This invention discloses a method for the simultaneous removal of
arsenic and
chlorine from waste acid based on
sodium arsenite minerals, belonging to the field of
wastewater treatment and
resource recovery technology. The method includes: adding an oxidant to the waste acid solution; supplementing
copper,
sodium,
calcium, and
chlorine sources according to the stoichiometric ratio of
sodium arsenite (NaCaCu₅(AsO₄)₄Cl·5H₂O); conducting a water bath heating reaction under stirring conditions; adjusting the pH of the solution; and inducing Na₂O. + Ca 2+ In situ,
sodium arsenate precipitate (
sodium arsenate chlorite) is formed by the coordination
precipitation reaction of Cu²⁺, As(V), and Cl⁻. After
solid-liquid separation, washing, and
drying, the
sodium arsenate chlorite mineral is obtained. This invention utilizes the coexistence of
arsenic and
chlorine in pollutants. By adjusting the ratio of key components and controlling the
reaction conditions, both
arsenic and chlorine are simultaneously introduced into the mineral lattice, achieving efficient removal and resource conversion of arsenic and chlorine. This invention achieves synergistic removal and
resource utilization of pollutants, resulting in significant environmental and
economic benefits.