The invention discloses a nano-silicon dioxide modified environment-friendly waterborne paint remover and a preparation method thereof. The nano-silicon dioxide modified environment-friendly waterborne paint remover is prepared from the following raw materials in parts by weight: 1.2-1.4 parts of nanometer montmorillonite, 1.5-2 parts of a penetrating agent T, 42-46 parts of benzyl alcohol, 11-12 parts of acetone, 10-11 parts of hydrogen peroxide, 3-3.5 parts of methylcellulose, 2-2.4 parts of urotropine, 1.3-1.5 parts of dodecylbenzenesulfonic acid, 1.6-1.9 parts of microporous starch, 2.2-2.5 parts of microcrystalline wax, 0.8-1 part of tetrabutyl titanate, a proper amount of ammonia water, a proper amount of ethyl alcohol, 50-55 parts of water, 1.2-1.5 parts of boronic acid, 0.4-0.6 part of sodium dichloro isocyanurate and 0.9-1.3 parts of nano-silicon dioxide. With using of the boronic acid and the sodium dichloro isocyanurate, the nano-silicon dioxide modified environment-friendly waterborne paint remover has the bacterium resistance and the corrosion resistance, is good in permeability and promotes peeling of a paint film; and by using the nano-silicon dioxide, peeling is formed at an interface, the peeling speed is increased, secondary pollution is prevented, and metal corrosion is retarded.