77results about How to "Achieve the effect of treating waste with waste" patented technology

The invention discloses a stabilizing agent for heavy metal contaminated soil and a preparation method and application thereof, and the stabilizing agent comprises the following raw materials: by weight, 20-60% of bone meal; 10-30% of biochar and 20-70% of calcined shell powder. The preparation method is as follows: (1) drying biomass in air and grinding into particles smaller than 60 meshes, cracking in a cracking furnace at 400-800 DEG C for 6-8 hours to obtain the biocar; calcining shell powder with the particle size below 20 meshes in a high temperature furnace at 800-1000 DEG C for 2 to 4 hours, naturally cooling to room temperature to obtain the calcined shell powder; and (2) proportionally mixing the biocar, the calcined shell powder and the bone meal evenly to obtain the stabilizing agent. The stabilizing agent compounding the three components in accordance with a specific proportion solves the problem of high cost, undurable stabilization effect and the like of stabilizing agents for the heavy metal contaminated soil in the prior art.

The invention discloses a treating method for efficiently catalyzing and oxidizing chlor-alkali industrial waste water. In the method, sodium hypochlorite in the chlor-alkali industrial waste water is decomposed mainly by adding a nickel oxide catalyst with an efficient surface; and simultaneously a small amount of other pollutants in the waste water is degraded. The treating method for efficiently catalyzing and oxidizing the chlor-alkali industrial waste water of the invention comprises the following step of: making sodium hypochlorite-containing alkaline waste water continuously flow through a catalytic oxidation reaction bed filled with a catalyst from the bottom to the top at an air speed of between 1.6 and 2.6 h<-1>.

The invention discloses a comprehensive utilization method of waste liquor in the production of basic cupric carbonate and relates to the field of treatment methods of industrial wastewater. The invention aims at providing a comprehensive utilization method of waste liquor in the production of basic cupric carbonate, and in particular relates to a method for reusing sodium bicarbonate in the waste liquor. The waste liquor in the production of the basic cupric carbonate is the waste liquor generated after the basic cupric carbonate is produced by a reaction between an acidic copper chloride solution or an acidic copper sulfate solution and a sodium carbonate solution. The comprehensive utilization method of the waste liquor in the production of the basic cupric carbonate mainly comprises the following steps: adding a little distilled water into a reaction kettle as a base solution; when the reaction temperature rises to 35-90 DEG C, starting a stirring device, and adding the waste liquor containing sulfate radicals or chlorine and the acidic copper solution into the reaction kettle for reaction, wherein the pH value during the addition of the solutions is controlled to be 3-6; and filtering, washing, drying and sieving reaction products to obtain the basic copper salt. The method disclosed by the invention is simple to operate, easy to control reaction conditions, and widely applicable to the recycling and reusing of the waste liquor in the production of basic cupric carbonate.

The invention discloses an ecological floating bed for oil-polluted water remediation. The main frame of the ecological floating bed comprises multiple assembled casing supports. Joints of the casing supports of the main frame are connected to matched PVC casing pipe joints and the joint openings are sealed by silica gel. A modified TiO2 photocatalytic material is carried by waste polyurethane foamed plastic recovered and recycled by an alcoholysis method so that the casing supports are prepared. The bottom of the main frame is wrapped by a non-woven fabric. Wrapped parts of the non-woven fabric and the main frame are tightened by a nylon rope. In each unit, a certain amount of a bottom filler layer and an upper filler layer are uniformly laid. Crops are planted in the upper filler layer. The paddy rice sprout on a floating bed can fully absorb redundant nitrogen and phosphor in water so that plant growth is promoted, the plant roots can promote floating bed bottom microbe growth so that floating bed water purification effects are improved, and the modified fly ash and the non-woven fabric have strong adsorptivity. The floating bed has three technology advantages and improves oil pollutant adsorption degradability and cleaning effects.

