Disclosed in the present invention are an off-site electro-catalytic reaction method and
reaction system. The off-site electro-catalytic reaction method comprises: in a
battery system,
ion pairs in an
electrolyte undergoing an
electron exchange reaction with an
electrode, so as to obtain an oxidation potential or a
reduction potential; the
electrolyte with the obtained oxidation potential or
reduction potential entering an independent
reaction system outside the
battery system, and undergoing a
redox reaction with a reactant in the
reaction system, so as to obtain a mixture containing a
reaction product; and after separation, the
electrolyte, which has undergone the
redox reaction, returning to the
battery system, so as to obtain the oxidation potential or
reduction potential again. By means of the new off-site electro-catalytic tandem reaction technique provided in the present invention, a complex reaction involving gas, liquid and
solid phases, etc. can be moved out of the surface of an
electrode, and a reaction process is performed outside of a battery, thereby preventing the
contamination of the
electrode, a catalyst, a separator, etc. by reactants and / or products; and the reaction
system built by means of an off-site electro-catalytic synthesis technique operates stably, can be used for fundamental
theoretical research, and has practical application significance.