The invention discloses flyash-hollow-
microsphere-based composite
titanium white and a preparation method thereof. According to the preparation method, flyash hollow microspheres serve as inner cores, crystals TiO2 serve as
coating powder, and the TiO2 can be coated on the surfaces of the flyash hollow microspheres through mechano-chemical action, so that composite
titanium white can have the nature of
pigment TiO2. The composite
titanium white disclosed by the invention has the characteristics that the preparation process is simple, the TiO2 is uniformly coated on the surfaces of the flyash hollow microspheres and firmly bonded to the flyash hollow microspheres, the hiding power is high, the cost is low, and the like. The flyash-hollow-
microsphere-based composite titanium white, as white
pigment, can be applied to the fields of coatings, plastics, inks and the like in a manner that the flyash-hollow-
microsphere-based composite titanium white partially substitutes titanium white. Furthermore, when the composite titanium white is applied to the coatings, the hollow heat
conductivity coefficient of the flyash hollow microspheres is small, the TiO2 has a high reflection role on
sunlight, and then, a complete hollow
isolation layer is formed in a manner that the flyash hollow microspheres are closely arranged after a
coating is dried, so that the composite titanium white has a good heat insulating effect. The flyash-hollow-microsphere-based composite titanium white has the nature of
pigment and heat insulating and heat preservation roles.