The invention relates to a novel technology for preparing
vanadium pentoxide by using stone
coal ignited residue containing scherbinaite, which comprises the following steps: the stone
coal ignited residue containing scherbinaite is directly filled in a
cement leaching tank without being smashed or ball-milled, and then leached by a dilute
sodium carbonate solution at normal temperature or by heating at the temperature of 60 DEG C to 100 DEG C; the obtained leach solution is adsorbed by resin and desorbed by saturated
sodium chloride; the desorbed solution is dephosphorized and then added with
ammonium chloride to precipitate
vanadium, so as to obtain
ammonium metavanadate, and the
ammonium metavanadate is pyrolyzed to obtain the
vanadium pentoxide. The invention has the advantages that (1) the nubbly stone
coal ignited residue containing the scherbinaite is directly filled in the
cement leaching tank for leaching so that the investment of fixed assets is saved and the problem of
dust pollution in workshop is solved; (2) energy is saved by utilizing the
waste heat of a
roasting furnace for heating the leach solution, the leaching speed is quickened, the
recovery rate is improved and the grade of vanadium contained in the leach solution is enriched; (3) by adopting the dilute
sodium carbonate solution to substitute sulphuric acid for warming leaching, per
ton of fine vanadium consumes approximately 2 tons of
sodium carbonate only, therefore, production cost is saved compared with leaching per
ton by sulphuric acid; (4) the water used for working can be recycled, thus realizing zero release; the leach residue is slightly alkaline and meets the national placement standards of general wastes.