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This invention provides an amino-functionalized transparent impact-resistant isophthalic resin and its preparation method, belonging to the field of functional polymer material synthesis. The amino-functionalized transparent impact-resistant isophthalic resin is a multi-component copolymer of styrene, isoprene, and a p-chloromethylstyrene derivative monomer containing tertiary amine functional groups. The preparation method employs a classic anionic polymerization method. First, an amino-functionalized polystyrene active segment SN1 is prepared. Then, it is added to a styrene / isoprene mixed monomer for a two-stage reaction to obtain a block copolymer segment SN1-SP with alternating styrene / isoprene sequences. Finally, styrene and the amino-functionalized monomer are added for a three-stage reaction or directly coupled with a coupling agent to obtain a special block copolymer SN1-SP-SN2, successfully yielding the amino-functionalized transparent impact-resistant isophthalic resin. By controlling the length of the special alternating sequence molecular chain and the block composition ratio, the mechanical properties of the product are controlled. Simultaneously, the tertiary amine polar groups are quantitatively introduced into the molecular chains, successfully achieving high impact resistance and transparency, and also enhancing the resin polarity. Using a lithium-based polymerization method, the resin particles are free of monomer and harmful impurities.