13 results about "Triethyl borate" patented technology

This invention discloses a process for preparing ultrafine glass powder using a spray pyrolysis method in the field of glass encapsulation materials. The process first prepares a homogeneous solution A using boric acid, aluminum nitrate nonahydrate, alkaline earth metal nitrates, lithium acetate, sodium acetate, and potassium acetate. Tetraethyl orthosilicate is dissolved in anhydrous ethanol to obtain solution B. A rare earth transition metal composite oxide nanoclusters encapsulated with a silica shell hybrid inorganic modifier is dispersed in anhydrous ethanol to obtain suspension C. Solution B and suspension C are mixed, and deionized water and hydrochloric acid are added to adjust the pH. After pre-hydrolysis and cooling, triethyl borate is added dropwise for co-condensation, and then mixed with solution A. After adjusting the pH and aging, the mixture is ultrasonically atomized and spray pyrolyzed to obtain ultrafine glass powder. The glass powder obtained by this invention has small particle size, high sphericity, and can be continuously produced.

The present application uses the mixture of residual liquid and cracking product (LPS) after the cracking of polydimethylsilane (PDMS) as raw material, and the polymerization reaction with tributyl borate or triethyl borate obtains viscous liquid (LPCS), which introduces the heterogeneous element boron; the viscous liquid (LPCS) further reacts with zirconium acetylacetonate to introduce the heterogeneous element zirconium, and the polycarbosilane ceramic precursor (PBZCS) doped with boron and zirconium elements is obtained; the precursor silk obtained after the melt spinning can be inosculated by the relatively simple air oxidation crosslinking method, and the boron and zirconium elements act as sintering agents to densify the fiber in high-temperature sintering, and the high-temperature-resistant ceramic fiber is obtained.

The invention relates to the technical field of refractory materials, in particular to a magnesium-carbon refractory material containing a metal-carbon complex phase and a preparation method thereof, and the magnesium-carbon refractory material containing the metal-carbon complex phase comprises fused magnesia particles, silicon-carbon complex phase particles, modified crystalline flake graphite, aluminum powder, monatomic silicon powder, nano carbon black and boron carbide. Through SiC-Si-C multiphase particles, SiC is used for resisting slag, and residual Si is oxidized and self-repaired; meanwhile, graphite is modified with triethyl phosphate and triethyl borate, a BPO4 coating is generated, medium and low temperature physical barrier and high temperature liquid phase sealing and filling are achieved, and the graphite is not damaged due to mild modification. The two constructs a multi-scale strengthening system, and carbon oxidation and slag erosion are effectively inhibited.

The application relates to the technical field of silicone rubber, in particular to a preparation method of a core-shell structure modified ceramic powder and a ceramized silicone rubber, which comprises the following steps: dispersing pretreated inorganic material powder in an ethylene glycol aqueous solution at a high speed, adding triethyl borate and a catalyst drop by drop under high-speed stirring, reacting, and ensuring that a shell layer is uniformly grown to a required thickness; a reaction formula is as follows: after the reaction is completed, standing and aging are carried out to stabilize the shell layer structure, the coated powder is separated out, impurities are removed through low-temperature drying, physically adsorbed water and solvents are removed, and finally, heat treatment is carried out to convert the amorphous gel shell layer into a crystalline or dense oxide shell layer and remove organic residues; a reaction formula is as follows: the inorganic material powder is weakly acid or weakly alkaline and is insoluble in water.

This invention discloses a method for preparing a slow-release lithium iron phosphate cathode material, belonging to the technical field of lithium iron phosphate cathode material preparation. The method includes the following steps: S1. Introducing a doped carbon source into a lithium silicate precursor for CVD carbon coating to obtain a carbon-coated lithium replenishing agent; the doped carbon source is a carbon source and a dopant source; the carbon source is at least one of methane, acetylene, ethylene, and propylene; the dopant source is at least one of trimethyl borate, triethyl borate, triisopropyl borate, and trimethylcycloborane; S2. Sintering the lithium iron phosphate precursor slurry and the carbon-coated lithium replenishing agent to obtain a slow-release lithium iron phosphate cathode material. This invention forms a uniform carbon layer on the surface of lithium silicate using a gas-phase carbon source to obtain a slow-release lithium replenishing agent; then, it is blended with the lithium iron phosphate precursor slurry and sintered to obtain a cathode material with both high capacity and long cycle life. This cathode material exhibits excellent battery capacity and excellent cycle life, and its battery capacity is not easily decayed.

The invention belongs to the technical field of cable preparation, and particularly relates to a copper core and aluminum core plastic insulation power cable and a preparation method thereof.The preparation method comprises the following steps that modified magnesium hydroxide and modified carbon black are dispersed in absolute ethyl alcohol, an acetic acid solution is added for stirring reaction, and composite particles are obtained after filtering and drying; the modified magnesium hydroxide is obtained by treating magnesium hydroxide with triethyl borate and KH-560; the modified carbon black is obtained by treating carbon black with TEOS, APTS and phosphorous acid; and uniformly mixing EVA, the composite particles, PE-g-MAH, an antioxidant and a lubricant, feeding the mixture into an extruder, and performing concentric extrusion with the cable core to obtain an outer sheath, thereby obtaining the power cable. According to the invention, the outer sheath containing the composite particles is coated outside the cable core, so that the service life of the cable in an ultraviolet environment is prolonged, and the smoke density of the cable in a fire disaster condition is reduced at the same time.

