The invention discloses an ESPR-based heavy metal analyzer, which comprises a chemical reaction part, a surface plasma resonance spectrometer and an information processing system, wherein the chemical reaction part includes a detection cell, a counter electrode, a reference electrode, an array electrode and an electrochemical workstation; the array electrode is positioned at the bottom of the detection cell, the counter electrode and the reference electrode are inserted in the detection cell, the counter electrode, the reference electrode and the array electrode are respectively connected to the electrochemical workstation; the electrochemical workstation and the surface plasma resonance spectrometer are respectively connected to the information processing system. The invention further discloses an analysis method of the ESPR-based heavy metal analyzer, which achieves the simultaneous detection of multi-objective heavy metals, enhances the detection sensitivity and spatial resolution, and reduces damages on thin metallic membrane plate (the array electrode and active points thereof).