172results about How to "No risk of secondary pollution" patented technology

The invention discloses a sodium alginate-MOF (metal organic framework) composite spherule as well as a preparation method and an application thereof, belongs to the field of material synthesis and overcomes the defect that a conventional MOF material has small grain size and poor acid resistance and is difficult to be separated from water. The co-precipitation technology is adopted, a sodium alginate-MOF mixed liquid is dropwise added to a precipitant solution containing calcium chloride, water and ethyl alcohol, a non-crosslinked composite spherule is obtained, then the composite spherule is added to a glutaraldehyde solution for cross-linking of a sodium alginate framework, the sodium alginate-MOF composite spherule is obtained, the grain size of the spherule is about 1 mm, and the composite spherule has the characteristics of high acid resistance, high separability from water, high water pollutant adsorption capacity, high mechanical strength, long service life, environment-friendliness and the like.

The invention relates to a hydroxyapatite modified eggshell adsorbent material as well as a preparation method and an application thereof. The invention also provides a method for removing the hydroxyapatite modified eggshell adsorbent material and recycling phosphate from wastewater. The invention has the advantages that: the speed of removing phosphate from the wastewater of the hydroxyapatite modified eggshell serving as an adsorbent is obviously higher than the speed of removing phosphate from the wastewater by using eggshell only; through the phosphorous removing process taking the hydroxyapatite modified eggshell as the adsorbent, the hydraulic retention time of a reactor is shorter, and the construction and operation cost is lower; the eggshell and hydroxyapatite do not release harmful ions in the phosphorous removing process, thereby avoiding the risk of secondary pollution on the water and protecting the environment.

The invention discloses an organic polymer heavy metal chelating flocculant as well as a preparation method and an application thereof. The organic polymer heavy metal chelating flocculant is prepared from the following raw materials in parts by weight: 100 parts of carboxymethyl starch, 5-20 parts of a crosslinking agent, 0.05-0.5 part of an initiator, 5-20 parts of acrylamide and 28-60 parts of carbon disulfide, wherein the crosslinking agent is adipic acid, phosphorus oxychloride or sodium trimetaphosphate. The organic polymer heavy metal chelating flocculant has the efficacies of both excellent heavy metal chelating precipitation and flocculation, has the advantages of rapidness in reaction speed, ideal effect of removing heavy metal ions, high treatment efficiency and the like, is low in dosage and cost and is capable of economically and efficiently treating sewage containing the heavy metal ions.

The invention relates to a method for promoting hydrolysis of sludge by using calcium peroxide and increasing effect of anaerobic digestion of sludge, which comprises the following steps: 1)a calcium peroxide processing unit: placing the calcium peroxide in the sludge, wherein the mass ratio of calcium peroxide to sludge is 0.01: 1-0.6:1, reacting for 1-24 hours, and hydrolyzing the sludge; and 2)an anaerobic digestion unit: after processing the calcium peroxide, performing anaerobic digestion on sludge under the effect of anaerobe and amphimicrobe in an anaerobic digestion tank, rapidly using an organic compound in the sludge, conversing to methane, carbon dioxide and water, increasing the sludge biogas output and then realizing the quantitative reduction. Compared with the prior art, the method for promoting hydrolysis of sludge by using calcium peroxide and increasing effect of anaerobic digestion of sludge has the advantages of low cost, shortened digestion time and easy enforcement.

The invention relates to a preparation method of an adsorption-visible light catalysis material for removing heavy metals and persistent organic pollutants in municipal sludge, particularly to a biomass activated carbon supported P-TiO2 material with adsorption and visible light catalysis composite functions. Agricultural waste biomass, phosphoric acid and TiO2 are taken as main raw materials, under the airtight high-temperature pyrolysis condition, the phosphoric acid can be used as a biomass carbon activator and a TiO2 photo-catalysis dopant simultaneously, P-TiO2 can produce electrons-hole pairs under sunlight, when organic matters or metal ions are adsorbed on the surface of the P-TiO2, the electrons or holes can be obtained respectively, and corresponding redox reactions happen, so that the pollutants are removed. Meanwhile, the heavy metal ions in the sludge can be adsorbed and fixed by biomass activated carbon, so that the mobility and the bio-availability of the heavy metal ions are effectively reduced. The adsorption-visible light catalysis composite functional material prepared with the method has the characteristics of low price, high efficiency, wide application range, convenience in use and the like, and the risk of secondary pollution is avoided.