Disclosed are an electrolyte suitable for a lithium-ion battery of a silicon-carbon system and a lithium-ion battery. The electrolyte provided in the present disclosure includes an organic solvent, an additive, and a lithium salt, where the additive includes lithium trifluoromethyl triethyl borate, prop-1-ene-1,3-sultone, and fluoroethylene carbonate. The combined use of the additive may significantly prolong the cycle life of a silicon-carbon battery, and enables the silicon-carbon battery to have both high-temperature / low-temperature performance and safety performance, so that the silicon-carbon battery is enabled to be more suitable for large-scale commercial production.

This application belongs to the field of lithium battery technology, and particularly relates to composite modified electrolyte sheets and their preparation methods, and lithium batteries. The method includes: adding succinate and polyvinyl alcohol to a solvent mixture, adding potassium trifluoromethanesulfonylimide and a first lithium salt in multiple batches to obtain a precursor solution; curing and drying the precursor solution in a preset mold to obtain a precursor substrate; dissolving lithium borate in a solvent mixture and adjusting the viscosity to obtain a first slurry; spin-coating the first slurry onto both sides of the precursor substrate to obtain a first electrolyte substrate; adding triethyl borate to anhydrous ethanol, adding a second lithium salt and boric acid to obtain a second slurry; spin-coating the second slurry onto both sides of the first electrolyte substrate to obtain a second electrolyte substrate; obtaining a framework suspension based on a first COF monomer, a second COF monomer, polyethylene glycol, and potassium carbonate; spin-coating the framework suspension onto both sides of the second electrolyte substrate to obtain a composite modified electrolyte sheet; reducing interfacial impedance and improving electrochemical performance.

The application relates to the technical field of refractory materials, in particular to a magnesium-carbon refractory material containing metal-carbon complex phases and a preparation method thereof, which comprises fused magnesia particles, silicon-carbon complex phase particles, modified flake graphite, aluminum powder, elemental silicon powder, nano carbon black and boron carbide. The SiC-Si-C complex phase particles are used for slag resistance and residual Si oxidation self-repairing. The graphite is modified by triethyl phosphate and triethyl borate to form a BPO4 coating, which realizes physical blocking at medium and low temperatures and liquid phase sealing at high temperatures, and the graphite is not damaged by the mild modification. The two components build a multi-scale strengthening system, and effectively inhibit carbon oxidation and slag corrosion.

This application belongs to the field of cable material technology and proposes a method for preparing environmentally friendly, low-smoke, halogen-free polyethylene cable material. High-density polyethylene is melt-grafted with vinyltrimethoxysilane and triethyl borate to form a cross-linked network containing Si-O-B bonds. During combustion, this network pyrolyzes to generate B2O3 and SiO2 nanoparticles. The former melts to form a liquid layer that adsorbs free radicals to inhibit the combustion chain reaction, while the latter forms a eutectic glass phase with B2O3. Combined with ZnO nanoparticles released from the decomposition of a borosilicate-metal chelating agent as a flux, a dense glass-ceramic layer is formed in the carbon layer to isolate oxygen and heat. Simultaneously, ethylene-vinyl acetate copolymer, as a vinyl elastomer, not only improves flexibility through its toughening phase, but its vinyl groups also interact with the Si-O-B bonds of the borosilicate-grafted polyethylene, achieving a comprehensive improvement in flame retardancy, smoke suppression, and mechanical properties.

The application relates to the technical field of photoelectric conversion materials, in particular to a perovskite precursor material for photoelectric conversion and a preparation method thereof. The preparation raw material of the precursor material comprises the following components: lead iodide, stannous iodide, methyl amine iodide and modified hyperbranched polymer; the preparation raw material of the modified hyperbranched polymer comprises the following components in parts by weight: triethyl borate 2-3 parts, 1,3-propanediol 2-3 parts, 2-amino-6-chlorobenzimidazole 0.5-0.8 parts, acryloyl chloride 0.3-0.5 parts, acrylic acid 0.3-0.4 parts, trifluoroethyl methacrylate 1-1.5 parts and dopamine 0.4-0.6 parts; the prepared perovskite precursor can improve photoelectric conversion efficiency and stability.

This invention relates to the field of methyl ethyl ketone peroxide (MEKP) production technology, specifically to a method for preparing MEKP and its applications. The method includes the following steps: adding [BMIM]PF6 ionic liquid to a reaction vessel, followed by a composite catalyst, triethyl borate, and MEKP; cooling and then adding H2O2 dropwise, heating to 20-30°C, and adding a MnHCF dispersion; cooling the reaction solution to crystallize, and filtering to obtain preliminary MEKP crystals; recovering the ionic liquid by vacuum distillation of the filtrate; dehydrating the solution using a vacuum membrane; adding polyurethane acrylate and DPGDA, then coating the solution with a gelatin-gum arabic wall material, and spray drying to obtain MEKP. This invention effectively solves the core pain points in MEKP production and applications through triple innovation: MnHCF bimetallic catalysis, borate ester stabilization, and microcapsule safety design. It demonstrates significant advantages in catalytic efficiency, storage stability, safety performance, and practical applications.