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60 results about "Diphosphenes" patented technology

In chemistry, a diphosphene is an organophosphorus compound that has a phosphorus-phosphorus double bond, denoted by R-P=P-R'. These compounds are not common but are of theoretical interest. Normally, compounds with the empirical formula RP exist as rings. However, when the organic substituent is very large, the diphosphene becomes stable. The parent compound, called diphosphene (diphosphaethylene), has the formula P₂H₂, but is not stable near room temperature.

Flame-retardant heat-insulating fabric for fire-fighting clothes and preparation process thereof

The invention provides a flame-retardant heat-insulating fabric for fire-fighting clothes and a preparation process thereof, and belongs to the technical field of fire-fighting fabrics. The preparation process comprises the following steps: preparing coated modified ammonium polyphosphate; modified expanded perlite; preparing a flame-retardant outer-layer fabric; preparing a heat insulation core layer fabric; preparing an antibacterial inner layer fabric; and bonding. The flame-retardant heat-insulating fabric for the fire-fighting clothes comprises a flame-retardant outer-layer fabric, a heat-insulating core-layer fabric and an antibacterial inner-layer fabric, ammonium polyphosphate is dispersed in deionized water, polyethyleneimine is added under the acidic condition, amino on the polyethyleneimine and ammonia ions of the ammonium polyphosphate are subjected to an ion exchange reaction, and the flame-retardant heat-insulating fabric for the fire-fighting clothes is obtained. According to the flame-retardant outer-layer fabric, ammonium polyphosphate is preliminarily coated, then a hydroxyethylidene diphosphonic acid solution is added for a salt forming reaction, coated modified ammonium polyphosphate with a core-shell structure is prepared, the coated modified ammonium polyphosphate and polyester powder are mixed and granulated, then the flame-retardant outer-layer fabric is prepared, and the flame-retardant property of the flame-retardant outer-layer fabric can be effectively improved.
Owner:JIANGXI YULING CLOTHING MANUFACTURING CO LTD

Organic light-emitting rare earth complex scintillator as well as preparation and application thereof

The invention discloses an organic rare earth luminescent complex scintillator as well as preparation and application thereof. The molecular structural formula of the complex is L13ML2, M is Tb, Eu or Er metal ions, and the valence state is + 3; l1 is a tetraphenyl diphosphine imide anion ligand (tpip) or a substituted tpip ligand; l2 is unsubstituted or substituted 2, 2 '-bipyridyl, 1, 10-phenanthroline and a non-ionic chelating group containing a polyheterocycle / fused heterocycle. The organic rare earth luminescent complex scintillator can effectively convert high-energy X-rays into narrow-band visible light and near-infrared light, and is suitable for being applied to the fields of high-energy ray detection and high-resolution imaging.
Owner:SOUTH CHINA UNIV OF TECH

A diamino diphosphine tetradentate ligand, a preparation method thereof and application thereof in suzuki cross-coupling reaction

The application relates to the field of organic synthetic chemistry, in particular to a diamino diphosphine tetradentate ligand, a preparation method thereof and application of the diamino diphosphine tetradentate ligand in Suzuki cross-coupling reaction. The diamino diphosphine tetradentate ligand provided by the application has a structure shown in formula I; due to special spatial structure and electronic properties, the diamino diphosphine tetradentate ligand can provide multi-point coordination to metal and form a stable complex with the metal, so that the activity and stability of a palladium catalyst can be improved, the palladium catalyst can efficiently catalyze the Suzuki cross-coupling reaction for constructing a C-C bond at an extremely low dosage, and the diamino diphosphine tetradentate ligand and the metal palladium catalyst have strong universality to Suzuki cross-coupling reaction substrates, and have wide potential application value.
Owner:ZHENGZHOU UNIV

