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37results about How to "Play a hydrophobic role" patented technology

Amphiprotic amphiphilic leather retanning fatting agent and preparation method thereof

The invention discloses amphiprotic amphiphilic leather retanning fatting agent and a preparation method of the amphiprotic amphiphilic leather retanning fatting agent. The constituent of the amphiprotic amphiphilic leather retanning fatting agent is (methyl) crylic acid-N-alkyl diene propyl amine-diallylamine terpolymer. According to the preparation method of the amphiprotic amphiphilic leather retanning fatting agent, N-alkyl diene propyl amine is firstly prepared, then the N-alkyl diene propyl amine, diallylamine, and (methyl) crylic acid are adopted for a free radical copolymerization reaction under the acidic condition to obtain an aqueous dispersoid containing the (methyl) crylic acid-N-alkyl diene propyl amine-diallylamine terpolymer, the solid content of a product is adjusted to 15-20% with water, and the amphiprotic amphiphilic leather retanning fatting agent is obtained. The molecular structure of the amphiprotic amphiphilic leather retanning fatting agent contains carboxyl of negative ions and tertiary amino of positive ions, and the polymer can display different electrical properties under different conditions of potential of hydrogen (PH), meanwhile the polymer contains alkyl of a long chain, and functions of lubrication fibers can be achieved. The polymer has the function of retanning, fatting and dyeing assistance at the same time, physical and mechanical properties of processed crust leather, such as tensile strength, fullness, softness and elasticity, are all improved, the surface of the processed crust leather is strong in lubrication feel and comfortable in hand feel, and the leather has a good waterproof performance.
Owner:四川德赛尔新材料科技有限公司

Phosphate leather fat liquoring agent and preparation method thereof

The invention provides a phosphate leather fat liquoring agent and a preparation method thereof. A phosphorylated polyether modified aminosilicone leather fat liquoring agent is prepared by modifying aminosilicone with allyl polyether and P2O5 serving as raw materials. An active group phosphate radical in a molecular structure can react with an amino group in a leather fiber structure, and can be tightly combined with chromium in chrome tanned leather in the form of a coordination bond, so that a phosphorylation product can be stored in leather fiber for a long time, and leather is endowed with certain flame retardance and antistatic property. A certain quantity of hydrophilic oxyethyl groups are introduced onto the molecular structure, so that the properties of water solubility, acid resistance, electrolyte resistance and the like of aminosilicone are improved effectively, and the self-emulsifying property of aminosilicone is enhanced. Aminosilicone is a leather fat liquoring agent per se, and can be used for endowing leather with higher flexibility and fullness and enhancing the physical and mechanical properties such as tear resistance, thickening rate and the like of the leather; and the leather fat liquoring agent with the structure has higher development and application values.
Owner:SHAANXI UNIV OF SCI & TECH

Long-acting weather-resistant chlorine salt corrosion-resistant polyester powder coating and preparation method thereof

The invention belongs to the technical field of preparation of polyester powder coatings, and particularly relates to a long-acting weather-resistant chlorine salt corrosion-resistant polyester powdercoating and a preparation method thereof. The powder coating comprises the following main raw materials in parts by weight: 530-560 parts of polyester resin, 45-60 parts of TGIC, 10-15 parts of triglycidyl trimellitate, 120-180 parts of titanium dioxide, 80-120 parts of barium sulfate, 8-12 parts of a brightening agent and 7-10 parts of leveling agent. The polyester resin used in the powder coating is good in linear structure, and excellent flowing performance is guaranteed; more trifunctional curing agents TGIC are used in the powder coating and matched with triglycidyl trimellitate with a low melting point and excellent water resistance to jointly serve as a low-temperature curing agent, the crosslinking density and water resistance of a coating film are further improved, and finally long-acting weather resistance and chlorine salt corrosion resistance are guaranteed. The final powder coating product can be used for low-temperature curing at 160 DEG C, and the prepared coating filmhas excellent long-acting weather resistance and chlorine salt corrosion resistance, and is especially suitable for infrastructure spraying of expressways, such as guardrails and bridges.
Owner:安徽鑫友高分子新材料科技有限公司

