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132results about How to "Fast chemical reaction" patented technology

Preparation method of room-temperature ball-milling solid phase chemical reaction of rare earth mixing with nano stannic oxide

The invention discloses a preparation method of room-temperature ball-milling solid phase chemical reaction of rare earth mixing with nano stannic oxide, relates to a preparation technology of the rare earth mixing with the nano stannic oxide, which can be applied for antistatic coating, plastics, fibre and other fields. Inorganic salts containing stannum and rare earth are taken as reactants, oxalic acid, ammonium carbonate, ammonium bicarbonate, sodium oxalate or sodium carbonate is taken as a ligand, the processing steps are sequentially dosing, mixing and preparing precursors of the room-temperature ball-milling solid phase chemical reaction, and the targeted product can be obtained after impurity removing, drying and thermal decomposition. The preparation method is characterized in that the reaction process does not use water, the stannum ion can be prevented from hydrolysis, uniform mixing can be realized, a solid phase reaction system is broken by utilizing the shearing force and the impact force generated during the ball milling process, the specific surface area of the reactant is increased, the reaction rate is increased, micro-fine and uniform precursors can be prepared, then the processes of cleaning, drying and controlling the thermolysis temperature and time are carried out, and thereby the rare earth mixing with nano stannic oxide powder, the particle size distribution of which is 30 to 80nm and has controllable morphology, can be obtained.
Owner:SICHUAN UNIV

Preparation method for pelletizing and producing yellow phosphorus by phosphorus ore concentrate

The invention provides a preparation method for pelletizing and producing yellow phosphorus by a phosphorus ore concentrate which comprises the following components in terms of producing 1000 Kg of yellow phosphorus: 7100-8500 Kg of phosphorus ore concentrate powder, 1800-2000 Kg of coke dust, 1800-3300 Kg of silica powder, 130 Kg of humic acid and 65 Kg of sodium hydroxide. The preparation method is as follows: grinding formula components by a ball mill; adding a binder composed of the humic acid and the sodium hydroxide, and evenly stirring; processing into a compound pellet by a ball pressing and forming machine; dying by a chain plate dryer; and sending into a yellow phosphorus electric furnace to prepare into a yellow phosphorus finished product. The invention fully utilizes powder phosphate ores and low-grade phosphate ores; the phosphorus ore concentrate powder obtained by mineral separation is produced into a pellet by the binder, and then the pellet is prepared into yellow phosphorus by the electric furnace. Compared with the existing phosphorus preparation by a phosphorus ore concentrate, the invention lowers cost by one time, reduces CO emission by about 35%, reduces electricity consumption by about 40%, improves capacity by 2 times and reduces materials by about 40%. Thus, the invention is an excellent method for solving the problems of high energy consumption, high emission and high pollution for yellow phosphorus production in China.
Owner:瓮安烨烨磷化工实业有限公司

Preparation method of porous structure ammonium vanadate material

The invention provides a preparation method of a porous structure ammonium vanadate material. The preparation method comprises the following steps: dissolving ammonium metavanadate in deionized water so as to obtain a NH4VO3 solution A; adjusting the pH value of the solution A to 1.5-3.0, and then carrying out phonochemistry reaction so as to obtain a solution B; pouring the solution B into a reactor, enabling microwaves and an ultraviolet lamp to simultaneously act on the solution B, heating to 60-90 DEG C, preserving heat, and then naturally cooling to a room temperature; and carrying out centrifugal separation on suspension liquid in the reactor so as to obtain a powder product, washing and drying, thus obtaining the porous structure ammonium vanadate material. The NH4V3O8 microcrystal prepared by the method is uniform in chemical composition and relatively high in purity, is a special porous structure and has good electrochemistry performance when serving as an anode material for a lithium ion battery; the specific area of the material can be effectively enlarged. The preparation method is simple, low in reaction temperature, short in reaction time, environmentally-friendly and suitable for large-scale production; the follow-up treatment is not needed.
Owner:盐城大数据资产经营管理有限公司

Oxidation sweetening and denitration method for hydroxyl radical of oxygen active particles injected in flue duct