Slime stripping agent as well as preparation method and application thereof

The invention belongs to the technical field of stripping agents, and particularly relates to a slime stripping agent and a preparation method and application thereof. The slime stripping agent disclosed by the invention is prepared from dodecyl dimethyl benzyl amine bromide, dichlorophenol, isothiazolinone, polyoxyethylene alkylolamide, hydroxyethylidene diphosphonic acid, dimethylformamide and sodium dodecyl benzene sulfonate. Through the combined action of the specific components, the slime stripping agent has good stripping capacity and can rapidly permeate and disintegrate slime, dirt and biological membranes attached to the surface of equipment, the cleanliness and operation efficiency of the equipment are recovered, and equipment blockage and performance reduction caused by slime accumulation are effectively avoided; meanwhile, the high killing effect on sulfate reducing bacteria and nitrifying bacteria is achieved.
Owner:ZHAOQING LINGYU ENVIRONMENTAL PROTECTION IND CO LTD

Desulfurizing agent for oil extraction in oil-gas field and preparation method thereof

The invention belongs to the technical field of desulfurizer preparation, and particularly relates to a desulfurizer for oil extraction of oil and gas fields and a preparation method thereof. The desulfurizing agent for oil extraction of the oil and gas field is prepared from the following raw materials: N-octadecyl-1, 3-propane diamine, an ionic liquid and organic copper mixture, ammonium molybdate, lysine sodium, hydroxyethylidene diphosphonic acid, polyoxyethylene sorbitan monostearate and the balance of water. According to the desulfurizing agent for oil extraction of the oil-gas field, water is used as a solvent, N-octadecyl-1, 3-propane diamine, an ionic liquid and organic copper mixture and ammonium molybdate in raw materials are used as main desulfurizing components to remove organic sulfur and inorganic sulfur, and lysine sodium, hydroxyethylidene diphosphonic acid and polyoxyethylene sorbitan monostearate are added, so that the desulfurizing agent for oil extraction of the oil-gas field is obtained. Due to the synergistic effect of the raw materials, the efficient removal of inorganic sulfur and organic sulfur in oil extraction of an oil and gas field is realized.
Owner:SHENGLI OILFIELD HAIFA ENVIRONMENTAL PROTECTION CHEM CO LTD +1

Multi-element micromolecule compounded high-temperature-resistant oil well cement retarder and application thereof

The invention relates to the technical field of well cementation engineering, in particular to a multi-element micromolecule compounded high-temperature-resistant oil well cement retarder and application thereof. The multi-element micromolecule compounded high-temperature-resistant oil well cement retarder is prepared from the following raw materials in parts by weight: 20 to 30 parts of disodium 1-hydroxyethylidene-1, 1-diphosphonate, 5 to 10 parts of sodium tetraborate, 5 to 10 parts of sodium gluconate, 2 to 5 parts of chromium sulfate and 65 to 130 parts of water. The invention can effectively solve the problem of performance failure of the traditional oil well cement retarder caused by a large temperature difference environment with a bottom hole circulation temperature of more than 220 DEG C and more than 90 DEG C.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Process for the preparation of polycyclic aliphatic dialdehydes

The present invention relates to a process for the preparation of polycyclic aliphatic dialdehydes by hydroformylation of polycyclic aliphatic diolefins in the presence of synthesis gas over an organophosphorus ligand modified metal catalyst system having a transition metal of the 8th-10th subgroup, wherein the hydroformylation is carried out by means of a water-soluble diphosphine or triarylphosphine complex catalyst at a pressure of greater than or equal to 0.5 MPa and less than or equal to 10 MPa and at a temperature of greater than or equal to 70° C. and less than or equal to 150°° C. in a homogeneous liquid reaction phase, the homogeneous liquid phase comprising at least one non-aqueous solvent, diolefin and / or mono- and / or dialdehydes thereof as reaction products and an aqueous catalyst solution, the proportions of these components in the solution being controlled so as to obtain a single-phase solution under the reaction conditions.
Owner:OQ CHEM GMBH

Ruthenium-carbon hydrogenation catalyst based on chiral diphosphine ligand modification and preparation method and application thereof

