374 results about "Acid preparations" patented technology

The invention discloses a molecular sieve based catalyst, a preparation method and an application thereof in crylic acid preparation by lactic acid dehydration. The method comprises the following steps: processing the ZSM-5 molecular sieve in aqueous alkali, or adopting an impregnation method to support phosphate, drying, roasting and finally obtaining the modified molecular sieve based catalyst. The catalyst realizes the reaction of crylic acid preparation by lactic acid dehydration in low temperature and has the advantages of high lactic acid conversion rate and crylic acid selectivity, and long-life of catalyst, the conversion rate of lactic acid dehydration reaction is 100%, and crylic acid selectivity can reach as high as 83.9%, thus having good industrial application prospect.

The invention relates to a method for undergoing a chlorobenzene nitration reaction by using a micro-channel reactor, belonging to the technical field of application of organic synthesis. In the method, nitric acid, sulfuric acid, water and chlorobenzene are taken as initial reaction raw materials, and processes such as mixed acid preparation, mixed acid and chlorobenzene preheating, mixed acid and chlorobenzene reacting and the like are completed in a micro-channel reactor system. In the reaction, nitro-sulfuric mixed acid is taken as a nitrating agent, the effective concentration of sulfuric acid in the mixed acid is 50-90 percent, the molar ratio of the nitric acid to the sulfuric acid in the mixed acid is 1:1-1:10, the molar ratio of the chlorobenzene to the nitric acid is 1:1.0-1:2.0, the reaction temperature is 50-100 DEG C, and the reaction time is 30-120 seconds. The chlorobenzene transformation ratio is up to 97 percent, the selectivity of nitrochlorobenzene serving as a product is over 96.5 percent, and the ratio of ortho-para nitrochlorobenzene is over 0.6. A strengthened mixed micro-channel reactor adopted in the invention is particularly suitable for undergoing a continuous nitration reaction, and has the characteristics of stable temperature control and safe process.

The invention discloses a method for extracting soluble dietary fiber, which comprises the following steps of: A, processing dietary fiber raw materials by adopting a carbon dioxide blasting, extruding and puffing method to obtain modified dietary fiber raw materials; B, carrying out microbial fermentation processing on the modified dietary fiber raw materials obtained in the step A by using mixed microbial bacterial solution to obtain a fermented mixture; and C, carrying out extraction filtration on the fermented mixture, drying filter residues obtained through extraction filtration after washing the filter residues to be neutral, thereby obtaining the soluble dietary fiber. Compared with the current acid preparation process, alkaline preparation process or microbial extraction process, by adopting the dietary fiber modification method, the content of the soluble dietary fiber in the product is up to 28.69+/-0.9%.

The invention discloses a high-efficiency desulfurized active coke analysis tower and an analysis method. The analysis tower comprises a material feeding section, a preheating section, a first buffering section, an analysis section, a second buffering section, a cooling section and a material discharging section which are communicated with one another in sequence from top to bottom, wherein the preheating section, the analysis section and the cooling section are all of tube-shell type heat exchange structures; a cooling section gas inlet is formed in the lower part of the cooling section, and a cooling section gas outlet is formed in the upper part of the cooling section and is communicated with an analysis section gas inlet formed in the lower part of the analysis section; an analysis section gas outlet formed in the upper part of the analysis section is communicated with a preheating section gas inlet formed in the lower part of the preheating section; a preheating section gas outlet formed in the upper part of the preheating section is emptied; the first buffering section is provided with a material distribution and gas guide structure and an analysis gas outlet; the analysis gas outlet is connected with an acid preparation system through a fan. The invention also provides an analysis method of the analysis tower. The analysis tower is simple in structure, high in heat exchange efficiency and low in energy consumption; regeneration of desulfurized active coke is realized; furthermore, high-concentration SO2 can be obtained, and recycling of sulfur is realized.

Preparations with deodorizing action are provided. The preparations include the zinc salt of ricinoleic acid; amino-functional amino acids; solubility promoters; organic and/or inorganic acids; and, optionally, water.

