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92results about How to "Improve flicker performance" patented technology

Bismuth silicate-germanate mixed crystal and preparation method thereof

The invention discloses a bismuth silicate-germanate mixed crystal and a preparation method thereof, belonging to the single crystal field. The molecular formula of the bismuth silicate-germanate mixed crystal is Bi4Si3-xGexO12. The preparation method comprises the following steps: using high-purity Bi2O3, SiO2 and GeO2 as raw materials to fully grind, presinter and obtain a polycrystalline material; and placing seed crystal at the bottom of a crucible in advance, placing the synthesized polycrystalline material in the crucible, and transferring the crucible to a crystal growing furnace while controlling the temperature to 1050-1150 DEG C, the temperature gradient of the solid-liquid interface to 20-50 DEG C/cm and the growth velocity to 0.2-0.5mm/h. The raw material components of the bismuth silicate-germanate mixed crystal provided by the invention are adjustable and are distributed evenly; the mixed crystal has the scintillation property of bismuth silicate and the scintillation property of bismuth germanate, the mixed crystal has large size; the preparation method adopts stable temperature field and simple processing equipment; and multicrystal can grow at the same time, the growth efficiency of the mixed crystal is high, the production cost is low and the mixed crystal is suitable for industrial production.
Owner:SHANGHAI INST OF TECH

Preparation method of lead tungstate powder with high scintillation property

The invention discloses a preparation method of a lead tungstate powder with high scintillation property, comprising the following specific steps of: a) dropwise adding a water soluble lead salt solution into a water soluble tungstate solution with a pH value being not less than 7 at the uniform velocity so that the coprecipitation chemical reaction is conducted at 30-80 DEG C; b) filtering, washing and drying the obtained lead tungstate precipitation; and c) carrying out thermal treatment on the obtained lead tungstate crystal grains. By the invention, the luminescence peak of the lead tungstate powder body is within the blue light wave band of 450-500nm and belongs to fast luminescence component; the luminescence strength is high and is remarkably improved by about 15 times in comparison with the luminescence strength of the power obtained by grinding lead tungstate crystal grains which grow by a descending method, can reach the luminescence level of the power obtained by grinding of bismuth germanate crystal grains which grow by a descending method and has excellent scintillation property; in addition, the invention has the advantages of simple operation, short reaction time, low requirements on experimental equipment, high controllability and the like, and is suitable for large-scale production.
Owner:SHANGHAI INST OF CERAMIC CHEM & TECH CHINESE ACAD OF SCI

Method for converting visually yellow cerium doped lutetium yttrium oxyorthosilicate crystals into colorless cerium doped lutetium yttrium oxyorthosilicate crystals in neutral atmosphere

The invention discloses a method for converting visually yellow cerium doped lutetium yttrium oxyorthosilicate crystals into colorless cerium doped lutetium yttrium oxyorthosilicate crystals in neutral atmosphere. The visually yellow cerium doped lutetium yttrium oxyorthosilicate crystals are heated in neutral atmosphere for a certain period of time to ensure that oxygen is diffused from the cerium doped lutetium yttrium oxyorthosilicate crystals, so Ce<4+> is changed into Ce<3+>, and the crystals become colorless. According to the method, the crystals are treated at high temperature in neutral atmosphere, so residual oxygen is removed from the crystals, and the visually yellow cerium doped lutetium yttrium oxyorthosilicate crystals are converted into colorless yellow cerium doped lutetium yttrium oxyorthosilicate crystals; therefore, transmissivity of the 420-nm part of the crystals is improved. The scintillation property of the crystals can be improved obviously. By the method, primary crystals are subjected to reduction heat treatment, so the properties of the crystals can be improved, and the properties of the crystal products which are not appropriately oxidized can be recovered. The properties of the crystals are greatly improved, and the utilization rate of the crystals is further improved.
Owner:CHINA ELECTRONICS TECH GRP NO 26 RES INST

Silicon film coated aluminum pigment as well as preparation method and application thereof

