying out dispersion and ultrasonic treatment on the intercalated layered titanate to obtain a stripped intercalated layered titanate nanosheet colloidal solution; and adding the modified lithium cobalt oxide into the intercalated layered titanate nanosheet colloidal solution, carrying out rotary evaporation to remove the solvent, carrying out vacuum drying, and carrying out heat treatment on the dried material to form the intercalated layered titanate nanosheet-coated modified lithium cobalt oxide layered composite oxide-coated positive electrode material.
Owner:TIANMU LAKE INST OF ADVANCED ENERGY STORAGE TECH CO LTD

Paper reinforcement plant-based composite material and preparation method thereof

The invention relates to a novel paper reinforcement plant-based composite material and a preparation method thereof. The composite material consists of plants, paper, bonding agents and polyurethane. The reinforcement method is characterized in that a paper reinforcement inner layer is introduced based on the reinforcement of the surface layer of polyurethane, paper reinforcement raw materials are easily available, waste resources can be recycled, the intensity of the composite material is improved effectively, the hygroscopicity is lowered, and the water resistance is intensified, so that the composite material is ordered in structure and universal in formation. By the preparation method of the composite material provided by the invention, raw materials are simple to treat, and dewaxing and washing are not needed; cellulose is not required to be separated individually, and thus a separation step is omitted; the diffusion of dust in an environment is reduced, and thus the health of operators in the field is protected; the preparation method is high in adaptability and easy to implement. The composite material provided by the invention has wide application, and can replace wood and plastics for manufacturing furniture, toys, containers, automobile decorative parts, daily necessities and the like.
Owner:JIUJIANG UNIVERSITY

Ethylene-ethylene acetate copolymer (EVA) refrigerator door seal particle and preparation method thereof

The invention discloses an ethylene-ethylene-vinyl acetate copolymer (EVA) refrigerator door seal particle which is composed of an EVA, polyethylene (PE), modified polyethylene, polypropylene (PP), modified polypropylene, an ethylene-olefin copolymer (POE), a mineral filler, a foaming agent, a nucleating agent, a lubricant, an antioxidant, a photoinitiator, a cross-linking agent, an antibacterial and mildew-proof agent, a pigment and the like. The invention further discloses a preparation method of the micro-foaming type EVA refrigerator door seal particles capable of being directly extruded. The preparation method comprises the steps of weighing, grinding, pre-crosslinking, mixing, banburying and extruding granulation. The material is ground and pre-crosslinked, and the foaming agent and the nucleating agent are added, so that when the material is used for producing the refrigerator door sealing strip, direct extrusion molding can be realized, high-temperature vulcanization and mold pressurization are not needed, and the micro-foaming refrigerator door sealing material can be prepared. The product is smooth in surface, contains a large number of microbubbles in the middle, and is high in material tearing strength, large in weld fillet tension, good in rebound resilience, resistant to low temperature, resistant to aging, good in sealing performance and good in heat preservation effect.
Owner:上海新上化高分子材料有限公司

One-pot preparation of sio 2 - Method for cellulose composite airgel material

The invention relates to a method for preparing a SiO2-cellulose composite aerogel material with a one-pot method. The method comprises the following steps: taking cellulose as a raw material and dissolving the cellulose with a green alkaluria solvent; taking organic sodium silicate as a silicon source, and stirring and dispersing to obtain a uniformly mixed aqueous solution of the cellulose and the sodium silicate; combining a sol-gel method to obtain regenerated cellulose wet gel containing a silicon source; taking cellulose gel as a framework and taking inorganic acid as a reaction solvent, and inducing to generate SiO2; finally, drying through a CO2 supercritical drying process to obtain the SiO2-cellulose organic-inorganic composite aerogel. The method has the advantages that the process is simple and rapid, has high feasibility and is green and environment-friendly; the problems in an in-situ immersion method that the SiO2 has poor dispersity, low complex content, poor complex stability and the like in a cellulose porous network structure are effectively solved; the prepared inorganic-organic composite aerogel has relatively low coefficient of heat conductivity and good heat insulation performance and has good application prospect in the aspects of low-temperature cold insulation materials, middle-temperature and low-temperature heat insulation and heat preservation materials and adsorption materials.
Owner:NANJING TECH UNIV

Organic Li-based bentonite-WPU (waterborne polyurethane) leather finishing agent and preparation method thereof

The invention discloses an organic Li-based bentonite-WPU (waterborne polyurethane) leather finishing agent and a preparation method thereof. The method comprises the following steps: firstly, carrying out organic modification on Li-based bentonite so as to prepare organic Li-based bentonite; and then, dispersing the organic Li-based bentonite into a WPU matrix in nano scale by using a latex commixing or in-situ polymerization method so as to obtain the organic Li-based bentonite-WPU leather finishing agent. In the invention, because quaternary ammonium salts, organic amines, a coupling agentand polyisocyanates are selected to carry out organic modification on Li-based bentonite, the surface microenvironment of a chain-connected silicate layer of the Li-based bentonite and the wetting action (on polymers) of the Li-based bentonite are improved, thereby enhancing the dispersibility of the Li-based bentonite in organic polymers and the compatibility of the Li-based bentonite and the organic polymers, and better facilitating the expression of nano effects; and because the Li-based bentonite with a two-dimensional nanostructure is introduced into the WPU matrix by using a latex commixing or in-situ polymerization method, therefore, due to the unique structure and properties of a nano-clay, while the transparency of a finishing material is not affected, the thermal stability, friction-resistant strength and water vapor permeability of the finishing material can be improved markedly, and the mechanical properties of the finishing material are also enhanced and toughened.
Owner:SICHUAN UNIV
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