The invention relates to a method for producing sulfuric acid and co-producing calcium carbide by phosphogypsum, and belongs to the technical field of environmental protection. According to the method, phosphogypsum is subjected to a water washing and purification pretreatment by a multi-stage cyclone; then the pretreated phosphogypsum is dried and dewatered; the dewatered phosphogypsum enters a multi-stage suspension heat exchanger to carry out preheating; the hot state gypsum enters a circulating fluidized bed decomposing furnace, then primary air and secondary air are respectively introduced to carry out decompositions; high temperature sulfur dioxide-containing flue gas discharged from the top of the circulating fluidized bed decomposing furnace enters the multi-stage suspension heat exchanger to carry out heat exchanging and cooling with the cold state gypsum; dust in the cooled hot flue gas is removed by a multi-stage dust removing device; the dust-removed flue gas enters an acid washing and purification system to further remove the dust and the gaseous impurities in the flue gas; the purified and cleaned flue gas is conveyed into an acid preparation system to produce the sulfuric acid product; the hot state calcium oxide discharged from the bottom of the circulating fluidized bed decomposing furnace is cooled, and conveyed into a sealed calcium carbide furnace to carry out an electrical arc reaction with a carbon material to generate the calcium carbide product; the high temperature furnace gas discharged from the top of the sealed calcium carbide furnace is directly conveyed into the decomposing furnace, wherein the high temperature furnace gas is adopted as a fuel and a reducing agent. The method of the present invention has good environmental protection benefits and strong economic advantages.

The invention discloses an oxygen-enriched molten pool antimony refining production process, and belongs to the field of smelting of nonferrous metal. The process comprises the following steps: 1) batching: raw materials are uniformly mixed according to a mass ratio to obtain a mixture; 2) granulation: the uniformly mixed mixture is prepared as spherulites; 3) the prepared spherulites are fed in an oxygen-enriched oxidation furnace for oxidation smelting to prepare a primary high-temperature melt and liquid-state high-antimony ore slag; 4) reduction smelting: the liquid-state high-antimony ore slag flows in an oxygen-enriched reducing furnace for reduction smelting to prepare a secondary high-temperature melt and reducing furnace slag; 5) metal recovery: the reducing furnace slag flows in a fuming furnace through a slag chute; and recovery includes valuable metal; and 6) the smoke is recovered. The process effectively increases the SO2 concentration in smelted smoke to achieve conventional acid preparation system requirements, reduces the pollution, meanwhile, increases the yield, and reduces the energy consumption.

The feed for weaned piglet contains vitamin additive 0.2-3 weight portions, trace mineral element additive 2-20 weight portions, enzyme preparation 0.2-5 weight portions, antioxidant 1-3 weight portions, amino acid additive 5-70 weight portions, growth promoter 1-20 weight portions, acid preparation 10-100, seasoning 5-60 weight portions, enzymolyzed protein 50-700 weight portions and feed carrier 80-150 weight portions. It is puffed to form puffed feed. It is superior to available feed for weaned piglet, which results in diarrhea and weight loss of weaned piglet, and is environment friendly.

The invention discloses a system for preparing sulfuric acid from sulfur foam and desulfurization waste liquid by a semi-dry method and an acid preparation method. The system is formed by sequentiallyconnecting a separation unit, an incineration unit, a purification unit, a dry absorption unit and a tail absorption unit. Sulfur is extracted from sulfur foam, mixed with salt and sent to an incinerator to be incinerated for acid making, and dissolved clear liquid obtained after the sulfur is extracted and mixed with salt meets the requirement for returning to a desulfurization section to be recycled or entering a cold drum section.

The invention provides processing process for gold products, which comprises the steps of gold melting, mould reversing, polishing, mould grasping, press finishing and embrotheridery, and is characterized by further comprising the step of brightness treatment, the step is performed after the step of embrotheridery, and the step of brightness treatment comprises the followings: (1), hot acid preparation: pouring sulfuric acid, phosphoric acid, nitric acid and potassium nitrate according to priority into a container for uniform stirring, and heating until boiling, so as to form the hot acid; (2), cold acid preparation: mixing hydrofluoric acid, hydrochloric acid and dairy salt together for uniform stirring so as to from mixed solution, and then pouring salt water heated into the mixed solution for uniform stirring, so as to form the cold acid; and (3), placing gold products treated through embrotheridery into hot acid for soaking and then taking out, then placing into the cold acid for soaking and then taking out, and finally washing the gold products clean by using water, wherein the hot acid is kept to be under a boiling state.

The invention relates to a dinitrodiazophenol waste water processing method, which relates to a waste water processing method. The invention aims at providing the dinitrodiazophenol waste water processing method which utilizes iron casting iron chips and the electrical bridge function of active carbon to process dinitrodiazophenol waste water. The technical solution is that acid waste water and alkali waste water are firstly mixed during the manufacturing process of dinitrodiazophenol, then iron chips and active carbon are fed into an electrolyzation tower for standby application after being uniformly mixed, waste water firstly enters into an acidifying tank, after the pH value is adjusted to 2 - through acid preparation, precipitator is added under the stirring condition, the electrochemical reaction is carried out through an electrolyzation tower, the waste water processed by the electrochemical reaction enters into a neutralization reaction tank for the neutralization reaction after filtration, alkalescnce preparation is added, and coagulant aid is added when a great deal of fine crystals generate, the granule of sedimentary is bigger, clear liquid on the upper portion is pumped to enter active carbon for adsorption after the neutralization reaction and the waste settlement. The method is mainly used for purifying dinitrodiazophenol waste water which is initiating agent of domestic blasting machines.