The invention discloses a sewage treatment filtercake by taking river sludge as a raw material and a manufacturing method, and the filtercake comprises the following components by mass percent: 80-100% of river sludge, 0-15% of flyash, 0-5% of red mud for steel production and 2-5% of swelling agent; the filtercake is obtained by adding 25-30% of water and 2-4% of pressing binder in terms of the mass of the raw material into the above components through the steps of mixing, pelleting, drying and high-temperature sintering successively. The filtercake in the invention has high main performance indexes such as film hanging property, water-gas distribution uniformity, bulk specific weight, strength, porosity, specific area and the like, and can be manufactured with a specified aperture and an apparent density conveniently by controlling the granularity and dosage of charcoal powder or mica powder, and has the advantages of wide sources of raw materials, simple production process, no pollution, low cost and high added value; the production equipment and technology in the current cement plants can be switched to producing ball-shaped filtercake of which the performance indexes for sewage treatment conform to the environmental protection requirements, thus achieving the effect of treating waste by waste.

A method for low-consumption co-treatment of flue gas desulfurization wastewater and ammonia-nitrogen wastewater comprises steps as follows: (1) flue gas desulfurization wastewater containing sulfateand ammonia-nitrogen wastewater are guided into a mixing tank to be mixed; (2) the pH and the temperature of mixed wastewater are adjusted in the mixing tank; (3) firstly, a biological reaction tank is inoculated with cultured activated sludge, the mixed wastewater is introduced from the mixing tank, microorganisms in the activated sludge take ammonia nitrogen as an electron donor in the biological reaction tank, sulfate is reduced to elemental sulfur, besides, ammonia nitrogen is oxidized into nitrogen, and synchronous removal of sulfur and nitrogen is realized. The problems that the water quality of the flue gas desulfurization wastewater hardly reaches the standard after treatment with conventional physical and chemical methods, the biodegradability is poor and biological treatment is difficult are solved, and co-treatment of two kinds of wastewater is realized.

The invention relates to a two-stage immersing, combusting and evaporating integrated device. The two-stage immersing, combusting and evaporating integrated device comprises an evaporation tank in a single form, wherein two evaporation chambers are formed in the evaporation tank; a treatment fluid can flow from a first evaporation chamber into a second evaporation chamber through a communicated area at the inner bottom of the tank, so that two-stage immersion, combustion and evaporation in one evaporation tank is achieved. The number of evaporators and various gas and liquid conveying pipelines is reduced, the energy is saved, and the floor area and the cost are reduced; moreover, the treatment process is simplified and operation management is facilitated.

The invention relates to a method for enhancing total mercury recovery rate of metallurgical fume by reducing bivalent mercury, which comprises steps as follows: (1) metallurgical fume discharged from a fume system is divided into two ways, the first way of fume directly enters an acid washing column, and the second way of fume is introduced into a sodium hydroxide washing column, so that SO2 in the fume reacts with NaOH to generate a solution of SO3<2-> or HSO3<-> or both; (2) the solution of SO3<2-> or HSO3<-> or both generated in the step (1) is introduced into the acid washing column as a reducer, wherein the introduction amount of the reducer is controlled, so that the mol ratio of the SO3<2-> or HSO3<-> concentration to the Hg<2+> concentration in the washing liquid in the acid washing column is kept within the range of 0.8-5000; and (3) the Hg<2+> in the acid washing column is directed reduced into HgO by the SO3<2-> or HSO3<-> in the reducer, and the HgO enters a subsequent mercury absorption column to be recycled through an exhaust port along with the fume. Compared with the prior art, the invention can greatly enhance the total mercury recovery rate of non-ferrous smelting fume, thereby achieving the goal of removing and recovering fume mercury more efficiently.

The invention relates to a device for removing heavy metals and polycyclic aromatic hydrocarbons in bottom sediment of river channels and a method thereof and belongs to the field of river-channel pollution treatment in environmental protection. The device comprises an electrolysis device, a biological fuel cell and a galvanometer, wherein the electrolysis device comprises a cathode area, a bottom-sediment area and an anode area; the negative electrode of the biological fuel cell is arranged at the outer side of a round drum, the positive electrode of the biological fuel cell is arranged at the inner side of the round drum, and a compost layer is arranged between the negative electrode and the positive electrode; a cathode rod is arranged in the cathode area, the top part of the cathode rod is electrically connected with the positive electrode, the negative electrode is connected with one end of the galvanometer, and the other end of the galvanometer is electrically connected with a positive rod; a substance exchange film is arranged between the anode area and the bottom-sediment area, a substance exchange film is also arranged between the bottom-sediment area and the cathode area, the top part of a cathode sampling area is provided with a cathode sampling port, the top part of a middle sampling area is provided with a middle sampling port, and the top part of an anode sampling area is provided with an anode sampling port. The device and the method have the advantages that the energy is saved and simultaneously the purpose of using wastes to treat wastes is achieved.