The invention relates to the technical field of catalysts, in particular to a chiral diphosphine ligand modification-based ruthenium-carbon hydrogenation catalyst as well as a preparation method and application thereof. The method comprises the following steps: preparing a nitrogen-containing defect carbon carrier; loading ruthenium and reducing; pre-coating the confinement by using an ionic liquid A; introducing a chloride ion template microenvironment; carrying out coordination with a chiral diphosphine ligand; weak coordination anion sizing is realized through the treatment of bis (trifluoromethanesulfonyl) imide silver; and finally introducing chiral ionic liquid B to construct an outer network. The catalyst realizes high enantioselective conversion of a prochiral substrate while maintaining high hydrogenation activity through a multi-layer chiral microenvironment synergistic effect, is excellent in cycling stability, and solves the technical problem that the activity and selectivity of a heterogeneous chiral catalyst are difficult to consider at the same time.
Owner:SHAANXI ROCK NEW MATERIALS CO LTD

GMP (Good Manufacturing Practice) large-scale production method for synthesizing glucan-guanidine-bisphosphonate conjugate by one-pot method

The present invention relates to a large scale GMP synthesis method of a modified glucan conjugate, and more particularly, to a glucan-guanidine-bisphosphonate conjugate wherein the bisphosphonate is an alendronate group. The large-scale GMP synthesis method related to the invention can be used for producing the glucan-guanidine-bisphosphonate conjugate with high purity and medicinal grade. The invention also relates to an application of the glucan-guanidine-bisphosphonate conjugate in a medicine for treating tumors.
Owner:DEXTECH MEDICAL AB

Diphosphine compounds and complexes

A diphosphine precursor compounds of Formula (I), conjugates thereof of Formula (H) and radionuclide conjugate complexes thereof are disclosed herein. The compounds are advantageous at least because they enable the easy one-step extemporaneous preparation of the corresponding complexes in the clinic in high radiochemical yields and under mild conditions. Also disclosed are the methods of making the compounds and complexes herein along with their uses. The complexes are particularly useful in the field of medicine and diagnosis, such as in medical imaging and targeted payload delivery.
Owner:CANCER RESEARCH TECHNOLOGY LTD

A method for preparing and applying a lauryl diphosphonic acid / mesoporous hydroxyapatite organic-inorganic hybrid composite material.

This invention discloses a preparation method and application of a lauryl bisphosphonate / mesoporous hydroxyapatite organic-inorganic hybrid composite material, belonging to the field of landfill leachate treatment technology. A solution of dipotassium hydrogen phosphate is prepared and then added dropwise to a mixed solution of calcium chloride and lauryl bisphosphonate. The pH of the solution is adjusted with alkali, washed with water, and then heated and dried to obtain the lauryl bisphosphonate / mesoporous hydroxyapatite organic-inorganic hybrid composite material. This composite material exhibits strong complexing ability with various heavy metal ions, and its adsorption performance is minimally affected by soluble organic acids in landfill leachate, ensuring long-term locking of heavy metal ions and avoiding secondary pollution caused by the re-dissolution of heavy metals. It has strong market potential and application value in the fields of landfill leachate treatment and environmental remediation.
Owner:SHANDONG XINTAI WATER TREATMENT TECH

Diphosphine-diborane complex and method for producing same

PendingCN120897923AOrganic grignard reactionsMetallocenesEthyl groupAsymmetric hydrogenation
The present invention relates to a stable equivalent body of 2, 2 ''-bis (1-phosphinoethyl)-1, 1''-diferrocene, which is useful as a ligand in various catalytic reactions including aromatic asymmetric hydrogenation, but is difficult to synthesize and / or separate and purify, and a method for efficiently producing the same, and more particularly, to a stable equivalent body of 2, 2 ''-bis (1-phosphinoethyl)-1, 1''-diferrocene, which is useful as a ligand in various catalytic reactions including aromatic asymmetric hydrogenation. The present invention provides: a diphosphine-diborane complex represented by general formula (1) (BH3) 2); and a method for producing the diphosphine-diborane complex, the method comprising reacting a magnesium source and an oxidizing agent with a phosphine-borane complex in this order.
Owner:TAKASAGO INTERNATIONAL CORP

