The invention relates to a method and a system for preparing high-whiteness and high-purity aluminum hydroxide from solid waste. The preparation method comprises the following steps: firstly, crushing raw materials to form pre-powder, preparing raw materials from the pre-powder, molding the pre-powder to obtain a blank, sintering the blank to obtain clinker, dissolving out the clinker to obtain slurry, and carrying out slurry desilication, carbon component reaction, hydrogen-aluminum separation and drying on the slurry to prepare the high-whiteness and high-purity aluminum hydroxide. The raw materials comprise aluminum-containing solid waste, calcium-containing solid waste, pulverized coal and sodium carbonate; the raw material crushing comprises the step of crushing the raw materials to process control fineness; and blank sintering refers to temperature programming roasting of the blank, and the roasting temperature ranges from 800 DEG C to 1100 DEG C. According to the invention, solid wastes such as fly ash, coal gangue, carbide slag and the like, pulverized coal and sodium carbonate are crushed into materials with the same fineness, high-whiteness and high-purity aluminum hydroxide can be obtained through alkali-process blank sintering, the recovery rate of aluminum in the solid wastes is 90% or above, and harmless, resource and synergistic utilization of the solid wastes such as fly ash and the like is realized.