The invention discloses silicon film coated aluminum pigment as well as a preparation method and application thereof. The silicon film coated aluminum pigment is aluminum pigment coated with a Si-O-Si film having N layers of network structures, every two adjacent network structures are connected with each other by means of a coupling agent, and N is more than or equal to 3. The silicon film coated aluminum pigment can be used only when being dry mixed with a powder coating, so that the coating rate is increased; a binding process is not needed, so that the problems of caking scrap and poor bonding effects which are caused by difficult control of the process can be avoided, the aluminum pigment is not damaged, and the metallic luster effect is guaranteed; furthermore, after the aluminum pigment is sprayed, the twinkle effect of a paint film is improved; in addition, the paint film is high in surface hydrophobicity, so that the acid and alkali resistance and weather resistance of the paint film are greatly improved. The coupling agent comprises long chains of polycarbon and functional groups; in a reaction process, the long-chain carbon has a steric hindrance effect and the hydrolyzed functional groups contain charges of the same properties, so that the particles of the aluminum pigment do not agglomerate by means of adsorption, and the phenomenon of caking scrap is avoided.
Owner:长沙族兴新材料股份有限公司

Lanthanum, dysprosium and cerium co-doped lutetium-yttrium orthosilicate scintillating material and crystal growth method

The invention discloses a lanthanum, dysprosium and cerium co-doped lutetium-yttrium orthosilicate scintillating material and a crystal growth method of the lanthanum, dysprosium and cerium co-doped lutetium-yttrium orthosilicate scintillating material. The chemical formula of the scintillating crystal is La2pDy2qCe2m(Lu(1-n)Yn)2(1-p-q-m)SiO5, wherein p is more than 0 and less than or equal to 0.02, q is more than 0 and less than or equal to 0.02, m is more than 0 and less than or equal to 0.03, n is more than or equal to 0.01 and less than or equal to 0.1, p, q and m meet the condition that pplus q plus m is more than 0 and less than or equal to 0.05; the growth method is as follows: S1: synthesizing a poly-crystal material block at the solid phase at the high temperature; S2: compressing and fusing the poly-crystal at the atmosphere of the protective gas; and S3: growing at equal diameter, and using a PID algorithm to automatically cool and anneal. The Dy and the La are doped in LYSO, the vacancy for growing the crystal is increased, the excessive oxidation of the crystal is avoided, the scintillating performance of the crystal is guaranteed, the luminescence spectrum of the crystal is expanded, and the case substitution rates of the ions Lu and Y are increased by means of cold isostaitc pressing, the automatic temperature-controlled growth is implemented through the PID algorithm, and the consistency of the crystals growing in batches is guaranteed.
Owner:安徽晶宸科技有限公司

Glass containing rare earth ion doped lutetium iodide micro-crystals and preparation method of glass film

The invention discloses glass containing rare earth ion doped lutetium iodide micro-crystals and a preparation method of a glass film. The glass is characterized by being prepared from the following raw materials by mole percent: 73-75mol% of ethyl orthosilicate, 5-16mol% of niobium ethoxide, 10-15mol% of lutetium iodide and 1-5mol% of rare earth iodide, wherein rare earth iodide is one of cerium iodide, europium iodide and terbium iodide. The glass has the advantages as follows: a sol-gel method is a low-temperature wet-chemical method glass preparation technology, and the glass is obtained through hydrolysis and polymerization chemical reaction of precursor raw materials, so that the glass can be prepared into a film material at a certain liquid viscosity and iodide raw materials are prevented from being decomposed and volatilized through low-temperature synthesis conditions; the glass prepared through the sol-gel method can generate a certain micropores in the material due to volatilization and decomposition of the solvent, and the micropores provide the good environment for generation of nano iodide micro-crystals, so that defects that crystallization particles are nonuniform and glass devitrification occurs due to incomplete uniformity of glass smelting chemical constituents and crystallization processing temperature can be overcome to a certain extent.
Owner:NINGBO UNIV
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