Method for preparing diphosphonated polysubstituted furan derivative in water phase

The invention discloses a method for preparing a diphosphonated polysubstituted furan derivative in a water phase. A beta-trifluoromethyl ketene compound and phosphine oxide are subjected to a continuous defluorination phosphonation cascade reaction in a water phase under the promotion of alkali, and finally a series of diphosphonated polysubstituted furan derivatives are obtained through post-treatment and purification. The method has the advantages of green and mild reaction conditions, good tolerance of functional groups, and high atom economic benefits.
Owner:NANJING TECH UNIV

Modified composite catalyst for piperazine synthesis and preparation method thereof

The invention discloses a modified composite catalyst for piperazine synthesis and a preparation method thereof, and relates to a catalyst technology. Cu is used as a main element of the catalyst, Cu and SiO2 are co-deposited on a negative electrode titanium plate in an electro-deposition mode to obtain Cu / SiO2, SiO2 is used as a carrier, the dispersity of Cu is improved, reduction of Cu active sites caused by agglomeration is avoided, and meanwhile, the preparation method of the modified composite catalyst for piperazine synthesis has a good application prospect. A diphosphonic acid compound, nickel salt and zirconium salt form metal phosphonate, the metal phosphonate and a Cu / SiO2 composite material are subjected to a hydrothermal reaction, and then the metal phosphonate and the Cu / SiO2 composite material are calcined to form the Ni / Zr doped composite Cu-based catalyst, so that additional Lewis acid sites can be provided, and the rate and efficiency of the catalytic reaction are improved.
Owner:ANHUI CHANGHUA CHEM CO LTD

Regeneration method of epoxidation reactor

The present invention relates in a first aspect to a process for regeneration of an epoxidation reactor that has been used in a process for the preparation of oxidized olefins, the process comprising: (i) providing an organic solvent, an olefin, an epoxidation agent and water to the reactor comprising a heterogeneous epoxidation catalyst in an epoxidation zone, to form a reaction mixture comprising an olefin, hydrogen peroxide, water, and an organic solvent; (ii) subjecting the mixture of (i) in the epoxidation zone of the reactor to epoxidation conditions in the presence of the catalyst, thereby obtaining a mixture comprising water, the organic solvent and an olefin oxide; (iii) removing the mixture comprising water, the organic solvent and the olefin oxide as obtained in (ii) from the reactor; whereby the precipitate is deposited in the reactor; the regeneration method comprises the following steps: (a) stopping supplying the organic solvent, the olefin, the epoxidation agent and the water to the reactor; (b) introducing a liquid aqueous system into the reactor wherein the liquid aqueous system comprises a chelating agent comprising a bisphosphonic acid of formula (I): (OH) 2 (O =) P-CR1R2-P (= O) (OH) 2 (I) wherein R1 and R2 are independently selected from the group consisting of a hydrogen atom, a hydroxyl group and a C1 to C5 alkyl group wherein R1 is preferably a hydroxyl group and R2 is preferably a methyl group (1-hydroxyethylidene-1, 3, 4-triazole-1-yl), 1, 1-diphosphonic acid, HEDP). A second aspect of the invention relates to a combined preparation process of an olefin oxide comprising a preparation stage and a regeneration stage of an epoxidation reactor, the preparation stage comprising steps (i), (ii) and (iii), whereby precipitates are deposited in the reactor; the regeneration stage comprises steps (a) and (b).
Owner:BASF SE +1

An alkali-magnesium cement-based emulsified asphalt mortar for semi-flexible pavement, its preparation method and application

The present invention relates to the field of pavement materials, and specifically discloses an alkali-magnesium cement-based emulsified asphalt mortar for semi-flexible pavements, its preparation method and application. The alkali-magnesium cement-based emulsified asphalt mortar for semi-flexible pavements is made from raw materials including an alkali-magnesium cement base material, cationic emulsified asphalt, hydroxyethylidene diphosphonate, filler and water. The raw materials of the alkali-magnesium cement base material include the following components in parts by weight: 289.3-309.4 parts of magnesium oxide, and 140.6-160.7 parts of magnesium sulfate. The weight part ratio of the dosage of hydroxyethylidene diphosphonate to the dosage of magnesium oxide is (1.45-1.55: 289.3-309.4). The toughness of the alkali-magnesium cement-based emulsified asphalt semi-flexible pavement material of the present invention is further improved, and it is not easy to crack, further improving the service life and safety performance of the road.
Owner:YANGZHOU UNIV +1

