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57results about How to "Easy regeneration" patented technology

Defluorination absorbing material based on aluminum base composite oxides and its preparation method and use and special device of the preparation method

ActiveCN101507911AExcellent adsorption and defluorination performanceGood defluoridation effectOther chemical processesChemical reactionWater source
The invention belongs to the field of materials for removing fluorine in water, and in particular relates to a fluorine-removal adsorption material based on alanate and aluminum-based composite oxide, a preparation method and uses of the same, and a special device for the preparation method. The fluorine-removal adsorption material based on the aluminum-based composite oxide, which is prepared by a heterotopic preparation method or an in-situ preparation method, comprises two parts of an active composition and a porous supported substrate, wherein the active composition is the aluminum-based composite oxide prepared from an aluminum salt solution and an inorganic alkaline solution by chemical reaction; and the aluminum-based composite oxide is loaded on the surface of the porous supported substrate by an in-situ loading method, and the mass ratio of the aluminum-based composite oxide to the porous supported substrate is 0.25-25:100. The fluorine-removal adsorption material based on the aluminum-based composite oxide can be used for the adsorption of fluorine pollutants in the water and particularly common fluorine in underground drinking water sources. In addition, the material can also be used for removing pollutants such as arsenic, iron, manganese, phosphate, and the like in the water.
Owner:清华苏州环境创新研究院

Preparation method of non-sintered ceramsite with ammonia nitrogen adsorption function

The invention provides a preparation method of non-sintered ceramsite with an ammonia nitrogen adsorption function. The method comprises the following steps: 1) preprocessing raw materials: immersing fly ash in a NaOH solution, washing the immersed fly ash with water, and drying the washed fly ash; drying excess sludge, calcium oxide, sodium bicarbonate and portland cement; and drying all above raw materials, crushing the dried raw materials, and sieving the crushed raw materials; 2) mixing the raw materials: mixing the above preprocessed raw materials, by mass, 66-85% of fly ash, 3-8% of calcium oxide, 7-13% of excess sludge, 1-5% of sodium bicarbonate and 3-9% of portland cement; 3) granulating: dissolving water glass in water, pouring the obtained water glass solution to the mixed raw materials, and uniformly stirring to make a blank; 4) curing: covering the blank with a wet gauze, regularly watering the blank, putting the blank in a sterilization pot, and carrying out steam curing; and 5) ageing: putting the cured blank in dry environment to prepare the non-sintered ceramsite with an ammonia nitrogen adsorption function. The non-sintered ceramsite prepared in the invention has the advantages of low price, high economical efficiency, environmental protection, and suitableness for treatment of medium and low concentrations of ammonia nitrogen wastewater.
Owner:WUHAN UNIV

Dividing wall rotary kiln device for flue gas dehydration

The invention relates to a dividing wall rotary kiln device for flue gas dehydration. The dividing wall rotary kiln device comprises loading equipment, a charging bin, a conveyor, a rotary kiln, waste heat generating equipment and a spare unloading bin, wherein the rotary kiln is a dividing wall rotary kiln, and is composed of an outer ring and an inner ring which are coaxially mounted; a ring-shaped material channel is arranged between the inner ring and the outer ring; the ring-shaped material channel is provided with refractory material support; and a furnace hearth is arranged in the center of the inner ring. The furnace hearth is connected with the waste heat generating equipment by a kiln tail cover. The loading equipment is communicated with the ring-shaped material channel by the loading bin, the conveyor and a charging ring; the ring-shaped material channel is connected with the spare unloading bin by a discharge ring. A wet flue gas inlet is connected with a flue gas pipeline; a gas outlet is divided into two paths, one path is connected with a dry flue gas exhaustion system, and the other path is connected with a condenser; and connecting pipelines are provided with valves respectively. According to the dividing wall rotary kiln device, lime is used as a dryer, and the ring-shaped material channel of the dividing wall rotary kiln is used for drying and dehydrating the industrial flue gas, so that the flue gas diffusion capacity is improved in a facilitated mode, the acid rain and atmospheric contamination is reduced, and the dwelling and living environment of people is improved.
Owner:SHIJIAZHUANG XINHUA IND FURNACE CO LTD

Preparation method for core-shell perovskite-type catalyst for preparing methanol through methane

The invention relates to a preparation method for a core-shell perovskite-type catalyst for preparing methanol through methane. The general formula of the core-shell perovskite-type catalyst is Fe2O3@A(1-m)A'mB(1-n)B'nO3. The preparation method for the core-shell perovskite-type catalyst comprises the following steps: adding nano-sized or micron-sized Fe2O3 into ethanol; dispersing under the effect of ultrasonic waves; removing the supernatant after complete precipitation; using ultrasonic waves to disperse Fe2O3 into deionized water to obtain a Fe2O3 suspension; adding soluble salts corresponding to A, A', B and B' to deionized water; stirring to allow the soluble salts to dissolve completely; adding a complexing agent; after heating and stirring for complexing, adding to the Fe2O3 suspension; stirring evenly; adding glycol; after thorough stirring, evaporating to obtain a colloidal mixture; drying and roasting to obtain the core-shell perovskite-type catalyst. The core-shell perovskite-type catalyst is a perovskite-type oxide catalyst of a core-shell structure; the active constituent, namely Fe2O3 is wrapped in the perovskite oxide, so that the phenomenon that the Fe2O3 is reduced to elementary substance Fe in the catalytic oxidation process, and the activity of the core-shell perovskite-type catalyst declines due to the sintering and accumulation of the Fe, is effectively prevented.
Owner:NORTHEAST GASOLINEEUM UNIV