The invention discloses a magnetic covalent organic frame material and a preparation method and an application thereof. The magnetic covalent organic frame material takes piperazine and cyanuric chloride as the construction units to form a covalent organic frame, and then the covalent organic frame is loaded on the organic frame material formed on the surface of magnetic ferriferrous oxide. The organic frame material better solves the problems of small particle size, poor stability and difficult separating from a water body of the current covalent organic frame materials. The method employs a solvothermal method, and akes the magnetic ferriferrous oxide nano particles as a carrier, the material is immersed into a piperazine-containing ligand solution, a cyanuric chloride ligand solution is dropped, and a hydro-thermal reaction is carried out under constant temperature condition to obtain the magnetic covalent organic frame material. The material has the characteristics of strong separating capability in water, large adsorption quantity on pollutants in the water body, high mechanical strength and environmental friendliness.

The invention discloses an in-situ repair method and system for heavy meal cadmium and polycyclic aromatic hydrocarbon polluted farmland soil. The method comprises the following steps: (1) spreading a mixture of carbon coated porous foamed iron subparticles, a peroxide and sodium phytate into polluted soil; (2) spraying a hydrogen peroxide solution into the polluted soil, concentrating and removing pollutants such as polycyclic aromatic hydrocarbon and heavy meal cadmium in the soil; and then recycling carbon coated porous foamed iron subparticles. The system comprises a material spreading device and a recycling device, the material spreading device comprises a material spreading moving rack, and the material spreading moving rack is provided with a mixture hopper, a hydrogen peroxide solution storage tank and a hydrogen peroxide solution spray head; the recycling device comprises a recycling moving rack, and the recycling moving rack is provided with a magnet recycling device and a foamed iron recycling tank. The method is simple in process, low in cost and high in continuity, the damage on soil microorganisms and organic matters is avoided, and the risk of secondary pollution does not exist.

The invention discloses a heavy metal polluted soil solidification and repairing composite compound and a solidification and repairing method. The composite compound comprises the following componentsin percentage by mass: 20-40% of quicklime and 60-80% of an iron-based biochar modified phosphate mineral, wherein the iron-based biochar modified phosphate mineral is obtained by uniformly mixing and drying an iron salt and biomass, further mixing the mixture with a phosphate mineral uniformly and performing co-pyrolysis. The method for solidifying and repairing heavy metal polluted oil by usingthe composite compound comprises the following steps: firstly, uniformly mixing the iron-based biochar modified phosphorate mineral with quicklime so as to obtain the heavy metal polluted soil solidification and repairing composite compound; applying the composite compound into heavy metal polluted soil, adding water, and performing uniform stirring; and performing maintenance of the best standards, so as to complete solidification repairing on the heavy metal polluted soil. By adopting the heavy metal polluted soil solidification and repairing composite compound, secondary dissolution of heavy metals can be greatly avoided, and the long-term stability of solidification of the heavy metal polluted soil can be greatly enhanced.