Anti-yellowing regenerated spandex and preparation method thereof

The invention relates to anti-yellowing regenerated spandex and a preparation method thereof, the anti-yellowing regenerated spandex comprises recycled spandex, a chain extender and a chelating agent, the recycled spandex comprises one or more of spandex waste silk, spandex waste or spandex components of waste fabrics; the chain extender comprises a bifunctional epoxy compound; the chelating agent is prepared from one or more of triphenyl phosphate, tripolyphosphate, hexametaphosphate, amino trimethylene phosphonate and hydroxyethylidene diphosphonate. Recycled spandex is adopted as a main raw material, and yellowing of a product in the storage and use process is remarkably delayed on the basis of guaranteeing the comprehensive performance of the fiber through repolymerization and addition of specific functional auxiliaries.
Owner:ZHEJIANG HUAFENG SPANDEX

Methods and compositions for in situ sequencing

The present disclosure relates in some aspects to methods, systems, and kits for using diphosphonic acid to promote N—O bond cleavage in a 3′ O—NH2 nucleotide in a cell or tissue sample. In some aspects, diphosphonic acid is used to promote N—O bond cleavage in a 3′ O—NH2 blocked reversible terminator during multiple cycles of a nucleic acid sequencing reaction in a cell or tissue sample. In some embodiments, the chemical reaction of the 3′ O—NH2 blocked reversible terminator with diphosphonic acid releases free alcohols and phosphoric acid derivatives, which are not damaging to the cell or tissue sample.
Owner:10X GENOMICS INC

A technetium 99 Tc] methylenediphosphonate oral formulation, process for its preparation, use

ActiveCN119564888BPowder deliverySkeletal disorderMethylenediphosphonic AcidMethylene diphosphonate
The present invention provides a technetium [ 99 Tc] methylene diphosphonate oral preparation and its preparation method and application, which are prepared from the following raw materials in parts by weight: methylene diphosphonic acid; reducing agent; pertechnetium [ 99 Tc] sodium sulfate; adhesive; solvent; the adhesive is made of polymer material; wherein, methylene diphosphonic acid, a reducing agent and high technetium [ 99 Technetium [ 99 Tc] methylene diphosphonate, and promptly 99 The invention discloses a method for preparing the technetium [ 99 The oral preparation of [Tc] methylene diphosphonate has good bioavailability. While achieving the same drug efficacy, it can reduce gastrointestinal irritation and improve patient compliance, achieving unexpected technical effects.
Owner:CHENGDU YUNKE PHARMA

Preparation method and application of transition metal phosphide catalyst

The invention relates to the technical field of catalysis, and particularly discloses a preparation method and application of a transition metal phosphide catalyst. The invention relates to a preparation method of a transition metal phosphide catalyst. The preparation method comprises the following steps: (1) carrier pretreatment: taking a carrier and carrying out dipping treatment by using an alkali solution or an acid solution; (2) active metal loading: dipping the pretreated carrier obtained in the step (1) in a solution containing active metal, and adding 1-hydroxyethylidene-1, 1-diphosphonic acid at the same time; and (3) phosphating treatment: phosphating the carrier loaded with the active metal in the step (2) in an inert atmosphere to obtain the transition metal phosphide catalyst, in the step (2), a functional auxiliary agent accounting for 3-5% of the weight of the carrier is also added, the functional auxiliary agent is composed of titanium oxide, zirconium oxide and cerium oxide, and the weight ratio of titanium oxide to zirconium oxide to cerium oxide is (2-3): (1.4-1.6): 1. The transition metal phosphide catalyst prepared by the invention is improved in the aspects of low-temperature fluidity improvement and durability of biodiesel.
Owner:SHANGHAI XIANGWEI NEW ENERGY TECHNOLOGY CO LTD

