The application discloses a conductive
silver paste for photovoltaic cells and a preparation method thereof. The conductive
silver paste comprises the following raw materials in percentage: 65-85% of silver
powder and 1-3% of modified binder, and the rest is an organic carrier. In the printing process of the conductive
silver paste, the substances in the organic carrier contact the silver
powder, so that the silver chelate in the organic carrier is fully contacted, and then a stable conductive path can be formed during baking. The modified binder is a lead-free glass formed by taking
bismuth trioxide as a main
raw material to form a
bismuth-based glass. The addition of
calcium fluoride in the
raw material can reduce the water absorption of the
bismuth-based glass, thereby ensuring the stability of the resistivity. The addition of
titanium dioxide can exist in a quadruple coordination form, so that the Si-O-Si bond in the glass is changed into a Si-O-Ti bond, thereby forming an interconnected tetrahedral structure, increasing the
network connectivity of the glass, and simultaneously increasing the antireflection effect of the glass and the
utilization rate of
light energy.