Preparation method of super-concentrated carboxyl-based ester-based emulsion polymer

The invention discloses a preparation method of a super-concentrated carboxyl-based ester-based polymer. The super-concentrated carboxyl-based ester-based polymer is prepared from the raw materials inparts by mass: 1.2-2.7 parts of hydrophilic small monomer for emulsification, 3.3-5.6 parts of hydrophobic small monomer for emulsification, 16-37 parts of carboxyl small monomer, 0.05-0.21 parts ofemulsion initiator, 2.1-5.2 parts of initiator a, 3.2-6.5 parts of initiator b, 370-440 parts of small ester-based monomers, 3.7-8.6 parts of a cross-linking agent, 3.5-7.7 parts of flexible small monomers, 19-44 parts of polyether, 0.2-0.8 part of oxidized graphene, 0.10-0.29 part of a chain transfer agent, 5-10 parts of a neutralizing agent, 5-10 parts of a pH regulator, 2.0-5.0 parts of co-emulsifier, 0.4-1.0 part of liquid film enhancer and the balance of water, the total raw materials is 1,000 parts, and the solid content is 50%. The hydrophobic monomers are adopted to prepare the polymeremulsion with excellent water resisting property. The emulsifier is self-made super-concentrated emulsifier, the generation of bubbles during the reaction is reduced, and the initiators with different initiation efficiency are adopted to stabilize the reaction rate. The polyether is added in the preparation method, and the polymer emulsion is enabled to have better connection property, and further has a good repairing effect as a waterproof coating.
Owner:HUBEI UNIV OF TECH

Preparation method of hydrophobic weather-resistant and aging-resistant composite fluorocarbon resin coating for tent

The invention discloses a preparation method of a hydrophobic weather-resistant and aging-resistant composite fluorocarbon resin coating for a tent. The preparation method comprises the following steps of uniformly mixing sericite powder, silicon carbide ceramic particles, titanium dioxide coated with coupling modified aluminum oxide powder and cerium oxide, and silicon dioxide nanometer fluid, soas to obtain a pigment filler; adding a thinner and an additive into fluorocarbon resin of film-forming resin, uniformly stirring by a high-speed stirring machine, adding the uniformly mixed pigmentfiller, sand grinding and stirring by a sand mold high-speed stirring machine, adding a crosslinking curing agent, continuing to sand grind and stir until fully and uniformly mixing, putting into a vacuum drying box, vacuuming and defoaming. The coating with excellent corrosion-resistant property and aging-resistant property is prepared by using the fluorocarbon resin of film-forming resin as a substrate, using the diphenylmethane diisocyanate as the crosslinking curing agent, and using the titanium dioxide coated with cerium oxide, the silicon dioxide nanometer fluid, sericite, coupling agent-modified aluminum oxide powder and silicon carbide ceramic particles as the fillers, and is used for coating the tent; the weather-resistant and aging-resistant properties of the tent are improved, and the service life is prolonged.
Owner:ANHUI YUTANG RAIN GEAR

Temporary steel protective coating and preparation method thereof

The invention discloses a temporary steel protective coating. The temporary steel protective coating comprises the following components in percentage by weight: 10-20% of tetraethoxysilane, 3-8% of silane monomer, 35-50% of water, 0.001-0.01% of acidic catalyst, 30-40% of mixed solvent and 1-5% of silane coupling agent. According to the invention, during coating synthesis, tetraethoxysilane, a silane monomer, a mixed solvent, water and an acidic catalyst are subjected to a sol-gel method, thus an organic-inorganic composite material is prepared through self-assembly and is of a three-dimensional mesh structure. A large number of hydroxyl groups are contained in the structure, thus the organic-inorganic composite material can be well combined with chemical bonds on the surface of steel. Thestructure contains one or more organic groups such as methyl capable of exerting hydrophobic effect, thus a base material is separated from water vapor and protection efficacy is achieved. Meanwhile,due to the organic-inorganic hybrid property of the material, the material is excellent in combination with silicates, the material can be used for temporary protection in an early stage of use by building steel and lasting protection after use by the building steel, and the performance of the material is superior to that of a method for spraying a layer of silane coupling agent diluent on the surface of the base material.
Owner:中昊北方涂料工业研究设计院有限公司