Desulfurizer for oil and gas field and preparation method thereof

The application belongs to the technical field of desulfurizer preparation, and particularly relates to a desulfurizer for oil and gas field oil production and a preparation method thereof. The desulfurizer for oil and gas field oil production comprises the following raw materials: N-octadecyl-1,3-propanediamine, an ionic liquid-organic copper mixture, ammonium molybdate, sodium lysine, hydroxyethylidene diphosphonic acid, polyoxyethylene sorbitan monostearate, and water as the balance. The desulfurizer for oil and gas field oil production uses water as a solvent, and N-octadecyl-1,3-propanediamine, the ionic liquid-organic copper mixture and ammonium molybdate in the raw materials as main desulfurization components to remove inorganic sulfur and organic sulfur, and sodium lysine, hydroxyethylidene diphosphonic acid and polyoxyethylene sorbitan monostearate are added to enhance the stability and permeability of the system, so that the raw materials synergize to achieve efficient removal of inorganic sulfur and organic sulfur in oil and gas field oil production.
Owner:SHENGLI OILFIELD HAIFA ENVIRONMENTAL PROTECTION CHEM CO LTD +1

A chromium phosphonate metal-organic framework material, a solvent-free preparation method thereof, and applications thereof

The present invention belongs to the technical field of crystalline materials, and particularly relates to a chromium phosphonate metal organic framework material and a solvent-free preparation method and application thereof. The chemical formula is [Cr(H2BPD) 1.5 The preparation method comprises the following steps: mixing an organic ligand, p-terephthalenediphosphonic acid, with chromium chloride hexahydrate, grinding the mixture, heating the mixture, and, after completion of the reaction, spontaneously cooling the mixture to room temperature. The mixture is repeatedly washed with ethanol until the supernatant is colorless and transparent, and vacuum-dried to obtain a light green chromium phosphonate metal-organic framework material. The chromium phosphonate metal-organic framework material can be used in proton conduction.
Owner:TIANJIN POLYTECHNIC UNIV

Environment-friendly silicon material surface cleaning reagent and preparation method thereof

The invention discloses an environment-friendly silicon material surface cleaning reagent and a preparation method thereof, the environment-friendly silicon material surface cleaning reagent comprises hydrofluoric acid, citric acid, EDTA tetrasodium, 1-hydroxyethylidene-1, 1-diphosphonic acid and pure water, and the environment-friendly silicon material surface cleaning reagent is characterized in that the citric acid accounts for 20-25%, the hydrofluoric acid accounts for 4-5%, the EDTA tetrasodium accounts for 0.5-1%, the 1-hydroxyethylidene-1, 1-diphosphonic acid accounts for 0.5-1%, and the pure water accounts for 0.5-1%. The proportion of the hydroxyethylidene diphosphonic acid is 0.5%-1%, the proportion of the pure water is 70%-73%, the chemical formula of the hydrofluoric acid is HF, the chemical formula of the citric acid is C6H8O7, the chemical formula of the EDTA tetrasodium is C10H12N2Na4O8, the chemical formula of the hydroxyethylidene diphosphonic acid is C2H8O7P2, and the chemical formula of the pure water is H2O. According to the environment-friendly silicon material surface cleaning reagent and the preparation method thereof, citric acid is used as a main material, HF and the chelating agent are matched, metal pollutants and surface oxides in a silicon material are removed, meanwhile, the reagent does not contain substances which chemically react with the silicon material, raw material loss is effectively avoided, and the raw material utilization rate is increased.
Owner:HONGYUAN NEW MATERIAL BAOTOU CO LTD +1

Liquid gel breaker for guanidine gum and polymer fracturing fluid as well as preparation method and application of liquid gel breaker

