The invention discloses a nano ceramic coating with high emissivity, which is prepared from a high temperature resistant basic material, an additive with high emissivity, a binder, a stabilizing agent and a solvent. The high temperature resistant basic material and the additive with high emissivity are one or several of alumina, silicon oxide, boron nitride, silicon carbide, ferric oxide and cerium oxide. The binder is one or several of silica gel, potassium silicate solution, aluminium phosphate solution, silicon oxide hydrate, ethanol and water. By weight percentage, the high temperature resistant basic material and the additive with high emissivity account for 5-78%, the binder accounts for 5-30%, the stabilizing agent accounts for 0.5-3% and the balance of solvent is water. The coating which can be used above 1300 DEG C has the advantages of being wide in work temperature range with the maximum service temperature close to 2000 DEG C, applicable to various base materials, strong in adhesive force to the base materials, applicable to reaction atmosphere, good in long-time durability and strong in heat shock endurance, improving thermal efficiency, lowering temperature of the base materials, and being excellent in abrasion and corrosion resistance, less in impact on environment, convenient to use and the like.