The invention discloses a
covalent organic framework material for directly capturing
carbon dioxide in air and
coupling solar photo-thermal rapid
desorption and a preparation method of the
covalent organic framework material, and belongs to the field of materials. According to the material,
piperazine with secondary amine sites and dialdehyde derivatives are used as raw materials, dioxane and
mesitylene, m-
xylene and
mesitylene or o-
xylene and
mesitylene are used as solvents, and
solvothermal reaction is performed; and after the reaction is finished, sequentially carrying out suction
filtration and washing by using DMF and THF, carrying out Soxhlet extraction for 24 hours, and then carrying out
vacuum drying to obtain the
covalent organic framework. The
aldehyde and the secondary amine are condensed according to the proportion of 1: 2, and the secondary amine site of the
raw material piperazine is converted into the
tertiary amine site in the covalent organic framework through
aminal reaction.
Tertiary amine
nitrogen atoms can specifically recognize
carbon dioxide in air and perform
chemical adsorption, and firm covalent bonds can ensure the stability of a covalent organic framework, so that efficient air
carbon dioxide capture is realized. In addition, ionic bonds formed by the covalent organic framework and carbon dioxide are also beneficial to
coupling solar photo-thermal low-energy-consumption
desorption.