The invention relates to the technical field of oilfield exploitation, in particular to a liquid gel breaker for guanidine gum and polymer fracturing fluid as well as a preparation method and application of the liquid gel breaker. The cleaning agent is prepared from, by mass, 10%-12% of ammonium persulfate, 6%-7.5% of sodium hypochlorite, 0.5%-1% of aminoethanol phosphoric acid, 0.5%-1% of hydroxyethylidene diphosphonic acid, 0.4%-0.8% of ethylene diamine tetraacetic acid disodium salt, 10%-12% of benzoyl peroxide, 0.5%-1% of tetramethylguanidine, 0.5%-1% of triethylamine, 3%-4% of isopropanol and the balance deionized water, and the total amount is 100%. The oxidant stabilizer is added into the liquid gel breaker, so that the oxidant is prevented from being decomposed and damaged under the storage condition, and the liquid gel breaker has the characteristics of high flash point and low volatility and is safe to store; the added oxidant activator can be suitable for gel breaking under a low-temperature condition, and the applicable range of the gel breaking temperature reaches 20-180 DEG C; and the fracturing fluid is thorough in gel breaking and does not cause damage to artificial fractures and reservoirs.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Synthesis method of hydroxymethylenediphosphonic acid disodium salt

PendingCN121554504AGroup 5/15 element organic compoundsMethylenediphosphonic AcidSulfite salt
The invention discloses a synthesis method of hydroxymethylenediphosphonic acid disodium salt, and relates to the field of radiopharmaceuticals, the synthesis method comprises the following steps: S1, tetraisopropyl methylenediphosphonate is subjected to a substitution reaction in a sodium hypochlorite solution to obtain tetraisopropyl dichloromethylenediphosphonate; s2, carrying out a dehalogenation reaction on the tetraisopropyl dichloromethylene diphosphate in a sodium sulfite solution to obtain tetraisopropyl monochloromethylene diphosphate; s3, carrying out a hydrolysis reaction on the tetraisopropyl monochloromethylenediphosphonate, so as to obtain pyridinium monochloromethylenediphosphonate; and S4, carrying out substitution reaction on the monochloromethylenediphosphonic acid pyridinium salt to obtain the hydroxymethylenediphosphonic acid disodium salt. The adopted raw materials and reagents are wide in source, low in price and easy to obtain, high-risk or highly-toxic chemicals are not contained, the technological process is environmentally friendly, the development direction of green chemistry is met, and good industrial application prospects are achieved.
Owner:JIANGSU HUAYI TECH

Method and composition for inhibiting scale in oil-bearing formations

The invention relates to the field of organic chemistry, and more particularly to compositions for inhibiting the deposition of scale in an oil-bearing formation and in gas and oilfield equipment and to methods for the use of said compositions. A method for inhibiting scale in oil-bearing formations is characterized in that a water-based composition is introduced into the near-wellbore region of a formation, said composition including (3-aminopropyl)triethoxysilane (APTES), sodium lignosulphonate (LS) and a scale inhibitor, wherein at least one of the following agents is used as the scale inhibitor: hydroxyethylidene diphosphonic acid (HEDP), hydroxyethylidene diphosphonic acid tetrasodium salt or a zinc complex of hydroxyethylidene diphosphonic acid disodium salt (HEDP-Zn). The technical result is an increase in the efficiency of scale inhibition as a result of the prolonged release of the inhibitor.
Owner:OBSHCHESTVO S OGRANICHENNOI OTVETSTVENNOSTIU IRKUTSKAIA NEFTIANAIA KOMPANIIA

A nano-slow-release capsule for scale inhibitor and a preparation method and application thereof

The application relates to the technical field of oilfield exploitation, and discloses a nano slow-release capsule for scale inhibitors and a preparation method and application thereof. The method comprises the following steps: (1) emulsifying a hydroxyethylidene diphosphonic acid-containing aqueous solution I, an oil phase and a nonpolar organic solvent to obtain a W / O emulsion; (2) performing heating and solidification treatment on the W / O emulsion to obtain the nano slow-release capsule for scale inhibitors; and the oil phase contains polymethyl methacrylate, an emulsifier and a polar organic solvent. The nano slow-release capsule has good slow-release performance, and solves the problem of low utilization rate of hydroxyethylidene diphosphonic acid in the process of scale inhibition in oilfield exploitation.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Concrete admixture for inhibiting negative effects of flocculants, and preparation method and application thereof

