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The present application discloses a kind of condensed ring aromatic hydrocarbon hydrogenation catalyst and its preparation method and application.The catalyst includes porous carrier, active metal component and auxiliary component, the active metal component is selected from at least one of La system, group VIB or group VIII metal element, the auxiliary component is selected from at least one of group IIA metal element, the catalyst, with X-ray photoelectron spectroscopy characterization, metal component M a+ (a>1) is reduced to M (a‑1)+ The ratio of M a+ Total reduction of at least 80%, preferably at least 90%.The catalyst of the present application is used for condensed ring aromatic hydrocarbon hydrogenation reaction, especially naphthalene and naphthalene hydrogenation reaction, with the characteristics of improving the conversion rate of reactants, the selectivity of target product.