The invention discloses a binary adjustable pre-converting method for preparing sulfuric acid from high concentration sulfur dioxide flue gas. The method comprises the following steps: a. high concentration SO2 flue gas successively subjected to twice heat exchange reaches the initiation temperature of a catalyst; and b, all (when the concentration is 14.5-20%) or part (when the concentration is 11-14.5%) of the high concentration SO2 flue gas enters a pre-converting catalyst layer of a converter for a converting reaction, the temperature is raised in reaction, and the flue gas leaves the pre-converting catalyst layer and enters a conventional #1 catalyst layer before the glue gas reaches the SO2 equilibrium conversion or is mixed with residual part of high concentration SO2 flue gas to enter the conventional #1 catalyst layer for a conventional '31-42'3+1 double-conversion and double-absorption normal flow for acid preparation. According to the method disclosed by the invention, SO2 concentration in flue gas entering the converting system fluctuates between 11% and 20%, the flue gas amount for preparing acid is decreased by 20-35%, the equipment investment is reduced by 20%, and the operating cost is lowered by 20%.

The invention discloses a method for preparing gallic acid. In the method, enzyme preparation and acid preparation processes are performed in two different containers by stages; and NaOH solution is used for adjusting pH value in both the enzyme preparation and acid preparation processes. The invention aims to provide a method for preparing gallic acid, which reduces reaction time and raw and auxiliary material consumption, overcomes the drawbacks of strong smell, effumability and easy environmental pollution of the ammonia water due to the fact that the pH value is adjusted not by ammonia water and reduces environmental pollution. And as microorganism growing and enzyme production processes are still performed in the acid production period, the method is advantageous over a common enzyme method in hydrolysis safety, and product purity and yield and can create great social and economic benefits.

The invention relates to a cracking technology for recovering and treating salt-bearing waste sulfuric acid. The cracking technology includes feeding the salt-bearing waste sulfuric acid, air and fuel for providing heat required by cracking into a cracking furnace, enabling the waste sulfuric acid to undergo cracking reaction in the cracking furnace to generate mixed furnace gas containing sulfur dioxide, molten salt droplets, sulfur trioxide, carbon dioxide, water vapor, nitrogen and smoke dust, removing part of the molten salt droplets in the furnace gas through the trapping effect of a retaining wall in the furnace, removing another part of the molten salt droplets in the furnace gas through phase change after a heat exchanger is cooled, and enabling desalted furnace gas to enter a subsequent acid preparation system after heat exchange so as to obtain a sulfuric acid finished product. According to the cracking technology, the cracking rate of the waste sulfuric acid is near 100%, and the salt separation recovery rate is near 100%. The method has good economic and social benefits.

The invention discloses a method for preparing sulfuric acid by utilizing enriched flue gas through high-temperature desulphurization of an electrolytic manganese residue. The method comprises: adding an activating agent and a reducing agent according to a certain ratio into the electrolytic manganese residue; performing uniform grinding; and feeding the obtained product to a rotary kiln after metering for high-temperature calcination desulphurization. The desulphurization rate of the acid leaching residue can be improved to more than 85%; the concentration of SO2 in the enriched flue gas can be improved to more than 5.5%; and an acid preparation process by means of one conversion and one absorption is adopted to produce 93% or 98% of industrial sulfuric acid. According to the method, the electrolytic manganese residue is utilized to prepare sulfuric acid; reuse of waste resource is realized, that is, the electrolytic manganese residue is recycled; and environmental pollution is reduced. The method has a wide industrial application.

The invention provides a preparation method of 7-amino-3-non-cephem-4-carboxylic acid which is 7-ANCA for short. The preparing procedures are as follows: 7-phenyl acetamide-3-hydroxy-3-cephem-4-carboxylic acid-p-nitrobenzyl ester is taken as raw material; firstly, metal borohydride is used to reduce the double bonds between the 3-parental nucleus and the 4-parental nucleus; sulfuryl etheride is used to esterify the 3-hydroxy, then alkali is used to remove the 3-methanesulfonic acid ester group to restore the double bonds between the 3-parental nucleus and the 4-parental nucleus; finally, a catalytic hydrogenation method is used to remove the protecting group on the 4-carboxyl of the parental nucleus, an enzyme method is used to remove the protecting group on the 7-amino of the parental nucleus, thus obtaining the product 7-ANCA. The invention has the advantages of being simple and feasible technology, improving production quality, reducing production cost and reducing environment pollution.