The invention relates to a method for treating arsenic in nonferrous smelting waste acid by jarosite slag collaborated by carbide slag, belonging to the technical field of heavy metal pollution control. In the invention, the jarosite slag and the carbide slag are uniformly mixed, and ball milling is carried out until the particle size of the mixture is not more than 0.56 mu m to obtain mixed slag powder; the mixed slag powder and potassium permanganate are added into the nonferrous smelting waste acid to mix evenly, air is continuously introduced under the stirring condition, and oxidation dearsenization reaction is performed for 24 to 36 hours to obtain a solid-liquid mixture; the solid-liquid mixture is subjected to solid-liquid separation to obtain an arsenic-containing solid matter and filtrate, the arsenic-containing solid matter is stacked and treated, and the filtrate enters the next step of deep arsenic removal treatment. In the invention, the jarosite slag and the carbide slag are adopted to remove arsenic in the nonferrous smelting waste acid, so that the arsenic removal effect is excellent, the process operation is simple, the production cost is low, the amount of sludge generated after arsenic removal is small, and the problem of large sludge stockpiling is relieved.

The invention provides a collaborative curing treatment method for electrolytic manganese slag and red mud. According to the method, quick lime, red mud and red mud leachate are adopted as raw materials to effectively cure and stabilize the electrolytic manganese slag, soluble alkali in the red mud exists in water in the form of OH-, reacts with manganese ions to generate precipitate, and reacts with ammonia nitrogen (NH3-N) to generate ammonia gas, and thus pollutants in the electrolytic manganese slag can be effectively removed. On one hand, the red mud leachate plays a role of a solvent, onthe other hand, alkaline substances in the red mud leachate play a role of reactants, thus the reaction rate is increased, and the treatment cost is reduced. The red mud and the red mud leachate areused, so that the use amount of the quick lime is effectively reduced, and the treatment cost is further reduced. According to the method, a step-by-step reaction means is adopted, the reaction efficiency is effectively improved, and the curing rate of manganese ions in the electrolytic manganese slag reaches 93.7% or above.

A method for preparing organic hydrotalcite includes the steps of firstly, filtering washing wastewater to remove solid impurities so as to obtain washing wastewater without solid impurities; and secondly, adding hydrotalcite into the washing wastewater, mixing, performing precipitation separation, drying, and grinding to obtain anionic surfactant modified hydrotalcite. Due to the fact that surfactant used during washing is most anionic surfactant, the anionic surfactant in the washing wastewater is used as modifier to synthesize the organic hydrotalcite, the organic hydrotalcite is prepared while the anionic surfactant in the washing wastewater can be absorbed effectively, and waste recycling is achieved. The prepared organic hydrotalcite is low in price, wastewater treating effect is evident, wastes are treated with wastes, and high economical and practical values are achieved.

The invention discloses a method for preparing an environment-friendly dye adsorbent from shrimp and crab shells. Waste shrimp and crab shells are used as raw materials, cleaned up with water, dried in the air, crushed, soaked in hydrochloric acid, taken out, washed with water to be neutral and dried, and the dye adsorbent is obtained. The characteristic that chitin in the shrimp and crab shells and porous structures formed in the process of removal of calcium carbonate with hydrochloric acid have a good adsorption effect on dye substances is used, an efficient adsorption material is prepared from the waste shrimp and crab shells through simple treatment and mixed with dye wastewater, the removal rate of dye molecules can reach 97% or above, solid-liquid separation can be realized, and efficient, quick and low-cost treatment of the dye wastewater is facilitated.

The invention discloses a deep dehydration conditioner for sewage sludge. The deep dehydration conditioner comprises, by mass, 30 to 70% of fly ash, 5 to 20% of active carbon powder, 10 to 30% of bentonite, 5 to 20% of quicklime powder and 4 to 10% of polyaluminum ferric chloride. The invention also comprises a preparation method for the deep dehydration conditioner. The preparation method comprises the following steps: mixing weighed fly ash, active carbon powder, bentonite and quicklime powder together to obtain a mixture; then putting weighed polyaluminum ferric chloride into a container, adding a same amount of water and carrying out blending to prepare mixed liquor; and finally, adding the mixture and the mixed liquor into a mixer and carrying out uniform stirring. The preparation method provided by the invention has the advantages of simple components, easiness, wide sources of raw materials and low cost; and most important, the preparation method is free of secondary pollution and enables waste water to be discharged after reaching the standard.