The invention belongs to the field of phosphate-containing sewage treatment, and discloses a method for adsorbing phosphate in sewage by using eggshells. The method comprises the following steps that: first, cleaned and shell-membranes-removed eggshells are dried at a temperature of 102 to 105 DEG C, and are grinded; the grinded eggshells are screened with a sieve of 300 meshes, such that eggshell power with a gain size of less than 300 meshes is obtained; 0.2 to 5g of eggshell powder is added to 50 to 1000mL of sewage with a phosphate concentration of 0.2 to 20mg/L and a pH value of 7 to 10; the resulting mixture is stirred for 8 to 12 hours under a temperature of 10 to 40 DEG C, and with a rotary speed of 50 to 200 rpm, such that the adsorption process is finished. According to the method, the phosphate adsorption is realized with the phosphate absorbability of eggshells. Compared with current common phosphate treatment methods, the method provided by the present invention has characteristics of no secondary pollution, abundant raw material source, low operation cost, and stable phosphate removing effect. The method accords with an environmental protective idea of: restricting waste with waste, and brings in good social benefit and environmental benefit.

The invention provides rhizobium Scot1305 and a symbiotic system of rhizobium Scot1305 and plants is established. Due to nitrogen fixation function, siderophore secretion function and soluble phosphorus activity of the rhizobium strain and protection effect of the rhizobium strain on key enzyme of plant tocopherol synthesis, enhancement effect of the strain on phytoremediation of Co contaminated soil is realized. The strain can coexist with plants in Co contaminated soil, and can promote the extraction and enrichment of heavy metals Co in the aerial parts of plants, and finally achieve the purpose that the content of Co in soil meets the environmental safety standard.

The invention relates to a compound repair agent for heavy metal polluted soil which is characterized by being prepared from the following raw materials in percent by weight: 40-55% of charcoal, 15-35% of bone powder and 15-35% of coal ash. By taking agricultural or industrial solid wastes which are wide in source and easy to obtain as a raw material, the compound repair agent is simple in process, sufficient in raw material, low in cost and obvious in application effect, reduces the heavy metal mobility and bioavailability of soil, and can solve the problem of sustainable utilization of heavymetal pollution in farmlands and fields of industrial and mineral industry. The application method is simple, the using process is labor-saving, the physical and chemical properties of soil can be also improved effectively, the fertilizer retaining and water retaining ability of soil is improved, and the compound repair agent is easy to popularize and apply.

The invention provides a method for restoring heavy metal pollution soil. The method comprises the following steps of: firstly, breeding algae on soil, subsequently absorbing a large quantity of heavy metal ions by the algae in the growing process by the characteristic of absorbing the heavy metal ions; and cultivating angleworms when the algae grow lushly, wherein the angleworms like to eat organic substances in the soil, the algae are the first choice of food for the angleworms, and the algae with the heavy metal ions are swallowed by the angleworms, so that the heavy metal ions are absorbed through digestive systems of the angleworms along with the algae organic substances, and therefore, heavy metal can be enriched in the angleworm bodies; and finally, removing the heavy metal out form a soil system through a manner of taking out the angleworms.

The invention discloses an automatic elevating apparatus and method of an aeration tube of a floating aerator, and belongs to the technical fields of water restoration and water treatment. The apparatus comprises a slide rail fixed on a floating aerator floating body, slidable mechanical arms are arranged at the top feet of the slide rail, the bottom foot of every mechanical arm is provided with a slidable aeration branch tube, a rope of a pulley group mechanism pulls a large fixed pulley fixed above the mechanical arm slide rail, the large fixed pulley coaxially drives a small fixed pulley having a certain ratio relative to the large fixed pulley to rotate, and the small fixed pulley controls the top feet of the X-shaped mechanical arms to move apart or close up, so a case that a rising or descending distance of the aeration branch tubes driven by the X-shaped mechanical arms is almost same to a distance of a weight moving closer to the water level is realized, and a gas conveying flexible tube is synchronously retracted or released by a gas conveying tube telescoping mechanism. The apparatus and the method allow the aeration tubes to be positioned in specific positions above the riverbed, reduce the disturbance to riverbed sediments and improve the oxygen charging efficiency.

