The invention relates to the technical field of metallurgical polysilicon purification, in particular to a hydrometallurgical purification method. The purification method of the present invention is as follows: the silicon powder with a particle size of 100 to 200 meshes is subjected to magnetic separation by a magnetic separator for use, and is prepared by pre-cleaning, pickling with dilute hydrochloric acid, pickling with dilute hydrofluoric acid, pickling with aqua regia, and dilute hydrofluoric acid. Acid and hydrogen peroxide pickling process pickling, the solid-to-liquid ratio is 1:3, soak for 12-16 hours, stir for 15 minutes every hour during soaking, and then rinse with deionized water for many times until the pH value of the water For neutrality, centrifugal drying, drying, packaging. Using the purification method of the present invention, by optimizing the conditions such as silicon powder particles, acid concentration, soaking time and stirring, the total content of metal impurities in metallurgical polysilicon is reduced to 100ppmw in advance, and the effect of 4N purity metallurgical silicon can be obtained, and reach A simple, easy, low-cost method that can be mass-produced.