The invention belongs to the technical field of restoration and treatment of
heavy metals in soil, and discloses a high magnetic modified
biochar, a preparation method of the high magnetic modified
biochar, and an application to treatment of the heavy
metal pollution to the soil. The preparation method comprises the following steps:
grinding and sieving the
biochar, adding the biochar into a NaOHsolution, stirring, filtering, and washing with water; adding a filter residue into an HCl solution, continuing to stir, filtering, washing with water to obtain a basic
charcoal material, and
drying for later use; adding the basic
charcoal material into an FeCl2-7H2O
aqueous solution, regulating the pH value, adding a
sodium borohydride solution until no bubble is generated, then adding a saturated
sodium dimethyl dithio
carbamate aqueous solution, continuing to stir, collecting a residue in the solution through a
magnetic field, and washing and
drying to obtain the high magnetic modified biochar. The specific surface area of the modified biochar is increased, the passivating efficiency of the
heavy metals in the soil is improved, the magnetic property of the high magnetic modified biocharis strong, the high magnetic modified biochar is removed from the soil through a
magnet, and the total content of the
heavy metals in the soil is reduced.