The invention discloses a hydroxyapatite-loaded nano zero-valent iron composite material as well as a preparation method and an application method thereof. The preparation method comprises the following steps: by taking hydroxyapatite subjected to hydrothermal synthesis as a carrier, adsorbing Fe<2+> for several hours, reducing ferrous iron in an inert gas atmosphere to obtain nano zero-valent iron, washing, centrifuging, and freeze-drying to obtain the hydroxyapatite-loaded nano zero-valent iron composite material. According to the method, the removal effect on hexavalent chromium is the best, high-toxicity hexavalent chromium is reduced into low-toxicity hexavalent chromium, the removal rate can reach 100%, divalent heavy metal cations such as copper, cobalt and nickel in the wastewatercan be efficiently and rapidly removed at the same time, and the removal rate is also up to about 98%. The method can be applied to removal and purification of heavy metal ions in wastewater, and canalso be used for remediation of soil polluted by various heavy metals.

The invention belongs to the field of water treatment, and in particular relates to a method for promoting generation of hydroxyl radicals from ozone. The method comprises the following steps: feeding ozone and thiosulfate into water with pollutants, and rapidly mixing to react, thereby prompting generation of the hydroxyl radicals from the ozone. The method provided by the invention is very fast in reaction speed, can lower the cost when being used in water treatment, can promote rapid reaction in acid, neutral and alkali environments without adjusting the pH value of a water body, is free of risk of secondary pollution and is beneficial to industrial application.

The invention relates to a sludge drying process and equipment. The process is: pretreat the sludge with high moisture content until the moisture content is lower than the set value, keep the temperature of the sludge constant, and input it into the sludge drying equipment, in which the sludge is continuously discharged to the It is pushed by the mouth, and the sludge is heated to above 120°C, accompanied by continuous stirring and crushing, and at the same time, the water vapor volatilized from the sludge is continuously drawn out by the air-inducing equipment until the sludge with the required moisture content is produced. The sludge is discharged from the drying equipment. The sludge drying equipment is produced for the improvement of the traditional hollow paddle dryer. The process of the present invention is simple and easy to operate, runs smoothly, and can make the degree of sludge drying more controllable, the sludge treatment capacity is larger, and there is no risk of secondary pollution; the equipment of the present invention has simple structure, stable operating performance, and high efficiency. High, and can achieve the goal of energy saving and emission reduction, it is expected to be widely used in the field of environmental protection and in chemical, pharmaceutical, food and other industries.

The invention discloses a method for catalytically degrading phthalate pollutant by directly utilizing sunlight, and belongs to the technical field of environmental engineering. The method comprises the following steps: preparing supernate by using low-price easily-available urea as a raw material through stepwise roasting, ultrasonic peeling and centrifuging; drying to obtain nano-carbon nitride having grain size mainly distributed in a range of 30-50nm; and modifying with a coupling agent, dispersing in a methyl alcohol solution, uniformly applying and immobilizing to the inner surface of a pre-treated glass container. The treated glass container serving as a catalyst can be used for remarkably accelerating the degrading process of phthalate under sunlight radiation, and the removal rate can be 95-100 percent. The method is applicable to actual operation of a pollutant treatment field, has high efficiency and low cost, is beneficial innovation of introducing sunlight catalysis to the environmental engineering; the catalyst is a non-metallic ingredient, does not have secondary pollution risk, has uniform and firm immobilization, is convenient for reclaiming and recycling after reaction, and has relatively good commercial value and application prospect.

The invention discloses a preparation method and application of modified nano zero-valent iron. The preparation method comprises the following steps of dissolving ferrous sulfate salt in sophorolipidsolution, dropwise adding sodium borohydride solution into nitrogen atmosphere to carry out liquid-phase reduction to obtain the modified nano zero-valent iron. The modified nano zero-valent iron prepared has the advantages of being good in stability, good in dispersibility, strong in reaction activity, ecological friendly and the like, and has a good immobilization effect on Cd, Cr and Zn in heavy metal polluted sediment, and the content of Cd, Cr and Zn residues in the treated sediment is increased by 22.034%, 16.493% and 18.436% correspondingly, so that the modified nano zero-valent iron has excellent application value and wide application prospect for repairing heavy metal polluted sediment.