The invention discloses an oil-resistant and wear-resistant modified PVC resin nanometer environment-friendly construction materials and a preparation method. The construction material comprises organic silicon resin, organic solvent, vitrified micro-beads, titanium dioxide, quartz sand, silicon carbide micropowder, nanometer cerium oxide, ethanedioic polyester, light calcium carbonate, water-retaining resin polyvinyl alcohol, dispersant, thickener, brightener, zinc sulfide, foamed aluminum, hydroxy propyl methyl cellulose, nanosilicone dioxide, adhesive, cobalt naphthenate, molybdenum, nickel, propylene glycol, and chromium. The construction material is used for exterior walls of buildings specially, all performances of the exterior walls are effectively improved, nitrile rubber modifled bakelite, is mixed with the raw material and cured after being heated, melted resin turns into unmelted body structure rapidly from the linear structure. Mechanical performance is improved, and performance of high temperature resistance and low expansion is achieved. With pitch-based carbon fibers, mechanical performance of the material is enhanced, harmful gas and dust in the tail gas can be greatly absorbed and removed.