The invention discloses a preparation method of a double-layer composite
solid electrolyte membrane, which comprises the following steps: step 1, stirring a
polymer matrix, a
lithium salt, a
solid electrolyte and an
organic solvent at 60-90 DEG C for 1-12 hours, and uniformly mixing to prepare a
solid electrolyte glue solution A; step 2, adding a
polymer matrix, a
lithium salt and a
side chain type polyion liquid into an
organic solvent, and stirring at 60-90 DEG C for 1-12 hours to uniformly mix to obtain a solid electrolyte glue solution B; and 3, uniformly
coating a polyfluortetraethylene plate with the solid electrolyte glue solution A, putting the polyfluortetraethylene plate into a
drying box,
drying at 50-120 DEG C for at least 2 hours, taking out the polyfluortetraethylene plate, forming a diaphragm A on the polyfluortetraethylene plate, uniformly
coating the diaphragm A with the solid electrolyte glue solution B, putting the polyfluortetraethylene plate into the
drying box, drying at 50-120 DEG C for at least 12 hours, taking out the diaphragm, and peeling off the diaphragm to obtain the double-layer composite solid electrolyte membrane. By adopting the AB double-layer
diaphragm structure design, the tensile strength of the whole composite solid electrolyte membrane is enhanced, the interfacial compatibility with a positive
electrode is effectively improved, and the
interfacial impedance is reduced.