The invention discloses an oxidation sweetening and denitration method for hydroxyl radical of oxygen active particles injected in a flue duct, belonging to the technical field of gas ionization discharging, plasma chemistry and environmental engineering application. The invention is characterized in that the oxygen active particles (O<2+>, O3, O(<1>D), O(<3>P)) with the concentration of 80 to 400 mg/L are injected the flue, wherein the O<2+> reacts with the H2O in the flue gas to form the HO2<->initiator, and the oxygen active particles and the HO2<->initiator are subjected to the plasma reaction to form the.OH within the reaction time of 1 mu s to 1 ms. The.OH oxidizes and removes the SO2 and the NOx in the flue gas to generate the submicron acid mist with the reaction time of 1 to 1 s, then the charge coagulation is performed to collect the mixing acid liquid, and finally the sulfuric acid and the nitric acid are separated and purified by chemical methods, wherein the acid resource recovery rate is 50 to 98%. The invention has the effects and the advantages of solving the problems of the existing desulphurization and denitration method of the flue gas, realizing the novel recycling and dry desulphurization and denitration method without using catalysts, absorbent and reducing agents, and generating any re-contaminative by-product and any negative effect to the environment.
Owner:DALIAN MARITIME UNIVERSITY

Method for producing phosphoric acid through ground phosphate rock in fast hot-melting mode

The invention relates to a technique method for producing phosphoric acid in fast hot-melting mode with low-quality and medium-quality ground phosphate rock and silica powder as the raw materials and pulverized coal as the heating energy. The method is characterized in that the ground phosphate rock and the silica powder finish the chemical reaction of calcium phosphate and silica in a rotary-flow melting calcining kiln at the temperature of 1450-1800 DEG C within 2 minutes, calcium metasilicate melted slag and phosphorus pentoxide furnace gas can be produced, phosphoric acid is obtained through heat exchanging, dedusting and hydration absorption of the furnace gas, and cement clinker can be obtained by adding proper amount of additives such as calcium carbonate or calcium oxide powder in the calcium metasilicate melted slag at the temperature of 1400 DEG C. By means of the method, phosphorus pentoxide is prepared from phosphate ore in one step directly, the existing processes of phosphate ore reduction and phosphorus oxidization are omitted, carbon for reducing is saved, and the technological process is simplified. The puzzle that in the existing rotary kiln process, tunnel kiln process and blast furnace process, materials become rings, the kiln temperature is difficult to control, reaction rate is low, the device cannot operate continuously, and industrial application is difficult is solved.
Owner:黄靖元

Blue fluorescent powder for white-light LED and preparation method thereof

The invention relates to blue florescent powder for a white-light LED, belonging to the technical field of rare earth luminescent materials. The blue florescent powder has a chemical formula of: Ca<1-x>SiO3:xEu2+, wherein x is more than 0 and less than 0.2. The preparation method comprises the following steps of: respectively weighing calcium salts, silicic acid, europium nitrate and an appropriate amount of surfactant and fluxing agent according to the stoichiometric ratio in the chemical formula; fully mixing the weighed reactant, the surfactant and an appropriate amount of ligands and then ball-milling, and adding a lubricating agent when in ball-milling; filtering, washing and drying to obtain a precursor; evenly mixing the precursor with the fluxing agent, and then calcining under the reducing atmosphere to obtain the required florescent powder. In the invention, the blue florescent powder for the LED is prepared by adopting a mechanical force solid-phase chemical reaction method, the specific surface area of the reactant is increased by utilizing the shearing force and the impact force generated in the ball-milling process, the contact face and the diffusion speed of the reactant are improved, and the required time in the chemical reaction is shortened. The prepared fluorescent powder has high luminescent strength as well as good color rendering property and stability, and is suitable for LEDs excited by ultraviolet and near ultraviolet.
Owner:SICHUAN UNIV

Molybdenite concentrate suspended-state roasting process and equipment

The invention discloses a molybdenite concentrate suspended-state roasting process, which comprises the following steps of: firstly, conveying molybdenum concentrate to a suspension roaster by using a gas-moving material spraying device through compressed air, and completing heat exchange in a heat exchange area, wherein the temperature of the heat exchange area is 500 to 750DEG C and the retention period is 2 to 15 seconds; secondly, performing oxidation desulfurization reaction in a reaction area of the suspension roaster to obtain roasted high-sulfur sand, wherein the temperature of the reaction area is 550 to 780DEG C, the air speed is 4 to 25m/s, and the retention period is 2 to 15 seconds; and finally, removing residual sulfur from the roasted high-sulfur sand in a rotary kiln at the temperature of between 550 and 780DEG C for 5 to 60 minutes to obtain roasted high-dissolubility molybdenum sand. The invention also provides molybdenite concentrate suspended-state roasting equipment, which overcomes various defects of stacked state roasting and fluidized roasting, has high thermal efficiency and good product quality, greatly shortens roasting time, can obtain the high-dissolubility low-sulfur molybdenum oxide, and ensures that SO2 in flue gas has high concentration and is convenient to recycle for making acid.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY
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