The invention discloses an activecarbon catalystloaded with copper-containing high-entropy alloy for acetylene hydrochlorination reaction as well as a preparation method and application of the active carbon catalyst. The catalyst comprises an activated carbon carrier and a metal component loaded on the carrier, the metal component is composed of a Cu element, a metal element A and a metal element B, the metal element A represents one or two precious metal elements of Au, Ag, Pd, Pt and Ru, the metal element B is selected from two or three metal elements of Fe, Mn, Zn, K, Ca, Sn, Ni, Co, Cr, Al and In, the number of the metal elements A and B is four, and the metal element B represents one or two precious metal elements of Au, Ag, Pd, Pt and Ru. The loading capacity of the copper element is 10-30 wt%, the loading capacity of each of the A metal elements is 0.01-0.05%, and the loading capacity of each of the B metal elements is 10-30 wt%. According to the preparation method of the catalyst, a traditional impregnation method and an electromagnetic field stirring technology are combined, and the prepared catalyst shows super-long stability and super-high activity in a reaction for preparing vinyl chloride through acetylene hydrochlorination.