The invention relates to a method for treating acidic mine wastewater containing heavy metal ions, which comprises the following steps: crushing and grinding magnetite to obtain magnetite particles; digesting the magnetite particles with sulfuric acid to obtain hydrogen sulfide gas; and introducing the hydrogen sulfide into the acidic mine wastewater containing heavy metal ions, and carrying out solid-liquid separation to obtain sulfide precipitates and wastewater without heavy metal ions. According to the method, pyrrhotite which is one of acidic mine wastewater sources serves as a vulcanizing agent source to treat heavy metal ions in the wastewater, and the effect of treating waste with waste is achieved.

The invention provides a red mud-containing briquette and a preparation method thereof. The red mud-containing briquette comprises, by weight, 60-70 parts of coal, 5-9 parts of red mud, 1-5 parts of adispersant and 2-5 parts of gelatinized starch, the dispersant is a naphthalene dispersant, and the coal is semi-coke or anthracite. The energy-saving, emission-reducing and environmentally-friendlybriquette is prepared by using pulverized coal as a main body and the red mud as a sulfur fixing agent and adding other substances such as a binding agent and the like, so the problem of red mud utilization can be solved, the problem of environmental pollution caused by the red mud and fire coal can also be solved, and the effect of treating wastes with wastes is achieved.

The invention provides a biological charcoal material for removing iodate in water and a preparation method thereof. The biological charcoal material comprises the following steps: taking waste plantstraws as raw materials and preparing the raw materials in powder; carrying out carbonization reaction at certain temperature; then carrying out post-treatment on carbonized powder, so as to obtain the biological charcoal material for removing iodate, wherein the removing efficiency of the biological charcoal material reaches 90 percent or more; the biological charcoal material has the advantagesof high efficiency of removing iodate in the water, low cost, wide material source, environment friendliness, no secondary pollution and simple preparation method; the reclamation of wastes is realized, and the biological charcoal material has social benefits and economic benefits; the invention further provides carbonization equipment for preparing the biological charcoal material; the equipmentis simple, convenient to use and low in cost, and is easy to popularize.

The invention discloses a high-concentration landfill leachate membrane concentrated solution treatment process and application thereof, and belongs to the field of wastewater treatment. The high-concentration landfill leachate membrane concentrated solution treatment process is characterized by comprising the following steps: pretreating the high-concentration landfill leachate membrane concentrated solution with pretreatment salt and a composite material, wherein the pretreatment salt is selected from ferric sodium oxalate or sodium diacetate; and the composite material is selected from the group consisting of light burning powder, sodium lignin sulfonate, fly ash, and slag. According to the process, efficient pretreatment is carried out before evaporation treatment, scaling of the evaporator is greatly relieved, and energy consumption of the evaporator is reduced; and in the curing process, active components in the filter residues and the evaporation mother liquor are utilized, a cured body meeting the landfill requirement is formed through activation, and the cost is reduced.

The invention discloses a super-high specific surface area carbon-based functional material and a preparation method and application thereof. The preparation method of the super-high specific surfacearea carbon-based functional material through coupling catalytic pyrolysis of sludge organic matter includes the following steps that firstly centrifugal filtration of sludge is conducted after alkalitreatment, supernatant is retained, the supernatant is dried and ground to powder, and then the powder is calcined at 700-900 DEG C to obtain a carbon-based adsorbent material. According to the super-high specific surface area carbon-based functional material and the preparation method and application thereof, coupling of sludge organic matter recovery and the super-high specific surface area carbon-based functional material is realized;, a sewage treatment method adopts the super-high specific surface area carbon-based functional material prepared by the preparation method to treat sewage; and the preparation method is not directly activated, compared with a general preparation method, the preparation method is simpler in step and lower in cost, we chose KOH to release the sludge organicmatter and extract SEPS during alkali treatment, at the same time, the residual KOH plays a catalytic role to the material during re-pyrolysis, and the effect of 'killing two birds with one stone' isachieved.