Preparation method of sludge ceramsite used for medium and low concentration ammonia nitrogen wastewater treatment

The invention provides a preparation method of sludge ceramsite used for medium and low concentration ammonia nitrogen wastewater treatment. The preparation method comprises the following steps: immersing fly ash in a 3-6% NaOH solution at 20-30DEG C for 3-4d, washing the immersed fly ash with deionized water, and drying the washed fly ash at 100-110DEG C; drying excess sludge and clay at 100-110DEG C; drying above three raw materials, crushing the dried three raw materials, and sieving the crushed three raw materials for later use; fully mixing, by mass, 30-60% of the preprocessed fly ash, 30-60% of the preprocessed excess sludge and 10% of the preprocessed clay to obtain a dry material; adding a proper amount of deionized water to the dry material, uniformly stirring to prepare a 1-3mm blank, placing the blank in a tray, and drying the tray in a 110DEG C oven until the surface of the blank has no water; putting the dried blank in a muffle furnace, heating the blank to 350-500DEG C, preheating the blank for 10-40min, heating the blank to 800-1100DEG C, sintering the blank for 10-25min, cooling the obtained product in the furnace to 180-200DEG C, and taking out the cooled product to obtain the sludge ceramsite. The sludge ceramsite prepared in the invention has the advantages of low price, economical property, high efficiency, environmental protection, and suitableness for treatment of medium and low concentration ammonia nitrogen wastewaters.
Owner:WUHAN UNIV

Dual-polarity battery stack

The invention provides a dual-polarity battery stack. Liquid holes formed in same positions on a single pole plate and a bipolar plate form a tubular liquid injection passage, a liquid injection and sealing device is arranged in the liquid injection passage of the dual-polarity battery stack and comprises a cylinder, a liquid injection hole is formed in the cylinder, the cylinder is a movable cylinder capable of rotating or moving upwards and downwards, and connection or staggering of the liquid injection hole and an electrolyte runner of the dual-polarity battery is achieved by rotation or moving of the rotatable cylinder; or the cylinder is a fixed cylinder, the fixed cylinder is fixedly arranged in the liquid injection passage, a liquid injection hole of the fixed cylinder communicateswith the electrolyte runner of the dual-polarity electrode plate, a movable piece is arranged in the fixed cylinder, and opening or closing of the liquid injection hole is achieved by rotation or upward-downward moving of the movable piece in the fixed cylinder. By the liquid injection and sealing device, electrolyte injection can be effectively completed, and the problem of short circuit in the battery stack caused by an electrolyte passing through the liquid injection passage also can be effectively solved.
Owner:BEIJING HAWAGA POWER STORAGE TECH

Fish enhancement and releasing station circulation water treatment tower and treatment system of water-power engineering

The invention discloses a fish enhancement and releasing station circulation water treatment tower and a treatment system of water-power engineering, belonging to the field of water resources and hydropower engineering, and providing a fish enhancement and releasing station circulation water treatment tower which is relatively simple in structure, relatively convenient to operate and maintain and meanwhile capable of increasing the content of dissolved oxygen in purified water, of the hydropower engineering. A first screening plate, a packing filtering layer, a zeolite fluidized bed layer and a second screening plate are arranged inside the treatment tower, so as to achieve purification treatment on wastewater. Meanwhile, by feeding air into the zeolite fluidized bed layer, the fluidization effect is improved, and the content of dissolved oxygen in water is increased; in addition, a salt dissolving pond can be constructed, and regeneration operation on zeolite can be conveniently performed. By adopting the fish enhancement and releasing station circulation water treatment tower and the treatment system, the sewage purification effect is improved, the equipment occupied space is reduced, the content of dissolved oxygen in purified water is increased, the operation and the maintenance are convenient, the regeneration operation on zeolite is simplified, and the regeneration efficiency is improved.
Owner:CHINA HYDROELECTRIC ENGINEERING CONSULTING GROUP CHENGDU RESEARCH HYDROELECTRIC INVESTIGATION DESIGN AND INSTITUTE

