The invention relates to a polyolefin powder capable of uniform mixing with plant small pieces and a preparation method of the polyolefin powder. The powder comprises the ingredients of polyethylene, polypropylene, polystyrene or the mixture of the three, the particle size of the powder is 100nm-1mm, apparent density is 0.18g/mL-0.40g/mL, and the uniform mixing of the powder with the small pieces of plant root, stem, trunk, leaf, and seed case can be achieved through a mixing medium. The preparation process of the powder comprises the following steps of: mixing solid materials in various forms with a special solvent, heating the mixture for dissolution, carrying out thermo-precipitation using a special precipitant, carrying out separation, rolling homogenization and dispersion, separating the solvent and the precipitant for recycling, drying the resulting product, and grinding the dried product. The whole preparation process has the characteristics of material recycling, less volatile matter, strong environment protection and the like; the prepared powder can be applied to preparing an environment-friendly composite material which is further applied to fabricating a container, furniture, a finishing material, a toy and the like; and the prepared powder can be used as raw material for powder coating and a hot melt adhesive material which is easy in uniform coating.