The invention discloses a 
sulfur-tolerant catalyst for removing co and vocs and a preparation method of the 
sulfur-tolerant catalyst. The 
sulfur-tolerant catalyst comprises a carrier, a 
coating, Pt, Pd, Ir, auxiliaries, Co, Mo and S. The method comprises the following steps of: dissolving 
cobalt salt, 
molybdenum salt and 
ammonium sulfide under an acidic condition, adding 
activated carbon into a dissolving solution for dipping, then performing aging, adding hydrazine 
hydrate for 
reflux, performing cooling, filtering, washing and 
drying in vacuum; soaking a carrier in a 
coating mixed solution, performing purging, 
drying, calcining, and soaking the carrier in a 
mixed solution of a 
chloroplatinic acid solution, a chloropalladic acid solution, a chloroiridic acid solution and a 
nitrate solution for more than 6 hours by adopting an equivalent-volume impregnation method; finally, adding a 
reducing agent at 40-80 DEG C, taking out the carrier, washing and 
drying the carrier so as to obtain a target product, putting the target product and a Co-Mo-S catalyst into a porous container together. The catalyst reduces the 
activation energy of 
organic matter, enables the oxidation temperature of the 
organic matter to be reduced to 300 DEG C to be subjected to oxygenolysis, and is good in sulfur-resistant effect and good in poison resistance to other harmful substances.