Method for synthesizing mixed ester through catalyst distillation

The invention discloses a method for synthesizing mixed ester through catalyst distillation. The method comprises the following steps: by taking ethanol, n-butyl alcohol and acetic acid as raw materials, a strong acid cation exchange resin as a catalyst and a catalyst distillation tower as a reactor, performing a catalyst distillation backflow reaction, and finally performing phase separation, thereby obtaining mixed ester of ethyl acetate and butyl acetate. According to the method, the intense water carrying power of the butyl acetate is utilized, azeotrope is prepared from the butyl acetate,butanol and water, and water generated from reactions is completely carried out from a tower top. Therefore, the conversion rate of alcohol reactants and the content of the acetic acid in the catalyst distillation tower can be increased, and the influence of product water to the reaction process in the tower is also eliminated. A tower top product is generally an ester-water mixture and comprisesa very small amount of acetic acid, so that the later purification difficulty of the ethyl acetate and the butyl acetate is greatly reduced, the production procedures are simplified, the production efficiency is improved, and the energy consumption is reduced.
Owner:GUANGXI UNIV FOR NATITIES

Renewable compound ionic liquid desulfurizing agent as well as preparation method and application thereof

The invention discloses a regenerable compound ionic liquid desulfurizing agent and a preparation method and an application thereof. The regenerable compound ionic liquid desulfurizing agent is formed by mixing a desulfurization component and a diluting solvent, the desulfurization component is composed of, by mass, ionic liquid, an alcohol amine solution and an enhancer, and the mass fraction of the ionic liquid accounts for 25-40% of that of the desulfurization component; the alcohol amine solution accounts for 25-40% of the mass fraction of the desulfurization component, and the enhancer accounts for 20-50% of the mass fraction of the desulfurization component; the ionic liquid is at least two of 1-ethyl-3-methylimidazole trifluoromethanesulfonate, 1-ethyl-3-methylimidazole propionate, 1-ethyl-3-methylimidazole diamine nitrile, 1-ethyl-3-methylimidazole bis (trifluoromethanesulfonyl) imide, 1-ethyl-3-methylimidazole histidine, 1-ethyl-3-methylimidazole glycolate, and 1-methyl-3-sulfobutyl imidazole bisulfate. The desulfurizing agent has a good removal effect on organic sulfur such as carbonyl sulfide, carbon disulfide and mercaptan, the adsorbed organic sulfur is desorbed through heating after adsorption saturation, and the desulfurizing agent can be regenerated and reused for multiple times.
Owner:ZHEJIANG UNIV OF TECH

Detection method and collection device for mercury in waste incineration flue gas

The invention relates to the technical field of environmental monitoring, in particular to a method for detecting mercury in waste incineration flue gas, which comprises the following steps: separating particulate mercury and gaseous mercury in flue gas through a filter membrane, and measuring the content of the particulate mercury in the flue gas; introducing the flue gas into a clay mineral solid adsorbent wetted by deionized water, and collecting mercuric oxide in the flue gas; introducing the flue gas into a solid acid adsorbent wetted by deionized water, and collecting the element mercury in the flue gas; heating and desorpting the clay mineral solid adsorbent and the solid acid adsorbent to respectively measure the content of mercuric oxide and the content of elemental mercury. The invention further relates to a collecting device which comprises a constant-temperature sampling gun and a constant-temperature adsorption bottle box, wherein a constant-temperature filter is arranged in the constant-temperature sampling gun; a first bottle body filled with a clay mineral solid adsorbent and a second bottle body filled with a solid acid adsorbent are sequentially communicated in the constant-temperature adsorption bottle box in the flue gas flowing direction. The device is suitable for a high-temperature, high-humidity and high-corrosion flue gas detection environment, and the higher the temperature, humidity and acidity of the flue gas are, the more beneficial to mercury collection of a clay mineral solid adsorbent and a solid acid adsorbent.
Owner:福建省锅炉压力容器检验研究院

A Partitioning Wall Rotary Kiln Device for Flue Gas Dehydration

The invention relates to a dividing wall rotary kiln device for flue gas dehydration. The dividing wall rotary kiln device comprises loading equipment, a charging bin, a conveyor, a rotary kiln, waste heat generating equipment and a spare unloading bin, wherein the rotary kiln is a dividing wall rotary kiln, and is composed of an outer ring and an inner ring which are coaxially mounted; a ring-shaped material channel is arranged between the inner ring and the outer ring; the ring-shaped material channel is provided with refractory material support; and a furnace hearth is arranged in the center of the inner ring. The furnace hearth is connected with the waste heat generating equipment by a kiln tail cover. The loading equipment is communicated with the ring-shaped material channel by the loading bin, the conveyor and a charging ring; the ring-shaped material channel is connected with the spare unloading bin by a discharge ring. A wet flue gas inlet is connected with a flue gas pipeline; a gas outlet is divided into two paths, one path is connected with a dry flue gas exhaustion system, and the other path is connected with a condenser; and connecting pipelines are provided with valves respectively. According to the dividing wall rotary kiln device, lime is used as a dryer, and the ring-shaped material channel of the dividing wall rotary kiln is used for drying and dehydrating the industrial flue gas, so that the flue gas diffusion capacity is improved in a facilitated mode, the acid rain and atmospheric contamination is reduced, and the dwelling and living environment of people is improved.
Owner:SHIJIAZHUANG XINHUA IND FURNACE CO LTD
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