ActiveCN119977404BSodium phosphatesTurpentine
The application relates to the technical field of concrete admixtures, and particularly discloses a concrete admixture for inhibiting negative effects of flocculants and a preparation method and application thereof. The concrete admixture for inhibiting negative effects of flocculants comprises the following components in mass fractions: 1-2 parts of a water reducing agent, 1-1.5 parts of hydroxyethylidene diphosphonic acid, 0.1-0.5 parts of sodium monofluorophosphate, 0.1-0.5 parts of glucomannan and 0.05-0.1 parts of turpentine. The concrete admixture for inhibiting negative effects of flocculants can effectively neutralize or weaken the adverse effects of flocculants on the performance of concrete, while keeping good workability and mechanical properties of the concrete, so that the long-term durability of the concrete is comprehensively improved.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY

A method for preparing ultra-high purity lead by electrolysis

PendingCN122303965AElectrolytic agentLead carbonate
This invention belongs to the field of wet electrolytic refining technology for recycled lead, and provides a method for electrolytically preparing ultra-high purity lead. It involves constructing a 1-hydroxyethylidene-1,1-diphosphonic acid-modified lead carbonate seed layer on the cathode plate surface, combined with a bypass impurity removal unit to continuously remove impurity ions from the electrolyte, and then using staged current density electrolysis to ensure uniform nucleation and stable deposition of lead on the cathode surface. The resulting cathode lead has a purity of not less than 99.996 wt%, and the deposited layer is dense, flat, and has a low risk of inclusions. This method solves the problems of difficulty in balancing high-throughput deposition and ultra-high purity, as well as the difficulty in synchronizing seed layer adhesion stability and pollution control in existing processes. It is suitable for the high-value preparation of recycled lead from waste lead-acid batteries.
Owner:HUNAN TENGCHI ENVIRONMENTAL PROTECTION TECH CO LTD

composition

PCT designated stageWO2026099378A1EpoxyPolymer science
The invention relates to compositions comprising Component A: Polyalkylene terephthalate in an amount of between 1 and 85 wt%; Component B: at least one organic phosphinic salt of formula (I) and / or at least one organic diphosphinic salt of formula (II), in which R1, R2 are identical or different and stand for a linear or branched C1- C6-alkyl and / or for C6-C14-aryl, R3 stands for linear or branched C1-C10alkylene, C6-C10arylene or for C1-C6-alkyl-C6-C-10-arylene, or C6-C10-aryl-C1-C6alkylene, M is aluminium, zinc or titanium, m is an integer of 1 to 4; n is an integer of 1 to 3, and x is 1 or 2, wherein n, x and m in formula (II) may at the same time adopt only integer values such that the diphosphinic salt of formula (II) as a whole is uncharged; in an amount of between 3 and 30 wt%; Component C: phosphazene in an amount between 0.5 and 15 wt%; Component D: Reaction product with melamine derivative with phosphoric acids or condensed phosphoric acids or mixtures thereof, in an amount of between 0.5 and 20 wt%; Component E: Epoxy compound with at least two epoxy groups per molecule in an amount of between 0.1 and 7 wt%; Component F: Copolyester comprising polyester hard segments, and soft segments derived from polyalkylene oxide glycol, wherein Component F is present in an amount of between 0.1 and 85 wt%; Component G: Reinforcers in an amount of between 5 and 60 wt%; Component H: Dicarboxylic acid anhydride functionalized polyolefin in an amount of between 0.1 and 5 wt%; and optionally Component I: a metal carbonate in an amount of between 0 and 5 wt%; and / or Component J: further additives in an amount of between 0 and 30 wt%; wherein the weight percentage is with respect to the total weight of the composition; as well as products made therefrom.
Owner:ENVALIOR DEUTSCHLAND GMBH +3