A semi-permanent silicone release agent and preparation method thereof

The invention relates to a semi-permanent organosilicone release agent and a preparation method thereof, and belongs to the technical field of manufacturing. Organic fluorine is added into synthetic organosilicone resin to serve as a functional monomer, fluorine-carbon side chains are enriched on the surface, fluorine atoms with the highest electronegativity surround the carbon chain to form a spiral structure, the hydrophobic effect is achieved, and meanwhile, the carbon chain is protected from being easily damaged by chemical media; through the chemical bonding effect between hydroxyl groupsand silicon atoms, the release agent which is high in surface activity, thermal stability and chemical inertness is prepared; along with volatilization of petroleum ether, macromolecular particles are gradually gathered and finally form the release agent; hydroxyl and the silicon atoms form covalent bonds and are combined with Si-O and Si-O-Si in organosilicone, thus, the surface becomes more compact, invasion of material molecules is effectively stoped through the compact release agent, and scale depositing is avoided; and the situation that the release agent is transferred to the surface ofa high molecular material product, and follow-up processing of the product is influenced is avoided, and the demolding efficiency is improved.
Owner:厦门翔矽新材料有限公司

Long-acting weather-resistant, chlorine-salt corrosion-resistant polyester powder coating and preparation method thereof

The invention belongs to the technical field of polyester powder coating preparation, and in particular relates to a long-acting weather-resistant, chlorine-salt corrosion-resistant polyester powder coating and a preparation method. The main raw materials of the powder coating of the present invention are: 530-560 parts of polyester resin, 45-60 parts of TGIC, 10-15 parts of trimesic acid triglycidyl ester, 120-180 parts of titanium dioxide, and 80-120 parts of barium sulfate , 8‑12 parts of brightening agent, 7‑10 parts of leveling agent. The polyester resin used in the powder coating of the present invention has a good linear structure, which ensures excellent fluidity; the powder coating uses a larger amount of trifunctional curing agent TGIC, and is matched with triglycidyl trimesic acid with a low melting point and excellent water resistance Esters are used as low-temperature curing agents to further improve the crosslinking density and water resistance of the coating film, and finally ensure long-term weather resistance and chloride salt corrosion resistance. The final powder coating product can be used for low-temperature curing at 160°C. The coating film prepared by it has good long-term weather resistance and chlorine salt corrosion resistance, and is especially suitable for infrastructure spraying on highways such as guardrails and bridges.
Owner:安徽鑫友高分子新材料科技有限公司

Formaldehyde self-absorption type foam glass insulation board

The invention discloses a formaldehyde self-absorption type foam glass insulation board, and belongs to the field of foam glass insulation boards. The formaldehyde self-absorption type foam glass insulation board is characterized in that purification balls are fixedly connected to the interiors of insulation holes inside a foam glass insulation board body, adsorption balls are fixedly connected to the interiors of the purification balls, the interiors of the adsorption balls are made of nano crystalline, activated carbon is evenly distributed on the outer surfaces of bamboo fibers communicating with the outer surfaces, the formaldehyde purification effect can be effectively achieved, and therefore indoor formaldehyde can be conveniently removed, staggered nets are arranged in a staggered mode, drying pieces are fixedly installed at the joints of the staggered nets, light balls with the interior made of silica gel are fixedly installed at the outer ends of the drying pieces, under the action of waterproof pieces, the hydrophobic effect can be effectively achieved, water erosion can be effectively prevented, sound absorption pieces are evenly distributed inside ventilation grooves, binding holes are evenly distributed inside the sound absorption pieces, and the sound insulation effect is greatly enhanced.
Owner:温州捷合郸科技有限公司
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